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RESEARCH PAPER · Inorganic Chemistry · 2020

A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster

Zhi‐Hui Shi, Yang Chi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 ClusterOriginalA highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 462Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Stepwise Coordination Assembly Approach toward Aluminum-Lanthanide-based Compounds14Borates as promising electrode materials for rechargeable batteries92Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge31KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold42A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Expanding the chemistry of borates with functional [BO2]− anions200Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)38Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages11NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units9Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements4RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks11Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family12A review of structures and physical properties of rare earth chalcophosphates77The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior26Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters7A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1Self-evolved BOx anchored on Mg2B2O5 crystallites for high-performance oxidative dehydrogenation of propane6Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances156Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O95Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Structural advantages of [B8O10(OH)6] for sustainable dual-functional scale/corrosion Inhibition in circulating water systems1

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  1. A highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 4

    Inorganic Chemistry Frontiers · 2020-01-01

    Mei Yan, Zongdong Sun, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  2. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  3. Stepwise Coordination Assembly Approach toward Aluminum-Lanthanide-based Compounds

    Inorganic Chemistry · 2020-09-04

    San‐Tai Wang, Shu‐Hua Zhang, Wei‐Hui Fang, Jian Zhang

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  4. Borates as promising electrode materials for rechargeable batteries

    Coordination Chemistry Reviews · 2020-09-30

    Sihan Yang, Huaiguo Xue, Sheng‐Ping Guo

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  5. Ba 2 B 7 O 12 F with novel FBB [B 7 O 16 F] and deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2020-10-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  6. KNa2ZrF7: A Mixed-Metal Fluoride Exhibits Phase-Matchable Second-Harmonic-Generation Effect and High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2020-12-15

    Xin Lian, Wen‐Dong Yao, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  7. A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer

    Chemical Communications · 2021-01-01

    Zhen‐Tao Lu, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

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  8. Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence

    Inorganic Chemistry · 2021-01-12

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  9. Second-order nonlinear optical and photoelectric properties of Zn4B6O12S

    Journal of Alloys and Compounds · 2021-02-03

    Wenfeng Zhou, Wen‐Dong Yao, Ru‐Ling Tang, Huaiguo Xue, Sheng‐Ping Guo

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  10. Expanding the chemistry of borates with functional [BO2]− anions

    Nature Communications · 2021-05-10

    Chunmei Huang, Miriding Mutailipu, Fangfang Zhang, Kent J. Griffith, Cong Hu, Zhihua Yang, John M. Griffin, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  11. Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)

    Inorganic Chemistry · 2021-07-09

    Xin Lian, Zhen‐Tao Lu, Wen‐Dong Yao, Sihan Yang, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  12. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  13. CsCdGa3O6: A I-II-III-O (I = alkali metal, II = divalent metal, III = Al, Ga, In) type oxide featuring [Ga4O14]16− helical belts linked [Ga6O6]6+ and [Ga8O8]8+ cages

    Journal of Solid State Chemistry · 2021-09-27

    Mei Yan, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  14. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

    Journal of Alloys and Compounds · 2021-11-24

    Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  15. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

    Journal of Alloys and Compounds · 2021-12-09

    Kaitong Liu, Jian Wei Han, Fuming Li, Congcong Jin, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  16. KNa 0.78 Eu 0.27 In 3.80 B 12 S 12 : a novel hexanary thioborate featuring a B 12 S 12 cluster and diverse InS x ( x = 4, 5, 6) units

    Inorganic Chemistry Frontiers · 2022-01-01

    Shanshan Han, Su‐Xin Yu, Wenlong Liu, Sheng‐Ping Guo

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  17. Ti0.85Eu3SiS7: The rare-earth/Ti based quaternary sulfide containing two variable valence elements

    Journal of Solid State Chemistry · 2022-03-19

    Sihan Yang, Xiaohui Li, Xiao Fen Huang, Wenlong Liu, Sheng‐Ping Guo

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  18. RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks

    Journal of Solid State Chemistry · 2022-05-09

    Yu-Long Wei, Gang-Xiang Liu, Da-Li Chen, Wen‐Dong Yao, Xin Lian, Wenlong Liu, Ru‐Ling Tang

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  19. Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family

    Inorganic Chemistry · 2022-05-27

    Ru‐Ling Tang, Yu-Long Wei, Yang Chi, Zhi‐Hui Shi, Wenlong Liu, Sheng‐Ping Guo

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  20. A review of structures and physical properties of rare earth chalcophosphates

    Coordination Chemistry Reviews · 2022-10-11

    Zi‐Xia Chen, Wenlong Liu, Sheng‐Ping Guo

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  21. The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior

    Chemical Communications · 2023-01-01

    Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  22. Mixed Rare-Earth Chalcogenide Borate Eu9–xRExMgS2B20O41 (RE = Sm, Gd) Featuring a 3D {[B20O41]22–}∞ Framework Connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– Clusters

    Inorganic Chemistry · 2023-05-06

    Nan Zhang, Shanshan Han, Yun Xie, Da-Li Chen, Wen‐Dong Yao, Xiao Fen Huang, Wenlong Liu, Sheng‐Ping Guo

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  23. A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties

    Journal of Solid State Chemistry · 2023-08-18

    Yun Xie, Da-Li Chen, Yu-Long Wei, Nan Zhang, Wen‐Dong Yao, Sheng‐Ping Guo

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  24. Self-evolved BOx anchored on Mg2B2O5 crystallites for high-performance oxidative dehydrogenation of propane

    iScience · 2023-10-06

    Dake Zhang, Shenghua Wang, Xingyu Lu, Chengcheng Zhang, Kai Feng, Le He, Hui Zhang, Wei Sun, Deren Yang

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  25. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  26. Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances

    Accounts of Chemical Research · 2024-02-01

    Wenfeng Zhou, Sheng‐Ping Guo

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  27. Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties

    Inorganic Chemistry · 2024-04-12

    Xinxin Fan, Mei Yang, Wen‐Dong Yao, Wenfeng Zhou, Tengfei Jiang, Wenlong Liu, Sheng‐Ping Guo

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  28. A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range

    Inorganic Chemistry · 2024-07-26

    Jie Song, Xianghao Kong, Conggang Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  29. Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O9

    Inorganic Chemistry · 2025-02-25

    Tingyu Wang, Han Luo, Shunke Zhang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  30. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

    Small · 2025-07-10

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  31. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

    Zhi Bing Deng, Rui Xiao, Mao‐Yin Ran, Ao Guo, Xiang Chen, Wenlong Liu, Sheng‐Ping Guo

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  32. From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity

    Inorganic Chemistry · 2025-08-21

    Qiu-Yang Du, Wen‐Dong Yao, Xu-Bin Ni, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  33. Structural advantages of [B8O10(OH)6] for sustainable dual-functional scale/corrosion Inhibition in circulating water systems

    Desalination · 2026-01-10

    Dong Guo, Ruidi Sun, Yahui Zhao, Yuansheng Pei, Li'an Hou

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