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RESEARCH PAPER · Science China Materials · 2021

Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency

Jiahao Jiao, Abudukadi Tudi, Min Zhang, Wenbing Cai, Junjie Li, Zhihua Yang, Shilie Pan

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Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparencyOriginalPromising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83Highly transparent Pb8O7I2, a novel lead oxyiodide5Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals1[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence5Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Li2B5O8Cl: A New Borate Chloride with Interpenetrating 3D B–O Frameworks Enriching Structural Chemistry of Borate0On the Pb2HgO2Cl2 structure type: Synthesis and crystal structure of a new representative, Pb2CdO2Br2, and electronic structure and chemical bonding in the whole Pb2MO2X2 (M=Cd, Hg; X=Cl, Br) family1First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties03Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides1Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3[Pb(ptz)(OH)(H2O)]: A Hybrid Nonlinear Optical Crystal with Large Birefringence0Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units2InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance0Synthesis, Crystal Structures, Spectroscopic and Thermal Characterization of Monosubstituted Lead Acetates Pb(XCH2COO)2 (X = Cl, Br, I, OH)0Growth and Characterization of Arsenic-Based Polymorphs of Co 2 AsO 4 F: Visible-Light-Induced Photocatalytic Dye Degradation, Electrocatalytic Hydrogen Evolution, and Catalytic Solvent-Free Sustainable Knoevenagel Condensation0Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials0

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  1. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  2. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

    Angewandte Chemie International Edition · 2022-04-29

    Jiahao Jiao, Meng Cheng, Rong Yang, Yuchen Yan, Min Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  3. Highly transparent Pb8O7I2, a novel lead oxyiodide

    Journal of Solid State Chemistry · 2022-05-28

    Dmitri O. Charkin, Artem S. Borisov, Vadim E. Kireev, Alexey N. Kuznetsov∥, Shorduz Umedov, Еvgeny V. Nazarchuk, Vladimir N. Bocharov, Oleg I. Siidra

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  4. Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals

    Crystal Growth & Design · 2023-02-13

    Jingcheng Feng, Lei Bai, Guochun Zhang

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  5. [K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV

    Advanced Science · 2023-02-27

    Wen‐Fa Chen, Bin‐Wen Liu, Shao‐Min Pei, Xiao‐Ming Jiang, Guo‐Cong Guo

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  6. Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence

    Inorganic Chemistry Communications · 2023-06-25

    Xiaofei Li, Huili Zhang, Dong‐Xue Jiao, Chao He, Yu-Xue Guo, Xing‐Tao An, Qi Wei

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  7. Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges

    Dalton Transactions · 2023-12-07

    Hongkang Su, Jiahao Jiao, Shi‐Bin Wang, Donghai An, Min Zhang

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  8. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  9. Li2B5O8Cl: A New Borate Chloride with Interpenetrating 3D B–O Frameworks Enriching Structural Chemistry of Borate

    ECS Journal of Solid State Science and Technology · 2024-03-04

    Lihan Deng, Chunyan Bai, Jin Li, N. T. Zhang

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  10. On the Pb2HgO2Cl2 structure type: Synthesis and crystal structure of a new representative, Pb2CdO2Br2, and electronic structure and chemical bonding in the whole Pb2MO2X2 (M=Cd, Hg; X=Cl, Br) family

    Solid State Sciences · 2024-07-24

    Dmitri O. Charkin, Vadim E. Kireev, Yevgeny E. Savchenko, Alexey N. Kuznetsov∥, A. A. Kompanchenko, Sergey M. Aksenov

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  11. First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties

    Physica Scripta · 2024-10-24

    Hongheng Chen, Mei Hu, Jialong Wang, Haiming Duan, Qun Jing, Zhaohui Chen

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  12. 3Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides

    Dalton Transactions · 2025-01-01

    Mayinuer Maimaiti, Yuchen Yan, Jiang Wu, Tingwen Han, Jing Xie, Min Zhang

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  13. Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence

    Inorganic Chemistry · 2025-01-27

    Jiang Wu, Jiahao Jiao, Mayinuer Maimaiti, Ke Li, Jugong Zheng, Min Zhang

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  14. [Pb(ptz)(OH)(H2O)]: A Hybrid Nonlinear Optical Crystal with Large Birefringence

    Inorganic Chemistry · 2025-10-09

    De-Xuan Jiang, Yuhang Wang, Yuxiao Wang, Ling Gao, Song‐De Han, Qi Wei, Li Wei, Guo‐Yu Yang

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  15. Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units

    Inorganic Chemistry Frontiers · 2025-12-20

    Haoran Wang, chenxu li, Xue Bai, Qingyu Liu, Xueling Hou, Min Zhang

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  16. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

    Dan-Dan Zhou, Chunli Hu, Bingxuan Li, Jianggao Mao, Fang Kong

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  17. F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance

    Materials Today Chemistry · 2026-05-06

    Dahong Peng, Hongkang Su, Ziting Yan, chenxu li, Shilie Pan, Min Zhang

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  18. Synthesis, Crystal Structures, Spectroscopic and Thermal Characterization of Monosubstituted Lead Acetates Pb(XCH2COO)2 (X = Cl, Br, I, OH)

    Journal of Structural Chemistry · 2026-07-01

    V. E. Kireev, D. O. Charkin, D.S. Degterev, O.S. Smulskaya, A. N. Gosteva, Kompanchenko A.A., A. M. Banaru, Sergey M. Aksenov

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  19. Growth and Characterization of Arsenic-Based Polymorphs of Co 2 AsO 4 F: Visible-Light-Induced Photocatalytic Dye Degradation, Electrocatalytic Hydrogen Evolution, and Catalytic Solvent-Free Sustainable Knoevenagel Condensation

    Inorganic Chemistry · 2026-08-28

    Bibaswan Sen, Dipali Karmakar, Debojyoti Kundu, Ankita Banik, Nayim Sepay, Priyabrata Banerjee, Uday Prabhakarrao Deshpande, S. Ali

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  20. Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials

    Small · 2026-10-11

    Haoran Wang, Haotian Qiu, chenxu li, Xue Bai, Qingyu Liu, Zhihua Yang, Min Zhang

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