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RESEARCH PAPER · Inorganic Chemistry · 2023

C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties

Wei Xu, Liang Ma, Yi‐Lei Lv, Siyu Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical PropertiesOriginalResearch progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4[C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy14Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence13(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals5[C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation6Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine1Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence1

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  1. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  2. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  3. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  4. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

    Inorganic Chemistry · 2024-07-11

    Dan Wang, Han Luo, Tingyu Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  5. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  6. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  7. [C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy

    Inorganic Chemistry · 2024-12-11

    Siyu Li, Danyang Dou, Cheng Chen, Qi Shi, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·

  8. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  9. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  10. Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals

    Inorganic Chemistry · 2025-08-05

    Tingyu Wang, Dan Wang, Bailiang Li, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  11. [C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation

    Journal of Molecular Structure · 2025-09-08

    Chao Ma, Yu-Ming Pan, Pei Han, Meihong Duan

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  12. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  13. Second-harmonic generation responses in low-dimensional metal bromides functionalized with l -arginine

    CrystEngComm · 2026-01-01

    Juan Cheng, Yingjie Wang, Qinglan Zhong, Ziyu Zhou, Hongmei Zeng, Guohong Zou, Zhien Lin

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  14. Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-03

    Chenyuan Ma, Xin-Mei Zeng, Jia-Tong Li, Xing-Yu Bi, Zhi Gang Fang, Meihong Duan

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