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RESEARCH PAPER · Accounts of Chemical Research · 2019

Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to Fluorooxoborates

Miriding Mutailipu, Min Zhang, Zhihua Yang, Shilie Pan

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Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to FluorooxoboratesOriginalA 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials98A new barium fluorooxoborate BaB 5 O 8 F· x H 2 O with large birefringence and a wide UV transparency window25A rich structural chemistry in π-conjugated hydroisocyanurates: layered structures of A 2 B(H 2 C 3 N 3 O 3 ) 4 · n H 2 O (A = K, Rb, Cs; B = Mg, Ca; n = 4, 10) with high ultraviolet transparency and strong optical anisotropy47Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge19Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks8K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19RE(H 2 C 3 N 3 O 3 ) 2 ·(OH)· x H 2 O (RE = La, Y and Gd): potential UV birefringent materials with strong optical anisotropy originating from the (H 2 C 3 N 3 O 3 ) − group31Redox-triggered switch based on platinum( ii ) acetylacetonate complexes bearing an isomeric donor–acceptor conjugation ligand shows a high second-order nonlinear optical response16Structural insights into three phosphates with distinct polyanionic configurations20Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Large third-order optical nonlinearity and ultrafast optical response in thin Au nanodisks6Laser stimulated second and third harmonic optical effects in F: SnO2 nanostructures grown via chemical synthetic route9Fluorine-Mediated Benzothiadiazole Derivatives for Second-Order Nonlinear Optics2Experiment and First-Principles Calculations of A2Mg2TeB2O10 (A = Pb, Ba): Influences of the Cosubstitution on the Structure Transformation and Optical Properties21Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)33BaCuSiTe 3 : A Noncentrosymmetric Semiconductor with CuTe 4 Tetrahedra and Ethane-like Si 2 Te 6 Units11Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family32Morphologically controlled synthesis, characterization and application of zinc-aluminum layered double hydroxide nano needles23K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17Histidinium‐Driven Chirality Control of Self‐Assembled Hybrid Molybdenum Oxyfluorides24First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals299KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 483CsAlB 3 O 6 F: a beryllium-free deep-ultraviolet nonlinear optical material with enhanced thermal stability153β-Ba(PO3)2 with DUV cut-off edge and large birefringence5Transformation of Optical Anisotropy Origins in Perovskite-Related Materials: A First-Principles Study23An unprecedented planar π-conjugated [B 2 P 5 ] 5− group with ultra-large birefringence and nonlinearity: an ab initio study17K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior11A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains62(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation78Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20Coinage metalides: a new class of excess electron compounds with high stability and large nonlinear optical responses36Diketopyrrolopyrrole based donor–acceptor π-conjugated copolymers with near-infrared absorption for 532 and 1064 nm nonlinear optical materials45Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook145K 2.64 Cs 0.36 SiF 7 : a new fluorosilicate with a trans -perovskite structure3Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5NaK 15 [B 4 O 5 (OH) 4 ] 6 (NO 2 ) 2 (CO 3 )·7H 2 O: assembly of an unprecedented mixed anion inorganic compound via a facile hydrothermal route4Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties11Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25Prediction of ternary fluorooxoborates with coplanar triangular units [BO x F 3−x ] x− from first-principles13Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11RbB 3 O 4 F 2 : a rubidium fluorooxoborate with an unprecedented [B 3 O 5 F 2 ] 3− functionalized unit and a large birefringence37Second-order nonlinear optical materials with a benzene-like conjugated π system49Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edges26A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance15Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44Density Functional Theory Investigation of Nonlinear Optical Properties of T-Graphene Quantum Dots112CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges26PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates14A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster33The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8Shilie Pan0Shilie Pan0Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window2Designing a Deep-UV Nonlinear Optical Fluorooxosilicophosphate127NLO activity analysis and spectroscopic investigation on electro-optic and physico-chemical properties of organic complex; N-benzyloxycarbonyl-L-Aspartic acid0The influence of different factors on exploitation properties of nonlinear optical polymeric materials based on an epoxy matrix doped with flavonoids5A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)30A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)86Solvent induced enhancement of nonlinear optical response of graphdiyne31KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Partial Isovalent Anion Substitution to Access Remarkable Second-Harmonic Generation Response: A Generic and Effective Strategy for Design of Infrared Nonlinear Optical Materials114New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units63AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides113LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap39Realizing Deep-Ultraviolet Second Harmonic Generation by First-Principles-Guided Materials Exploration in Hydroxyborates111A 2 Bi 2 (SeO 3 ) 3 F 2 (A = K and Rb): Excellent Mid-Infrared Nonlinear Optical Materials with Both Strong SHG Responses and Large Band Gaps64Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Comparative study of structural, optical and magnetic properties of Er3+ doped yttrium gallium borates9Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12Quantitative Polarization‐Resolved Second‐Harmonic‐Generation Microscopy of Glycine Microneedles18Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Na4CdGe2S7: A Sodium-Rich Quaternary Wide-Band-Gap Chalcogenide with Two-Dimensional [Ge2CdS7]∞ Layers6Role of Fluorooxo-Functional Units in Symmetry Breaking and Second Harmonic Generation Response Contribution in Fluorooxoborate Nonlinear Optical Crystals15Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups26Temperature-dependent behaviours of electro-elastic constants for the Bi 2 ZnB 2 O 7 piezoelectric crystal5Layered oxide B2S2O9 with a deep-ultraviolet band gap and a strong and robust second-harmonic generation32Switchable NLO response induced by rotation of the fulvalene diruthenium-linked polyoxometalate derivatives4Crystal growth, characterization and theoretical studies of the noncentrosymmetric compound Al3(IO3)9·(HIO3)6·18H2O4Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response12Borates: A Rich Source for Optical Materials1089Predicting Berborite as Potential Deep-Ultraviolet Nonlinear Optical Crystal from First Principles29Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42A review on the recently developed promising infrared nonlinear optical materials103Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117Competing hydrogen-bonding interactions in a high- T c organic molecular-ionic crystal with evident nonlinear optical response2Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization28Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2Electroluminescent materials toward near ultraviolet region149From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)9Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20M(B(SeO 3 ) 3 )H 2 O (M = Al, Ga): the first boroselenites with a unique sandwich like double-layer structure9NaKB 6 O 9 F 2 : a new complex alkali metal fluorooxoborate with puckered layers10Novel noncentrosymmetric polar coordination compounds derived from chiral histidine ligands36Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure6RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9Recent advances of oxyfluorides for nonlinear optical applications69Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23To improve the key properties of nonlinear optical crystals assembled with tetrahedral functional building units46Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence142M(NH 2 SO 3 ) 2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence27New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2Finding Short-Wavelength Birefringent Crystals with Large Optical Anisotropy Activated by π-Conjugated [C(NH2)3] Units45Different mechanism of stereochemical activity and birefringence in post-transition metal halides: A first-principles investigation1A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Toward the Enhancement of Critical Performance for Deep-Ultraviolet Frequency-Doubling Crystals Utilizing Covalent Tetrahedra137Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials111Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application167Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application18Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point18CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Expanding the chemistry of borates with functional [BO2]− anions200Deep‐Ultraviolet Nonlinear‐Optical van‐der‐Waals Beryllium Borates**6Sr2Nb6O13F8·4H2O and Sr3Nb2O2F12·2H2O: A Variant of Three-Dimensional Tungsten Bronze and a Polar Molecular Oxide Fluoride17

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  1. A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials

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  2. A new barium fluorooxoborate BaB 5 O 8 F· x H 2 O with large birefringence and a wide UV transparency window

    Dalton Transactions · 2019-01-01

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  3. A rich structural chemistry in π-conjugated hydroisocyanurates: layered structures of A 2 B(H 2 C 3 N 3 O 3 ) 4 · n H 2 O (A = K, Rb, Cs; B = Mg, Ca; n = 4, 10) with high ultraviolet transparency and strong optical anisotropy

    Dalton Transactions · 2019-01-01

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  4. Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2019-01-01

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  5. Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+

    Chemical Communications · 2019-01-01

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  6. K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks

    New Journal of Chemistry · 2019-01-01

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  7. K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal

    Chemical Communications · 2019-01-01

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  8. LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution

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  9. Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method

    Dalton Transactions · 2019-01-01

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  10. Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Fei Liang, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Zheshuai Lin, Yanjun Li

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  11. RE(H 2 C 3 N 3 O 3 ) 2 ·(OH)· x H 2 O (RE = La, Y and Gd): potential UV birefringent materials with strong optical anisotropy originating from the (H 2 C 3 N 3 O 3 ) − group

    Dalton Transactions · 2019-01-01

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  12. Redox-triggered switch based on platinum( ii ) acetylacetonate complexes bearing an isomeric donor–acceptor conjugation ligand shows a high second-order nonlinear optical response

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  13. Structural insights into three phosphates with distinct polyanionic configurations

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  14. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

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  15. BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge

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  16. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

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  17. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

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  18. Large third-order optical nonlinearity and ultrafast optical response in thin Au nanodisks

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  19. Laser stimulated second and third harmonic optical effects in F: SnO2 nanostructures grown via chemical synthetic route

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  20. Fluorine-Mediated Benzothiadiazole Derivatives for Second-Order Nonlinear Optics

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  21. Experiment and First-Principles Calculations of A2Mg2TeB2O10 (A = Pb, Ba): Influences of the Cosubstitution on the Structure Transformation and Optical Properties

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  22. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

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  23. Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)

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  24. BaCuSiTe 3 : A Noncentrosymmetric Semiconductor with CuTe 4 Tetrahedra and Ethane-like Si 2 Te 6 Units

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  27. K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound

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  28. Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)

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  29. Histidinium‐Driven Chirality Control of Self‐Assembled Hybrid Molybdenum Oxyfluorides

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  30. First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals

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  31. KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 4

    Chemistry of Materials · 2019-11-01

    Zhiyong Bai, Chun‐Li Hu, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  32. CsAlB 3 O 6 F: a beryllium-free deep-ultraviolet nonlinear optical material with enhanced thermal stability

    Chemical Science · 2019-11-05

    Hongkun Liu, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  33. β-Ba(PO3)2 with DUV cut-off edge and large birefringence

    Materials Letters · 2019-11-26

    Na Li, Xuefang Lu, Qun Jing, Ping Wei, Lu Qi, Zhongqi Jiang, Zhaohui Chen

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  34. Transformation of Optical Anisotropy Origins in Perovskite-Related Materials: A First-Principles Study

    The Journal of Physical Chemistry C · 2019-12-03

    Tinghao Tong, Ming‐Hsien Lee, Jun Zhang

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  35. An unprecedented planar π-conjugated [B 2 P 5 ] 5− group with ultra-large birefringence and nonlinearity: an ab initio study

    Chemical Communications · 2019-12-04

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  36. K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold

    Chemistry of Materials · 2019-12-04

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  37. (NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior

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  38. (NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior

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  39. A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals

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  40. Emergent Deep‐Ultraviolet Nonlinear Optical Candidates

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  41. Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich

    Angewandte Chemie · 2019-12-10

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  42. [O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains

    Dalton Transactions · 2020-01-01

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  43. 2(C 3 H 7 N 6 ) + ·2Cl − ·H 2 O: an ultraviolet nonlinear optical crystal with large birefrigence and strong second-harmonic generation

    Chemical Communications · 2020-01-01

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  44. Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra

    Chemical Communications · 2020-01-01

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  45. Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material

    Dalton Transactions · 2020-01-01

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  46. Coinage metalides: a new class of excess electron compounds with high stability and large nonlinear optical responses

    Physical Chemistry Chemical Physics · 2020-01-01

    Xianghui Li, Xiaoling Zhang, Qiaohong Chen, Li Zhang, Jinghua Chen, Di Wu, Wei‐Ming Sun, Zhi‐Ru Li

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  47. Diketopyrrolopyrrole based donor–acceptor π-conjugated copolymers with near-infrared absorption for 532 and 1064 nm nonlinear optical materials

    Journal of Materials Chemistry C · 2020-01-01

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  48. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

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  49. Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook

    Inorganic Chemistry Frontiers · 2020-01-01

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  50. K 2.64 Cs 0.36 SiF 7 : a new fluorosilicate with a trans -perovskite structure

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