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RESEARCH PAPER · Inorganic Chemistry · 2021

Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)

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Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)OriginalPhase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif47Synthesis, structural evolution and optical properties of a new family of oxychalcogenides [Sr 3 VO 4 ][MQ 3 ] (M = Ga, In, Q = S, Se)10Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)97Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap65The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**22First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance56Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra17Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24A review of structures and physical properties of rare earth chalcophosphates78Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution30Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64On the Crystal Chemistry of RE2Si2O7: Revisited Structures, Group–Subgroup Relationship, and Insights of Ce3+-Activated Radioluminescence19Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties1Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70A comprehensive review on synthesis, properties, and applications of quaternary transition metal oxychalcogenides19Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation11Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence20NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence6A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8ANb 2 (PS 4 )(S 2 ) 3 (A = K, Rb, Cs): the first Nb-based NLO thiophosphates with [NbS 2 (S 2 ) 3 ] and [Nb 2 PS 6 (S 2 ) 4 ] units exhibiting tri-state structural transformation and high performance6Ca6Ln12O9(BO3)10 (Ln = La-Gd) - new members of NLO borates family0Systematic Development of Visible-Light-Responsive d 0 Transition-Metal Oxysulfide Photocatalysts1

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  2. Synthesis, structural evolution and optical properties of a new family of oxychalcogenides [Sr 3 VO 4 ][MQ 3 ] (M = Ga, In, Q = S, Se)

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  3. Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation

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  4. Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)

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  5. Heteroanionic Melilite Oxysulfide: A Promising Infrared Nonlinear Optical Candidate with a Strong Second-Harmonic Generation Response, Sufficient Birefringence, and Wide Bandgap

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  6. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

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  7. From CsKTaF7 to CsNaTaF7: Alkali Metal Cations Regulation to Generate SHG Activity**

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  8. First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †

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  9. Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance

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    Jingjing Xu, Kui Wu, Yan Xiao, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  10. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): Two Nonlinear Optical Germanates Induced by Diverse PbOx Polyhedra

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    Mei Yan, Ru‐Ling Tang, Gang-Xiang Liu, Lei Huai, Wenlong Liu, Sheng‐Ping Guo

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  11. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

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    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  12. A review of structures and physical properties of rare earth chalcophosphates

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  13. Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS6

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  14. Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction

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    Yong‐Fang Shi, Shenghua Zhou, Bingxuan Li, Yi Liu, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  15. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

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  16. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

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  17. Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution

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  18. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

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  19. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

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  20. On the Crystal Chemistry of RE2Si2O7: Revisited Structures, Group–Subgroup Relationship, and Insights of Ce3+-Activated Radioluminescence

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  21. Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides

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  22. A series of new rare-earth sulfide borates RE3S3BO3 (RE = Nd, Tb, Dy): Syntheses, structures and optical properties

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  23. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

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  24. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

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  25. A comprehensive review on synthesis, properties, and applications of quaternary transition metal oxychalcogenides

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  26. Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties

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  27. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

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  29. Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials

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  30. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

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  31. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

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  36. ANb 2 (PS 4 )(S 2 ) 3 (A = K, Rb, Cs): the first Nb-based NLO thiophosphates with [NbS 2 (S 2 ) 3 ] and [Nb 2 PS 6 (S 2 ) 4 ] units exhibiting tri-state structural transformation and high performance

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