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RESEARCH PAPER · Crystal Growth & Design · 2019

Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family

Yangwu Guo, Fei Liang, Zhuang Li, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like FamilyOriginalRational design of infrared nonlinear optical chalcogenides by chemical substitution287HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure146Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties14Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap214Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap16Highly Distorted [HgS 4 ] Motif-Driven Structural Symmetry Degradation and Strengthened Second-Harmonic Generation Response in the Defect Diamond-Like Chalcogenide Hg 3 P 2 S 8473D bicontinuous diamond-like morphologies in thin films of soluted block copolymers1Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se720Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Hg-based chalcogenides: An intriguing class of infrared nonlinear optical materials129Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design28Achieving a strong second harmonic generation response and a wide band gap in a Hg-based material41Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12AgGaSe2-Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury34Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response27Crystal structure, electronic structure, and optical properties of the novel Li 4 CdGe 2 S 7 , a wide-bandgap quaternary sulfide with a polar structure derived from lonsdaleite6Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy37Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12The Kurtz–Perry Powder Technique Revisited: A Study of the Effect of Reference Selection on Powder Second-Harmonic Generation Response20Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results24Synthesis, Crystal Structure, and Nonlinear-Optical Properties of a Diamond-Like Chalcogenide Cu 2 GeS 313Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation10Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury–Tellurostannate Hybrids with Transition-Metal Complexes4Infrared nonlinear optical materials with multiple strongly ionic cations5K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5Partial congener substitution induced wide band gap witnessed in diamond-like chalcogenide ZnHg 2 P 2 S 8 and its second-order nonlinear optical properties3Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals15First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg 3 P 2 S 80

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  1. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  2. HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure

    Chemistry of Materials · 2020-04-24

    Mengyue Li, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  4. SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2021-02-26

    Xin Pang, Ruiqi Wang, Xiangli Che, Fuqiang Huang

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  5. Li 4 MgGe 2 S 7 : The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

    Angewandte Chemie International Edition · 2021-07-24

    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  6. Li4MgGe2S7: The First Alkali and Alkaline‐Earth Diamond‐Like Infrared Nonlinear Optical Material with Exceptional Large Band Gap

    Angewandte Chemie · 2021-07-24

    Ailijiang Abudurusuli, Junben Huang, Peng Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  7. Highly Distorted [HgS 4 ] Motif-Driven Structural Symmetry Degradation and Strengthened Second-Harmonic Generation Response in the Defect Diamond-Like Chalcogenide Hg 3 P 2 S 8

    ACS Applied Materials & Interfaces · 2021-07-28

    Wenhao Xing, Fei Liang, Chunlan Tang, Ece Uykur, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  8. 3D bicontinuous diamond-like morphologies in thin films of soluted block copolymers

    The Journal of Chemical Physics · 2021-08-04

    Yury Anatolievich Kriksin

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  9. Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se7

    Journal of Alloys and Compounds · 2021-08-09

    Charles W. Sinagra, Felix O. Saouma, Calford Odhiambo Otieno, Saul H. Lapidus, Jian‐Han Zhang, Andrew J. Craig, P. Grima, Jacilynn A. Brant, Kimberly A. Rosmus, Kate E. Rosello, Joon Ik Jang, Jennifer A. Aitken

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  10. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  11. Hg-based chalcogenides: An intriguing class of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-12-09

    Chunxiao Li, Xianghe Meng, Zhuang Li, Jiyong Yao

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  12. Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design

    Journal of Materials Chemistry C · 2021-12-15

    Chunlan Tang, Wenhao Xing, Fei Liang, Mengran Sun, Jian Tang, Zheshuai Lin, Jiyong Yao, Kaixin Chen, Jieyun Wu, Wenlong Yin, Bin Kang

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  13. Achieving a strong second harmonic generation response and a wide band gap in a Hg-based material

    Inorganic Chemistry Frontiers · 2022-01-01

    Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  14. Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties

    Inorganic Chemistry · 2022-01-26

    Bingheng Ji, Kui Wu, Yunhua Chen, Fei Wang, Aaron J. Rossini, Bingbing Zhang, Jian Wang

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  15. AgGaSe2-Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury

    Chemistry of Materials · 2022-06-26

    Lihua Gao, Jingjing Xu, Xinyu Tian, Bingbing Zhang, Xiaowen Wu, Kui Wu

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  16. Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response

    Inorganic Chemistry · 2022-08-10

    Xiao Fen Huang, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

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  17. Crystal structure, electronic structure, and optical properties of the novel Li 4 CdGe 2 S 7 , a wide-bandgap quaternary sulfide with a polar structure derived from lonsdaleite

    Acta Crystallographica Section C Structural Chemistry · 2022-08-22

    Andrew J. Craig, Seung Han Shin, Jeong Bin Cho, Srikanth Balijapelly, Jordan C. Kelly, Stanislav S. Stoyko, Amitava Choudhury, Joon Ik Jang, Jennifer A. Aitken

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  18. Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy

    Science China Materials · 2022-09-23

    Wen‐Fa Chen, Xiao‐Ming Jiang, Shao‐Min Pei, Ming‐Shu Zhang, Bin‐Wen Liu, Guo‐Cong Guo

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  19. Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

    Dalton Transactions · 2023-01-01

    Xiao-Yu Lou, Yu Zhou, Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  20. The Kurtz–Perry Powder Technique Revisited: A Study of the Effect of Reference Selection on Powder Second-Harmonic Generation Response

    Molecules · 2023-01-22

    Mengran Sun, Guili Wang, Jiyong Yao

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  21. Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results

    Chemistry of Materials · 2023-01-24

    Wen‐Dong Yao, Xiyue Cheng, Sheng‐Ping Guo, Myung‐Hwan Whangbo, Bohan Ding, Shuiquan Deng

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  22. Synthesis, Crystal Structure, and Nonlinear-Optical Properties of a Diamond-Like Chalcogenide Cu 2 GeS 3

    Inorganic Chemistry · 2023-06-29

    Xianghe Meng, Pifu Gong, Jinlong Shi, Chunxiao Li, Zheshuai Lin, Jiyong Yao

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  23. Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation

    Journal of Alloys and Compounds · 2023-10-06

    Jordan C. Kelly, Chad E. Hoyer, Seung Han Shin, Jeong Bin Cho, Stanislav S. Stoyko, Allyson Bonnoni, Andrew J. Craig, Kate E. Rosello, Evan T. O’Hara, Joon Ik Jang, Jennifer A. Aitken

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  24. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

    Ziting Yan, Jinbin Fan, Shilie Pan, Min Zhang

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  25. Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury–Tellurostannate Hybrids with Transition-Metal Complexes

    Inorganic Chemistry · 2024-04-01

    Xiao Yang, Taohong Ren, Hongjin Zhu, Dingxian Jia

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  26. Infrared nonlinear optical materials with multiple strongly ionic cations

    Progress in Solid State Chemistry · 2024-04-01

    Yang Wang, Yuqiang Fang, Ruiqi Wang, Fuqiang Huang

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  27. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  28. Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds

    Dalton Transactions · 2025-01-01

    Guili Wang, Bohui Xu, Chunxiao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao

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  29. Partial congener substitution induced wide band gap witnessed in diamond-like chalcogenide ZnHg 2 P 2 S 8 and its second-order nonlinear optical properties

    Dalton Transactions · 2025-01-01

    Chunlan Tang, Aoge Yao, Wenhao Xing, Jian Tang, Lei Kang, Wenlong Yin, Jieyun Wu, Bin Kang

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  30. Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response

    Dalton Transactions · 2026-01-01

    Qixian Ren, Junwei Feng, Longquan Shao, Meihuizi Zhou, Chen Cui, Yabo Wu

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  31. Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals

    Coordination Chemistry Reviews · 2026-02-02

    Ailijiang Abudurusuli, Linan Wang, Junben Huang, Xueling Hou, Miriding Mutailipu, Shilie Pan, Junjie Li

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  32. First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg 3 P 2 S 8

    Advanced Physics Research · 2026-07-23

    Saravana Karthikeyan SKS, Sankar Ganesh Ramaraj, Ryo Watanabe, Choji Fukuhara, Chang Yi Kong

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