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RESEARCH PAPER · Dalton Transactions · 2019

RE(H 2 C 3 N 3 O 3 ) 2 ·(OH)· x H 2 O (RE = La, Y and Gd): potential UV birefringent materials with strong optical anisotropy originating from the (H 2 C 3 N 3 O 3 ) − group

Xia Hao, Min Luo, Chensheng Lin, Donghong Lin, Liling Cao, Ning Ye

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RE(H 2 C 3 N 3 O 3 ) 2 ·(OH)· x H 2 O (RE = La, Y and Gd): potential UV birefringent materials with strong optical anisotropy originating from the (H 2 C 3 N 3 O 3 ) − groupOriginalLiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates44How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates327RbNa(HC 3 N 3 O 3 )·2H 2 O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material69Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy47A 2 Bi 2 (SeO 3 ) 3 F 2 (A = K and Rb): Excellent Mid-Infrared Nonlinear Optical Materials with Both Strong SHG Responses and Large Band Gaps64Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence13Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units17Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials111AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large Birefringence22Synthesis and Characterization of New-Type Ionic Cocrystals with Cyanuric Acid and Alkali Halides: AX·(H3C3N3O3)2 (A = Rb, Cs; X = Cl, Br)6K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence10From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement26Potential optical functional crystals with large birefringence: Recent advances and future prospects322Revealing Electron–Phonon Coupling Dependence on the π-Conjugated Groups in Rare-Earth Borates6A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals33Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence91Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence18Explorations of Second-Order Nonlinear Optical Materials in the Monovalent Trithiocyanurate System18C 10 H 6 NO 2 Cd(NO 3 )·2H 2 O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection4Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure7Ultrastable 3D cage-like metal–organic frameworks constructed using polydentate cyanurate ligands and their gas adsorption properties6Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate19[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60(C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems5La 2 (CN 2 ) 3 – the missing link of rare-earth carbodiimides, prepared through an efficient synthetic route and its Ce 3+ activated photoluminescence5An alkali and rare earth metal mixed cyanurate KLa2(C3N3O3)2Cl with large birefringence: Synthesis and characterization2Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations2Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence2

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  1. LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates

    Inorganic Chemistry Frontiers · 2019-01-01

    Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Wenlong Yin, Tixian Zeng, Bin Kang, Zheshuai Lin, Mingjun Xia

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  2. How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates

    Journal of the American Chemical Society · 2019-09-12

    Jing Lu, Yu‐Kun Lian, Lin Xiong, Qianru Wu, Min Zhao, Ke-Xin Shi, Ling Chen, Li‐Ming Wu

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  3. RbNa(HC 3 N 3 O 3 )·2H 2 O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material

    Inorganic Chemistry Frontiers · 2019-10-14

    Yunxia Song, Donghong Lin, Min Luo, Chensheng Lin, Qiaoling Chen, Ning Ye

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  4. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  5. A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy

    Inorganic Chemistry · 2020-06-28

    Xia Hao, Min Luo, Chensheng Lin, Guang Peng, Tao Yan, Donghong Lin, Liling Cao, Xifa Long, Guangsai Yang, Ning Ye

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  6. A 2 Bi 2 (SeO 3 ) 3 F 2 (A = K and Rb): Excellent Mid-Infrared Nonlinear Optical Materials with Both Strong SHG Responses and Large Band Gaps

    Chemistry of Materials · 2020-08-21

    Shuangshuang Shi, Chensheng Lin, Guangsai Yang, Liling Cao, Bingxuan Li, Tao Yan, Min Luo, Ning Ye

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  7. Co-crystal AX·(H 3 C 3 N 3 O 3 ) (A = Na, Rb, Cs; X = Br, I): a series of strongly anisotropic alkali halide cyanurates with a planar structural motif and large birefringence

    Dalton Transactions · 2021-01-01

    Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

    Read original paper ↗ ·

  8. Two metal-free cyanurate crystals with a large optical birefringence resulting from the combination of π-conjugated units

    Dalton Transactions · 2021-01-01

    Xiaomeng Liu, Lei Kang, Ruixin Guo, Zheshuai Lin

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  9. Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials

    Coordination Chemistry Reviews · 2021-04-14

    Xianghe Meng, Wenlong Yin, Mingjun Xia

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  10. AZn4(OH)4(C3N3O3)2 (A = Mg, Zn): Two Zn-Based Cyanurate Crystals with Various Cation Coordination and Large Birefringence

    Inorganic Chemistry · 2021-07-16

    Xiaomeng Liu, Pifu Gong, Zheshuai Lin

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  11. Synthesis and Characterization of New-Type Ionic Cocrystals with Cyanuric Acid and Alkali Halides: AX·(H3C3N3O3)2 (A = Rb, Cs; X = Cl, Br)

    Crystal Growth & Design · 2021-11-19

    Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  12. K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yingshuang Sun, Chensheng Lin, Shenghao Fang, Haotian Tian, Ning Ye, Min Luo

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  13. From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement

    Inorganic Chemistry · 2022-01-11

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Yilin Li, Jiang‐Gao Mao

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  14. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  15. Revealing Electron–Phonon Coupling Dependence on the π-Conjugated Groups in Rare-Earth Borates

    Crystal Growth & Design · 2022-02-22

    Fangyan Wang, Fei Liang, Xinyuan Zhang, Dazhi Lu, Haohai Yu, Huaijin Zhang, Jiyang Wang, Yicheng Wu

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  16. A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

    Chemistry of Materials · 2022-04-07

    Yingshuang Sun, Chensheng Lin, Haotian Tian, Yuqiao Zhou, Jindong Chen, Shunda Yang, Ning Ye, Min Luo

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  17. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

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  18. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

    Angewandte Chemie International Edition · 2022-11-08

    Xianghe Meng, Xingyu Zhang, Qingxiong Liu, Zhengyang Zhou, Xingxing Jiang, Yonggang Wang, Zheshuai Lin, Mingjun Xia

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  19. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

    Angewandte Chemie · 2022-11-08

    Xianghe Meng, Xingyu Zhang, Qingxiong Liu, Zhengyang Zhou, Xingxing Jiang, Yonggang Wang, Zheshuai Lin, Mingjun Xia

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  20. Explorations of Second-Order Nonlinear Optical Materials in the Monovalent Trithiocyanurate System

    Crystal Growth & Design · 2022-12-01

    Xia Hao, Chensheng Lin, Ning Ye, Donghong Lin, Dan Zhao, Yuqiao Zhou, Enbo Shangguan, Min Luo

    Read original paper ↗ ·

  21. C 10 H 6 NO 2 Cd(NO 3 )·2H 2 O: a birefringent crystal with an enlarged band-gap derived from covalent edge-sharing connection

    Dalton Transactions · 2023-01-01

    Yu Wang, Yaoguo Shen, Weiqi Huang, Sangen Zhao

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  22. Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure

    Dalton Transactions · 2023-01-01

    Lehui Liu, Feifei Yuan, Yisheng Huang, Zhoubin Lin, Lizhen Zhang

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  23. Ultrastable 3D cage-like metal–organic frameworks constructed using polydentate cyanurate ligands and their gas adsorption properties

    Dalton Transactions · 2023-01-01

    Wenhao Xing, Kaijin Kang, Jian Tang, Chunlan Tang, Wenlong Yin, Bin Kang, Jianguo Deng

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  24. Cs 2 Mg(H 2 C 3 N 3 S 3 ) 4 ·8H 2 O: An Excellent Birefringent Material with Giant Optical Anisotropy in π-Conjugated Trithiocyanurate

    Inorganic Chemistry · 2023-05-11

    Xia Hao, Chensheng Lin, Min Luo, Yuqiao Zhou, Ning Ye, Enbo Shangguan

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  25. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  26. (C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems

    Inorganic Chemistry · 2024-05-10

    Mingliang Ding, Qiong Sen Wu, Yaoguo Shen, Jinquan Hong, Guofa Dong, Liang Ma

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  27. La 2 (CN 2 ) 3 – the missing link of rare-earth carbodiimides, prepared through an efficient synthetic route and its Ce 3+ activated photoluminescence

    Dalton Transactions · 2025-01-01

    Philipp Schneiderhan, Elaheh Bayat, Markus Ströbele, David Enseling, Thomas Jüstel, Hans‐Jürgen Meyer

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  28. An alkali and rare earth metal mixed cyanurate KLa2(C3N3O3)2Cl with large birefringence: Synthesis and characterization

    Solid State Communications · 2025-02-05

    N.F. Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  29. Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations

    Crystal Growth & Design · 2025-05-22

    Xia Hao, Xuan Liu, Ruijie Wang, Chensheng Lin, Min Luo, Guang Peng, Tao Yan, Ning Ye

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  30. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  31. A one-pot method in water to synthesize a new cyanurate K(H 2 C 3 N 3 O 3 )·H 2 O with large birefringence

    Dalton Transactions · 2025-11-17

    Bingheng Ji, Chu Chu, Bingbing Zhang, Jian Wang

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