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RESEARCH PAPER · Chemical Communications · 2023

The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behavior

Mei Yang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behaviorOriginalHg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect30Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates13Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances156Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4Sr2HgGe2OS6: A Hg-Based Oxychalcogenide Infrared Nonlinear Optical Material Exhibiting Favorable Balance between a Large Band Gap and Strong Second Harmonic Generation Response10Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Oxidation-induced irreversible phase transformation of ethyltriphenylphosphonium-based copper chloride single crystals for achieving second harmonic generation and magnetism0Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides8A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates7Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2Spin-Resolved Second-Harmonic Generation from Europium 4f/5d States in a Weakly Stabilized Metastable Polymorph of Eu 2 P 2 S 60Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides0

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26 direct citing papers saved.

  1. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·

  2. A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties

    Journal of Solid State Chemistry · 2023-08-18

    Yun Xie, Da-Li Chen, Yu-Long Wei, Nan Zhang, Wen‐Dong Yao, Sheng‐Ping Guo

    Read original paper ↗ ·

  3. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

    Inorganic Chemistry · 2023-09-28

    Nan Zhang, Xiao Fen Huang, Wen‐Dong Yao, Yao Chen, Zheng-Rui Pan, Bingxuan Li, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  4. Na 2 CeF 6 : A Highly Laser Damage‐Tolerant Double Perovskite Type Ce(IV) Fluoride Exhibiting Strong Second‐Harmonic Generation Effect

    Small · 2023-12-05

    Ru‐Ling Tang, Wei Xu, Xin Lian, Yue‐Qi Wei, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  5. Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates

    Inorganic Chemistry Frontiers · 2024-01-01

    Nan Zhang, Mei Yang, Wen‐Dong Yao, Wei Xu, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  6. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  7. Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances

    Accounts of Chemical Research · 2024-02-01

    Wenfeng Zhou, Sheng‐Ping Guo

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  8. Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties

    Inorganic Chemistry · 2024-04-12

    Xinxin Fan, Mei Yang, Wen‐Dong Yao, Wenfeng Zhou, Tengfei Jiang, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Sr2HgGe2OS6: A Hg-Based Oxychalcogenide Infrared Nonlinear Optical Material Exhibiting Favorable Balance between a Large Band Gap and Strong Second Harmonic Generation Response

    Inorganic Chemistry · 2024-05-23

    Guili Wang, Chunxiao Li, Ming‐Hsien Lee, Jiyong Yao

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  10. Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy

    ACS Applied Materials & Interfaces · 2024-09-23

    Ping Feng, Sheng-Hua Zhou, Bingxuan Li, Jia-Xiang Zhang, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  11. Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials

    Inorganic Chemistry · 2024-11-06

    Fang-Xu Tian, Nan Zhang, Wen‐Dong Yao, Mingyang Li, Haiping Xu, Wenlong Liu, Jing Zhu, Sheng‐Ping Guo

    Read original paper ↗ ·

  12. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  13. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  14. Oxidation-induced irreversible phase transformation of ethyltriphenylphosphonium-based copper chloride single crystals for achieving second harmonic generation and magnetism

    Dalton Transactions · 2025-01-01

    Mengjie Sang, Yanqing Liu, Guokui Liu, Yangyang Dang

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  15. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

    Small · 2025-03-27

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Jian Tang, Wenwen Jiang, Nian‐Tzu Suen, Wenlong Yin, Sheng‐Ping Guo

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  16. Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides

    Inorganic Chemistry · 2025-05-30

    Fang-Xu Tian, Wen‐Dong Yao, Wenfeng Zhou, Jing Zhu, Sheng‐Ping Guo

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  17. A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps

    Inorganic Chemistry · 2025-07-10

    Zhi Bing Deng, Qiu-Yang Du, Fang-Xu Tian, Zong-Ze Li, Mingyang Li, Mao‐Yin Ran, Wenlong Liu, Sheng‐Ping Guo

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  18. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

    Small · 2025-07-10

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  19. Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates

    Inorganic Chemistry · 2025-07-18

    Zi-Nan Chen, Hai-Ping Xu, Wen‐Dong Yao, Mingyang Li, Chen‐Yi Zhao, Wenlong Liu, Sheng‐Ping Guo

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  20. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

    Zhi Bing Deng, Rui Xiao, Mao‐Yin Ran, Ao Guo, Xiang Chen, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  21. From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity

    Inorganic Chemistry · 2025-08-21

    Qiu-Yang Du, Wen‐Dong Yao, Xu-Bin Ni, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  22. Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances

    Inorganic Chemistry Frontiers · 2025-11-24

    Jiaxue Wang, Yixin Song, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  23. Spin-Resolved Second-Harmonic Generation from Europium 4f/5d States in a Weakly Stabilized Metastable Polymorph of Eu 2 P 2 S 6

    Chemistry of Materials · 2026-05-08

    Minwei Xiang, Hanxiang Mi, X Y Wang, 蘇思豪, Xiyue Cheng, Shuiquan Deng

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  24. Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses

    Inorganic Chemistry · 2026-07-25

    Cihai Hong, Aoge Yao, Chunlan Tang, Zhihui Zhang, Jian Tang, Lei Kang, Jing Ling Zhao, Wenlong Yin, Bin Kang

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  25. EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide

    Inorganic Chemistry · 2026-08-16

    Yu‐Xuan Zhang, Jiang-Hui Fan, Zhen‐Cheng Wu, Shao-Peng Gui, Mao‐Yin Ran, Sheng‐Ping Guo

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  26. d-f synergistic effect contributing record-high second-harmonic generation response in phase-matchable Mn-based chalcogenides

    Chinese Chemical Letters · 2026-09-01

    Yu‐Xuan Zhang, Sheng-Xian Xiao, Zhen-Cheng Wu, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·
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