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RESEARCH PAPER · Nature Communications · 2021

Expanding the chemistry of borates with functional [BO2]− anions

Chunmei Huang, Miriding Mutailipu, Fangfang Zhang, Kent J. Griffith, Cong Hu, Zhihua Yang, John M. Griffin, Kenneth Reinhard Poeppelmeier, Shilie Pan

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Expanding the chemistry of borates with functional [BO2]− anionsOriginalA new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices9BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure11Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence4Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure6Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units17Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals147Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals16Identical in Formula but Not Isotypic in Configuration: Discovery of a New Highly Polymerized [B12O24] Cluster in Cs3AlB6O1212Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units102Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units9Coordination-Directed Structural Modulation and Design of Deep-Ultraviolet Nonlinear Optical Materials4Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5K3BaTeB7O15: A new borotellurite with mixed metal cations5K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units6Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion133Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion13Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140(N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphates33A 2 B 6 O 9 F 2 (A = NH 4 , K): new members of A 2 B 6 O 9 F 2 family with deep-UV cutoff edges and moderate birefringence17Cd 4 REO(BO 3 ) 3 (RE = Sm, Eu, Tb): three new cadmium–rare earth oxyborates with both good NLO and luminescence properties6KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring10Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material43Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings2NH 4 (B 6 PO 10 (OH) 4 )·H 2 O: exhibiting the largest birefringence in borophosphates43Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7α-LiMB 9 O 15 (M = Sr, Pb): flexible [B 3 O 7 ] units leading to the low temperature phase of β-LiMB 9 O 15 (M = Sr, Pb)11Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window62A Theoretical Perspective to Study the Optical Properties of Tetrafluoroborates4Borates as a new direction in the design of oxide ion conductors21Vanadate Encapsulated Polyoxoborate Framework with [V12B18] Clusters: An Efficient Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions28Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains186Fabrication of monodispersed B, N co-doped hierarchical porous carbon nanocages through confined etching to boost electrocatalytic oxygen reduction30Liquid fragility maximum in lithium borate glass‐forming melts related to the local structure15NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence29Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap79LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Layered Double Hydroxide Templated Synthesis of Amorphous NiCoFeB as a Multifunctional Electrocatalyst for Overall Water Splitting and Rechargeable Zinc–Air Batteries120Rb 3 B 11 P 2 O 23 : Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material58Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity13Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)17An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence17Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework5Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units1Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Recent progress in borate-based short-wavelength nonlinear optical crystals with boron–oxygen skeleton modification28Three new aluminoborates: from 1D tube to 3D framework9BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Advancements in Nanomaterials for Solar Cell Applications: A Comprehensive of Recent Developments1Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Li3B8O13X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO3 Units18NaRb 6 (B 4 O 5 (OH) 4 ) 3 (BO 2 ) Featuring Noncentrosymmetry, Chirality, and the Linear Anionic Group BO 2 –101Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence129Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5A Polar Tetragonal Tungsten Bronze with Colossal Second‐Harmonic Generation18Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)23Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36Cs 3 [(BOP) 2 (B 3 O 7 ) 3 ]: A Deep-Ultraviolet Nonlinear Optical Crystal Designed by Optimizing Matching of Cation and Anion Groups169Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features20Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Design Principles for Noncentrosymmetric Materials23The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Novel “Anti-Zeolite” Ba3Sr3B4O12: Eu3+ Phosphors: Crystal Structure, Optical Properties, and Photoluminescence2Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211The synthesis of novel lanthanum hydroxyborate at extreme conditions3Self-evolved BOx anchored on Mg2B2O5 crystallites for high-performance oxidative dehydrogenation of propane6Visible to mid-infrared giant in-plane optical anisotropy in ternary van der Waals crystals41Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy12PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12Study on a direct hydrazine borane fuel cell based on an anion exchange membrane3K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10(C(NH2)3)2(I2O5F)(IO3)(H2O) and C(NH2)3IO2F2: Two Guanidine Fluorooxoiodates with Wide Band Gap and Large Birefringence20“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units7CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra5DFT-based 11 B solid-state NMR calculations for guiding fine local structure identification and phase-property modulation in Zn x Y 1− x BO 3–0.5 x borate oxide ion conductors1Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units3Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8HgBr 2 : an easily growing wide-spectrum birefringent crystal38K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units7New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19Quadrupolar NMR crystallography guided crystal structure prediction (QNMRX-CSP)11Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties18Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Design of Deep-Ultraviolet Zero-Order Waveplate Materials by Rational Assembly of [AlO2F4] and [SO4] Groups9Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Low- And High-Temperature Crystal Chemistry of Magnetic Materials with Tunable Properties5Extending Unique 1D Double-Chains to 2D Layers with Birefringent Gain by Introducing a Hydroxyl Group5NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges5An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution32An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution1Tunable Optical Anisotropy in Rare‐Earth Borates with Flexible [BO3] Clusters7M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Thermal Expansion of Alkaline-Earth Borates1Modulating Electron Density of Boron–Oxygen Groups in Borate via Metal Electronegativity for Propane Oxidative Dehydrogenation5Borates: Solid‐State Chemistry0Thermal Expansion of Alkaline-Earth Borates4About compounds containing 16-valence electron anions [XYZ] n− – a brief and current overview including some properties of such anions0Exploring the effect of facile i-line photolithography on the structure and physicochemical properties of photosensitive glass ceramics1(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation24LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10Hydroflux Synthesis and Structural Phase Transition of Rare‐Earth Borate Hydroxides Na2[RE(BO3)(OH)2] (RE=Y, Gd−Er)7Thermocrystallochemistry of Magnetic Materials with Managed Properties (Review)0A2Cd(PO3)4 (A = K, Rb, Cs): Series of cadmium polyphosphates with infinite 1[(PO3)4]ꝏ chains and deep ultraviolet transparency windows2A novel bimetallic 3-D organic-inorganic hybrid vanadoborate architecture with exceptional proton conductivity4Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4A new structure type of the Na3Yb(BO3)2: Synthesis, crystal structure, thermal behavior, ionic conductivity, and spectroscopy2Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Ba 3 Al 2 B 12 O 24 : a beryllium-free member of the Sr 2 Be 2 B 2 O 7 family with a 2 ∞ [B 12 Al 2 O 28 ] double-layered structure4CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Li 2 CeRbB 18 O 30 and Li 2 Cs 2 SrB 18 O 30 : promising low-birefringence materials for UV and deep UV zero-order waveplates4Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks0Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1Unveiling the supercapattery behaviour of novel kotoite-type Co3(BO3)2 nanoparticles8Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal5

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  1. A new acentric borate–nitrate Cs 3 B 8 O 13 (NO 3 ) with interpenetrating porous 3D covalent and ionic lattices

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  2. BaZn 3 (BO 3 ) 2 F 2 : a new beryllium-free zincoborate with a KBBF-type structure

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  3. Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks

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  4. Na 2 La 2 B 10 O 19 : a new lanthanum sodium borate with infinite 2D layer 2∞[B 10 O 19 ] 8− and moderate birefringence

    New Journal of Chemistry · 2021-01-01

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  5. Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure

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  6. Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units

    Dalton Transactions · 2021-01-01

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  7. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

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  8. Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals

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  9. Identical in Formula but Not Isotypic in Configuration: Discovery of a New Highly Polymerized [B12O24] Cluster in Cs3AlB6O12

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  10. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

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  11. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

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  12. Coordination-Directed Structural Modulation and Design of Deep-Ultraviolet Nonlinear Optical Materials

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  13. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

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  14. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

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  15. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

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  16. K3BaTeB7O15: A new borotellurite with mixed metal cations

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  17. K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units

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  18. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

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  19. Na4B8O9F10: A Deep‐Ultraviolet Transparent Nonlinear Optical Fluorooxoborate with Unexpected Short Phase‐Matching Wavelength Induced by Optimized Chromatic Dispersion

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  20. Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals

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  21. (N 2 H 6 )[HPO 3 F] 2 : maximizing the optical anisotropy of deep-ultraviolet fluorophosphates

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  22. A 2 B 6 O 9 F 2 (A = NH 4 , K): new members of A 2 B 6 O 9 F 2 family with deep-UV cutoff edges and moderate birefringence

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  23. Cd 4 REO(BO 3 ) 3 (RE = Sm, Eu, Tb): three new cadmium–rare earth oxyborates with both good NLO and luminescence properties

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  24. KEu 2 In 3 B 12 S 13 : a novel type of thioborate featuring B 12 S 12 cluster and unique In 6 S 6 12-membered ring

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  25. Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material

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  26. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

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  27. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

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  28. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

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  29. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

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  30. Na 4 Ga 8 S 14 : a Ga-enriched wide band gap ternary alkali-metal sulfide with unique [Ga 12 S 42 ] 12-membered rings

    Dalton Transactions · 2022-01-01

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  31. NH 4 (B 6 PO 10 (OH) 4 )·H 2 O: exhibiting the largest birefringence in borophosphates

    Chemical Communications · 2022-01-01

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  32. Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra

    CrystEngComm · 2022-01-01

    Yazhuo Dong, Chong‐An Chen, Juan Chen, Jian‐Wen Cheng, Jinhua Li, Guo‐Yu Yang

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  33. α-LiMB 9 O 15 (M = Sr, Pb): flexible [B 3 O 7 ] units leading to the low temperature phase of β-LiMB 9 O 15 (M = Sr, Pb)

    Inorganic Chemistry Frontiers · 2022-01-01

    Kaitong Liu, Jian Wei Han, Fuming Li, Shujuan Han, Zhihua Yang, Xuping Wang, Shilie Pan

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  34. Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

    Science China Chemistry · 2022-03-10

    Yanhui Zhang, Fuming Li, Rong Yang, Yun Mo Yang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  35. A Theoretical Perspective to Study the Optical Properties of Tetrafluoroborates

    ChemPhysChem · 2022-05-07

    Jun Sun, Zhaofeng Wu, Ming‐Hsien Lee, Haiming Duan

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  36. Borates as a new direction in the design of oxide ion conductors

    Science China Materials · 2022-05-24

    Xiaohui Li, Yang Li, Zhenyu Zhu, Xiaoge Wang, Pohua Chen, Senchuan Huang, Xianyi Wei, Guohong Cai, Pascal Manuel, Sihai Yang⧫, Jianhua Lin, Xiaojun Kuang, Junliang Sun

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  37. Vanadate Encapsulated Polyoxoborate Framework with [V12B18] Clusters: An Efficient Bifunctional Electrocatalyst for Oxygen and Hydrogen Evolution Reactions

    Crystal Growth & Design · 2022-07-11

    Tanmay Rom, Rathindranath Biswas, Krishna Kanta Haldar, Uttam Kumar Saha, Sudhindra Rayaprol, Avijit Kumar Paul

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  38. Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F

    Inorganic Chemistry · 2022-07-27

    Xingqi Li, Dongdong Chu, Wenqi Jin, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  39. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains

    Light Science & Applications · 2022-08-12

    Fangfang Zhang, Xinglong Chen, Min Zhang, Wenqi Jin, Shujuan Han, Zhihua Yang, Shilie Pan

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  40. Fabrication of monodispersed B, N co-doped hierarchical porous carbon nanocages through confined etching to boost electrocatalytic oxygen reduction

    Nano Research · 2022-08-13

    Xuefei Wang, Chao Han, Haitao Li, Panpan Su, Na Ta, Yanfu Ma, Zhenguo Huang, Jian Liu

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  41. Liquid fragility maximum in lithium borate glass‐forming melts related to the local structure

    International Journal of Applied Glass Science · 2022-09-02

    Oliver L. G. Alderman, Chris J. Benmore, Bryce Reynolds, Brock Royle, Steve A. Feller, Rick J. K. Weber

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  42. NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge

    Inorganic Chemistry · 2022-10-10

    Wenjuan Ma, Jie Zhang, Feng Yu, Bin Dai

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  43. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

    Inorganic Chemistry · 2022-11-01

    Lihan Deng, Mengfan Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  44. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

    Inorganic Chemistry · 2022-11-04

    Jingdong Yan, Dongdong Chu, Zilong Chen, Jian Wei Han

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  45. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

    Advanced Optical Materials · 2022-11-17

    Ziting Yan, Dongdong Chu, Min Zhang, Zhihua Yang, Shilie Pan

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  46. Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap

    Materials Horizons · 2022-11-25

    Jiazheng Zhou, Zhongxu Fan, Kewang Zhang, Zhihua Yang, Shilie Pan, Junjie Li

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  47. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

    Advanced Optical Materials · 2022-12-03

    Xiaojing Li, Zilong Chen, Fuming Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  48. Layered Double Hydroxide Templated Synthesis of Amorphous NiCoFeB as a Multifunctional Electrocatalyst for Overall Water Splitting and Rechargeable Zinc–Air Batteries

    Advanced Energy Materials · 2022-12-05

    Masumeh Moloudi, Abolhassan Noori, Mohammad Safi Rahmanifar, Yasin Shabangoli, Maher F. El‐Kady, Nahla B. Mohamed, Richard B. Kaner, Mir Fazlollah Mousavi

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  49. Rb 3 B 11 P 2 O 23 : Materials Design of a New Chemically Benign Deep-Ultraviolet Nonlinear Optical Material

    ACS Materials Letters · 2022-12-12

    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, P. Shiv Halasyamani, Hongwei Yu

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  50. Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity

    Inorganic Chemistry · 2022-12-21

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Lev S. Manelis, A. M. Banaru, Alexey V. Povolotskiy, Valentina A. Yukhno, M. Yu. Arsent’ev, Yevgeny E. Savchenko, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Р. С. Бубнова, Sergey M. Aksenov

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