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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

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Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBBOriginalNaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Syntheses, characterization and theoretical calculation of the first alkali magnesium pyrophosphate fluorides with a short cutoff edge4Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters7Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Na2Mg2P2O7F2: A new diphosphate of the cuspidine family without disorder designed by targeted structural modulation1Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties9“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>0NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture0Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units6Four zinc borates: From acentric chain to centric porous layer0Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0

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  1. NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge

    Inorganic Chemistry · 2022-10-10

    Wenjuan Ma, Jie Zhang, Feng Yu, Bin Dai

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  2. Syntheses, characterization and theoretical calculation of the first alkali magnesium pyrophosphate fluorides with a short cutoff edge

    Journal of Molecular Structure · 2023-01-11

    Yanhui Zhang, Aixin Zhu, Hualing Tian, Xiaofeng Gu, Zhi Guo Su

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  3. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  4. Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters

    Inorganic Chemistry · 2023-05-06

    Nan Zhang, Shanshan Han, Yun Xie, Da-Li Chen, Wen‐Dong Yao, Xiao Fen Huang, Wenlong Liu, Sheng‐Ping Guo

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  5. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  6. Na2Mg2P2O7F2: A new diphosphate of the cuspidine family without disorder designed by targeted structural modulation

    Inorganica Chimica Acta · 2023-06-07

    Yanhui Zhang, Yun Mo Yang, Xifa Long, Hualing Tian, Xiaofeng Gu, Zhi Guo Su

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  7. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

    Inorganic Chemistry · 2023-07-26

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Changyou Liu, Xifa Long, Yun Mo Yang

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  8. Na1.5Cs0.5[Al{BO3}{B9O15(OH)3}1/3]: An Acentric Layered Aluminoborate with Nonlinear-Optical Properties

    Inorganic Chemistry · 2023-08-21

    Chong‐An Chen, Guo‐Yu Yang

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  9. “One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra

    Journal of Materials Chemistry C · 2024-01-01

    Haoran Wang, Jiahao Jiao, Abudukadi Tudi, Shilie Pan, Min Zhang

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  10. The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>

    SSRN Electronic Journal · 2024-01-01

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Maxim Yu. Arsent apos ev, Maria Georgievna Krzhizhanovskaya, Valeriy L. Ugolkov, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  11. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

    Huanhuan Zhao, Die Xu, Zhaohui Chen

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  12. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  13. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

    Inorganic Chemistry · 2024-08-21

    Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

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  14. Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement

    Dalton Transactions · 2024-12-13

    Xiaoqin Ma, Xin-Jun Zhao, QinglianT. Zhang, Xifa Long, Yun Mo Yang

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  15. CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture

    Inorganic Chemistry · 2025-04-18

    David Unnervik, Takuya Harada

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  16. Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units

    Crystal Growth & Design · 2025-08-20

    Jin-Ni Zhao, Juan Chen, Guo‐Yu Yang

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  17. Four zinc borates: From acentric chain to centric porous layer

    Chinese Journal of Structural Chemistry · 2025-10-22

    Juan Chen, Jin-Ni Zhao, Guo‐Yu Yang

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  18. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

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