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RESEARCH PAPER · Inorganic Chemistry · 2025

Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

Kang Yang, Duanliang Wang, Fangcong Liu, Chuanrui Zhu, Qiyao Wang, Kui Wu, Jiyang Wang, Chuanying Shen

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Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated GenesOriginalA mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Halide substitution regulates structure and luminescence in Sb(III)-based 0D-OIMHs0Halide substitution regulates structure and luminescence in Sb(III)-based 0D-OIMHs0Dual‐Functional Ultraviolet Nonlinear Optics and Bright Luminescence Achieved in the First Fluorine‐Containing Hybrid Lone‐Pair Metal Mixed Halides8Control of Symmetry and Photophysical Properties of Hybrid Antimony Chlorides via Mixed Organic Cations0Enhanced Birefringence in Organic–Inorganic Hybrid Antimony Halides via Partial Halogen Substitution1Unlocking Nonlinear Optics and Photoluminescence with Simultaneous Enhancement of Bandgap and Birefringence in Hybrid Sb-Based Halides2Heavy‐Halide Coordination and Lattice‐Confined Molecular Alignment Enable Giant Birefringence in Hybrid Metal Halides0“-Ethylene” vs “-ethane”: How minor cation variations drive the self-assembly of structurally different supramolecular diiodine-halometalate hybrid complexes0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  2. Halide substitution regulates structure and luminescence in Sb(III)-based 0D-OIMHs

    SSRN Electronic Journal · 2026-01-01

    Miaomiao Pang, Yiguo Feng, Meiyuan Liu, Binling Yao, Rong Fu, Hui Min, Nian Zhao, Dong Shao

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  3. Halide substitution regulates structure and luminescence in Sb(III)-based 0D-OIMHs

    SSRN Electronic Journal · 2026-01-01

    Miaomiao Pang, Yiguo Feng, Meiyuan Liu, Binling Yao, Rong Fu, Hui Min, Nian Zhao, Dong Shao

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  4. Dual‐Functional Ultraviolet Nonlinear Optics and Bright Luminescence Achieved in the First Fluorine‐Containing Hybrid Lone‐Pair Metal Mixed Halides

    Advanced Functional Materials · 2026-03-25

    Jiajing Wu, Yu‐Qi Xu, Wen‐Dong Yao, Zhen‐Cheng Wu, Yi-Fan Fu, Ruo‐Nan Li, Yu‐Mei Zhang, Qiao‐Feng Huang, Sheng‐Ping Guo

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  5. Control of Symmetry and Photophysical Properties of Hybrid Antimony Chlorides via Mixed Organic Cations

    Inorganic Chemistry · 2026-04-21

    Gaosong Wang, Jiale Xu, Feiping Xiao, Jiejun Pan, Kaixuan Chen, Can Han, Pingqi Gao, Jiancan Yu

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  6. Enhanced Birefringence in Organic–Inorganic Hybrid Antimony Halides via Partial Halogen Substitution

    Crystal Growth & Design · 2026-05-25

    Qin Zhang, Luli Wang, Xuemei Lan, Liling Cao, Xuehua Dong, Ling Huang, Guohong Zou

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  7. Unlocking Nonlinear Optics and Photoluminescence with Simultaneous Enhancement of Bandgap and Birefringence in Hybrid Sb-Based Halides

    Inorganic Chemistry · 2026-06-19

    Yu‐Mei Zhang, Yuqi Xu, Wen‐Dong Yao, Qiu-Xia Tang, Liming Kong, Jiajing Wu

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  8. Heavy‐Halide Coordination and Lattice‐Confined Molecular Alignment Enable Giant Birefringence in Hybrid Metal Halides

    Advanced Functional Materials · 2026-08-07

    Mingshu Zhang, Shuya Zhao, Zhen‐Cheng Wu, Zheyu Zhang, Sheng‐Ping Guo, Yan Zhou

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  9. “-Ethylene” vs “-ethane”: How minor cation variations drive the self-assembly of structurally different supramolecular diiodine-halometalate hybrid complexes

    Polyhedron · 2026-08-31

    Nikita A. Korobeynikov, Andrey N. Usoltsev, Irina A. Shentseva, Maxim N. Sokolov⧫, Alexander S. Novikov, Sergey A. Adonin

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  10. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

    Read original paper ↗ ·
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