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RESEARCH PAPER · Chemistry of Materials · 2002

New Selenites: Syntheses, Structures, and Characterization of Centrosymmetric Al2(Se2O5)3 and Ga2(Se2O5)3 and Non-centrosymmetric In2(Se2O5)3

Kang Min Ok, P. Shiv Halasyamani

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New Selenites: Syntheses, Structures, and Characterization of Centrosymmetric Al2(Se2O5)3 and Ga2(Se2O5)3 and Non-centrosymmetric In2(Se2O5)3Original22 New compounds and structures in the solid state2ChemInform Abstract: New Selenites: Syntheses, Structures, and Characterization of Centrosymmetric Al2(Se2O5)3 and Ga2(Se2O5)3 and Non‐centrosymmetric In2(Se2O5)3.0Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]11321 New compounds and structures in the solid state1Hydrothermal synthesis and crystal structure of a three-dimensional metal selenite containing double helical chains: Fe3(H2O)(SeO3)313Au2(SeO3)2(SeO4): Synthesis and Characterization of a New Noncentrosymmetric Selenite−Selenate56The chiral structure induced by lone-pair electrons: syntheses and characterization of two novel chiral rare-earth selenites containing homochiral helical chains11Syntheses and structures of three new scandium selenites: Sc2(SeO3)3·H2O, Sc2 (SeO3)3·3H2O and CsSc3(SeO3)4 (HSeO3)2·2H2O12Two new octahedral/pyramidal frameworks containing both cation channels and lone-pair channels: syntheses and structures of Ba2MnIIMn2III(SeO3)6 and PbFe2(SeO3)428Synthesis and structure of a novel three-dimensional metal selenite containing multidirectional intersecting double helical chains: [Fe2(H2O)4(SeO3)2]8Thallium(III) selenite, Tl2(SeO3)31Selenious Acid as a Ligand: Molecular and Crystal Structure of [Co(H2O)2Cl2(H2SeO3)2]2Effective second-order nonlinearity in acentric optical crystals with low symmetry53Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)244Synthesis, Structure, and Characterization of Novel Two- and Three-Dimensional Vanadates: Ba2.5(VO2)3(SeO3)4·H2O and La(VO2)3(TeO6)·3H2O60Nd5(AsO3)4Cl3: The First Oxo‐Arsenate(III)‐Chloride of the Lanthanides23Synthesis and Crystal Structure of In(OH)(SeO3)10Selenium Oxoanion Compounds of Palladium(II)25Syntheses, crystal structures and photoluminescence properties of three novel organically bonded indium selenates or selenites27Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5115La4(Si5.2Ge2.8O18)(TeO3)4 and La2(Si6O13)(TeO3)2: Intergrowth of the lanthanum(III) tellurite layer with the XO4 (X=Si/Ge) tetrahedral layer20Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl432Synthetic Approaches for Noncentrosymmetric Molybdates59New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures11Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System15Noncentrosymmetry in New Templated Gallium Fluorophosphates34The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching21Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H1019A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl20Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O887Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Explorations of new selenites of the group IIIA and IVA metals13Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Synthesis, Band and Crystal Structures, and Optical Properties of the Ternary Compound Mg2Te3O814New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Cobalt selenium oxohalides: catalysts for water oxidation15Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Enhanced Second Harmonic Generation from an Organic Self-Assembled Eutectic Binary Mixture: A Case Study with 3-Nitrobenzoic and 3,5-Dinitrobenzoic Acids23Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B2Se3O109Variable dimensionality and framework found in a series of quaternary zinc selenites, A 2 Zn 3 (SeO 3 ) 4 · x H 2 O (A = Na, Rb, and Cs; 0≤ x ≤1) and Cs 2 Zn 2 (SeO 3 ) 3 ·2H 2 O7Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Two anionically derivatized scandium oxoselenates(IV): ScF[SeO3] and Sc2O2[SeO3]12ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Sc2[Se2O5]3: The First Rare-Earth Metal Oxoselenate(IV) with Exclusively [Se2O5]2− Anions6BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63New Crystal Structures of Rare‐Earth Metal(III) Oxotellurates(IV) RE2Te3O9: A1‐Type (RE=La, Ce) and A2‐Type (RE=Pr, Nd)8The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2Piezoelectricity and related properties in orthorhombic cadmium diiodate4Synthesis and crystal structure of two scandium oxotellurates(IV): Sc2Te3O9 and Sc2Te4O111Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence7The cerium(III) fluoride oxoselenate(IV) CeF[SeO 3 ]0Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence0InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5

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  1. 22 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2002-01-01

    Martin P. Attfield

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  2. ChemInform Abstract: New Selenites: Syntheses, Structures, and Characterization of Centrosymmetric Al2(Se2O5)3 and Ga2(Se2O5)3 and Non‐centrosymmetric In2(Se2O5)3.

    ChemInform · 2002-08-13

    Kang Min Ok, P. Shiv Halasyamani

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  3. Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]

    Inorganic Chemistry · 2002-12-10

    Thomas C. Shehee, Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

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  4. 21 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2003-01-01

    Martin P. Attfield

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  5. Hydrothermal synthesis and crystal structure of a three-dimensional metal selenite containing double helical chains: Fe3(H2O)(SeO3)3

    Journal of Solid State Chemistry · 2004-06-18

    Dong‐Rong Xiao, Yu Hou, Enbo Wang, Haiyan An, Jian Jun Lu, Yangguang Li, Lin Xu, Changwen Hu

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  6. Au2(SeO3)2(SeO4): Synthesis and Characterization of a New Noncentrosymmetric Selenite−Selenate

    Inorganic Chemistry · 2004-08-17

    Mathias Siegfried Wickleder, Oliver Büchner, Claudia Wickleder, Sherif el Sheik, Gunther Brunklaus, Hellmut Eckert

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  7. The chiral structure induced by lone-pair electrons: syntheses and characterization of two novel chiral rare-earth selenites containing homochiral helical chains

    Journal of Molecular Structure · 2004-09-24

    Dong‐Rong Xiao, Haiyan An, Enbo Wang, Lin Xu, Changwen Hu

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  8. Syntheses and structures of three new scandium selenites: Sc2(SeO3)3·H2O, Sc2 (SeO3)3·3H2O and CsSc3(SeO3)4 (HSeO3)2·2H2O

    Journal of Solid State Chemistry · 2004-11-01

    Magnus G. Johnston, William T. A. Harrison

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  9. Two new octahedral/pyramidal frameworks containing both cation channels and lone-pair channels: syntheses and structures of Ba2MnIIMn2III(SeO3)6 and PbFe2(SeO3)4

    Journal of Solid State Chemistry · 2004-12-01

    Magnus G. Johnston, William T. A. Harrison

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  10. Synthesis and structure of a novel three-dimensional metal selenite containing multidirectional intersecting double helical chains: [Fe2(H2O)4(SeO3)2]

    Journal of Molecular Structure · 2005-03-03

    Dong‐Rong Xiao, Haiyan An, Enbo Wang, Lin Xu

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  11. Thallium(III) selenite, Tl2(SeO3)3

    Acta Crystallographica Section C Crystal Structure Communications · 2005-06-22

    William T. A. Harrison

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  12. Selenious Acid as a Ligand: Molecular and Crystal Structure of [Co(H2O)2Cl2(H2SeO3)2]

    Zeitschrift für anorganische und allgemeine Chemie · 2005-08-29

    Makram Ben Hamida, Mathias Siegfried Wickleder

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  13. Effective second-order nonlinearity in acentric optical crystals with low symmetry

    Applied Optics · 2005-11-10

    Pancho Tzankov, Valentin P. Petrov

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  14. Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2

    Journal of Solid State Chemistry · 2006-02-08

    Tyler A. Sullens, Philip M. Almond, Jessica A. Byrd, James V. Beitz, Travis H. Bray, Thomas E. Albrecht‐Schmitt

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  15. Synthesis, Structure, and Characterization of Novel Two- and Three-Dimensional Vanadates: Ba2.5(VO2)3(SeO3)4·H2O and La(VO2)3(TeO6)·3H2O

    Inorganic Chemistry · 2006-04-01

    T. Sivakumar, Kang Min Ok, P. Shiv Halasyamani

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  16. Nd5(AsO3)4Cl3: The First Oxo‐Arsenate(III)‐Chloride of the Lanthanides

    Zeitschrift für anorganische und allgemeine Chemie · 2006-10-01

    Makram Ben Hamida, Mathias Siegfried Wickleder

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  17. Synthesis and Crystal Structure of In(OH)(SeO3)

    Zeitschrift für anorganische und allgemeine Chemie · 2006-12-11

    B.M. Paterson, William T. A. Harrison

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  18. Selenium Oxoanion Compounds of Palladium(II)

    Inorganic Chemistry · 2007-06-12

    Jie Ling, Thomas E. Albrecht‐Schmitt

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  19. Syntheses, crystal structures and photoluminescence properties of three novel organically bonded indium selenates or selenites

    Journal of Solid State Chemistry · 2007-07-05

    Mei‐Ling Feng, Heng‐Yun Ye, Jiang‐Gao Mao

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  20. Two New Noncentrosymmetric Polar Oxides: Synthesis, Characterization, Second-Harmonic Generating, and Pyroelectric Measurements on TlSeVO5 and TlTeVO5

    Chemistry of Materials · 2007-08-21

    T. Sivakumar, Hong Chang, Jaewook Baek, P. Shiv Halasyamani

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  21. La4(Si5.2Ge2.8O18)(TeO3)4 and La2(Si6O13)(TeO3)2: Intergrowth of the lanthanum(III) tellurite layer with the XO4 (X=Si/Ge) tetrahedral layer

    Journal of Solid State Chemistry · 2007-12-05

    Fang Kong, Hai‐Long Jiang, Jiang‐Gao Mao

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  22. Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr3(SeO3)(Se2O5)Cl2 and Sr4(Te3O8)Cl4

    Journal of Solid State Chemistry · 2007-12-18

    Hai‐Long Jiang, Jiang‐Gao Mao

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  23. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

    Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, Alexander J. Norquist

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  24. New indium selenite-oxalate and indium oxalate with two- and three-dimensional structures

    Journal of Solid State Chemistry · 2008-10-16

    Junjun Cao, Guodong Li, Jie‐Sheng Chen

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  25. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

    Dalton Transactions · 2009-01-01

    Fang Kong, Chun‐Li Hu, Ting Hu, Yong Lian Zhou, Jiang‐Gao Mao

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  26. Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System

    Inorganic Chemistry · 2009-06-18

    Fang Kong, Qipu Lin, Fei‐Yan Yi, Jiang‐Gao Mao

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  27. Noncentrosymmetry in New Templated Gallium Fluorophosphates

    Inorganic Chemistry · 2009-10-28

    Sarah J. Choyke, Samuel M. Blau, A.A. Larner, Amy Narducci Sarjeant, Jeongho Yeon, P. Shiv Halasyamani, Alexander J. Norquist

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  28. The Role of Stereoactive Lone Pairs in Templated Vanadium Tellurite Charge Density Matching

    Inorganic Chemistry · 2010-05-11

    Kelvin B. Chang, Desmond J. Hubbard, Mat­thias Zeller, Joshua Schrier, Alexander J. Norquist

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  29. Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10

    Solid State Sciences · 2010-07-24

    Yongjiang Wang, Shilie Pan, Xueling Hou, Gang Yu Liu, Jide Wang, Dianzeng Jia

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  30. A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl

    Solid State Sciences · 2010-09-13

    Dong Woo Lee, Kang Min Ok

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  31. Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

    Inorganic Chemistry · 2010-11-23

    Suyun Zhang, Chun‐Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  32. A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems

    Dalton Transactions · 2011-01-01

    Qian-Hua Gu, Chun‐Li Hu, Jian‐Han Zhang, Jiang‐Gao Mao

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  33. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

    CrystEngComm · 2011-01-01

    Min Zhang, Shi-Lie Pan, Xiao-Yun Fan, Zhou Zhong-Xiang, Kenneth Reinhard Poeppelmeier, Yun Mo Yang

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  34. New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8

    Inorganic Chemistry · 2011-04-12

    Dong Woo Lee, Seung‐Jin Oh, P. Shiv Halasyamani, Kang Min Ok

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  35. Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites

    Inorganic Chemistry · 2011-04-28

    Suyun Zhang, Jiang‐Gao Mao

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  36. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  37. Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite

    Dalton Transactions · 2012-01-01

    Suyun Zhang, Chun‐Li Hu, Pei-Xin Li, Hai‐Long Jiang, Jiang‐Gao Mao

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  38. Explorations of new selenites of the group IIIA and IVA metals

    Journal of Solid State Chemistry · 2012-02-15

    Fang Kong, Pei-Xin Li, Suyun Zhang, Jiang‐Gao Mao

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  39. Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2012-07-16

    Dong Woo Lee, Saet Byeol Kim, Kang Min Ok

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  40. Synthesis, Band and Crystal Structures, and Optical Properties of the Ternary Compound Mg2Te3O8

    Zeitschrift für anorganische und allgemeine Chemie · 2012-11-20

    Wan‐Feng Lin, Qiu‐Ju Xing, Jun Ma, Jian‐Ping Zou, Si‐Liang Lei, Xubiao Luo, Guo‐Cong Guo

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  41. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

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  42. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

    Inorganic Chemistry · 2013-08-16

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  43. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

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    Yiseul Shin, Dong Woo Lee, Kwang‐Yong Choi, Hyun‐Joo Koo, Kang Min Ok

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  44. Cobalt selenium oxohalides: catalysts for water oxidation

    Dalton Transactions · 2014-01-01

    Faiz Rabbani, Henrik Svengren, Iwan Zimmermann, Shichao Hu, Tanja M. Laine, Wenming Hao, Björn Åkermark, Torbjörn Åkermark, Mats Johnsson

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  45. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

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  46. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

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  47. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

    Journal of Solid State Chemistry · 2014-09-30

    Hyun Sun Ahn, Eun Pyo Lee, Hong‐Young Chang, Dong Woo Lee, Kang Min Ok

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  48. Enhanced Second Harmonic Generation from an Organic Self-Assembled Eutectic Binary Mixture: A Case Study with 3-Nitrobenzoic and 3,5-Dinitrobenzoic Acids

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  49. Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B2Se3O10

    Inorganic Chemistry · 2015-02-19

    Michael Daub, Harald Scherer, Harald Hillebrecht

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  50. Variable dimensionality and framework found in a series of quaternary zinc selenites, A 2 Zn 3 (SeO 3 ) 4 · x H 2 O (A = Na, Rb, and Cs; 0≤ x ≤1) and Cs 2 Zn 2 (SeO 3 ) 3 ·2H 2 O

    Journal of Solid State Chemistry · 2016-10-07

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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