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RESEARCH PAPER · Inorganic Chemistry · 2019

Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

Eun Jeong Cho, Seung‐Jin Oh, Hongil Jo, Junsu Lee, Tae‐Soo You, Kang Min Ok

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Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic PropertiesOriginalCs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges16Nitrate nonlinear optical crystals: A survey on structure-performance relationships146[NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties4Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material25A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters50Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response63Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Cs3B3O3F6 with a Deep-Ultraviolet Cutoff Edge and a Suitable Birefringence as the Potential Zero-Order Waveplate Material31Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph31Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)315Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4Turning UV Light-Active BiOF into Visible Light-Active BiOF by Forming a Heterojunction with g-C3N4 and Its Photoelectrochemical Water Splitting Performance in Reverse Osmosis-Rejected Wastewater35Metal oxyhalides: an emerging family of nonlinear optical materials124Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40Hybrid Germanium Bromide Perovskites with Tunable Second Harmonic Generation122Hybrid Germanium Bromide Perovskites with Tunable Second Harmonic Generation8Enhanced Second-Harmonic-Generation Response in a KH2PO4-Type Calcium Nitrate Carboxylate with Unusual Three-Dimensional Inorganic and Organic Connections3Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution42D Bismuth Oxyfluorides: A New Member of Cationic Nanosheets1Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Towards the design of oxychalcogenide materials as candidates for solar water- splitting photocatalysis0Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range44Recent advances in bismuth oxyfluoride-based photocatalysts for energy and environmental remediation22The doping effect on the linear and nonlinear optical behaviors of nickel oxide films for multiple optoelectronic applications21Synthesis Methods of Mixed-anion Compounds0Synthesis Methods of Mixed-anion Compounds1Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media9Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations17Exploiting Rigid Inorganic π‐Conjugated Units and Deprotonatable Organic π‐Conjugated Dimers for Enhanced Linear and Nonlinear Optical Properties9A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5

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  1. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  2. Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+

    Chemical Communications · 2019-01-01

    Kang Min Ok

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  3. Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation

    Dalton Transactions · 2019-01-01

    Shujuan Han, Hao Li, Zhihua Yang, Hao Yu, Shilie Pan

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  4. K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges

    Inorganic Chemistry · 2019-05-01

    Xueyan Zhang, Hongping Wu, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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  5. Nitrate nonlinear optical crystals: A survey on structure-performance relationships

    Coordination Chemistry Reviews · 2019-09-10

    Xiaomeng Liu, Pifu Gong, Yi Jin Yang, Gaomin Song, Zheshuai Lin

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  6. [NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties

    Inorganica Chimica Acta · 2019-10-08

    Zhongqi Jiang, Wenqiang Chen, Qun Jing, Ming‐Hsien Lee, Zhaohui Chen

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  7. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  8. Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material

    Chemical Science · 2020-01-01

    Guang Peng, Yi Jin Yang, Tao Yan, Dan Zhao, Bingxuan Li, Ge Zhang, Zheshuai Lin, Ning Ye

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  9. A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters

    Inorganic Chemistry · 2020-05-22

    Xuehua Dong, Ying Long, Xiaoyu Zhao, Ling Huang, Hongmei Zeng, Zhien Lin, Xin Wang, Guohong Zou

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  10. Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2020-07-01

    Jee Yoon Chung, Hongil Jo, Seongbeom Yeon, Hye Ryung Byun, Tae‐Soo You, Joon Ik Jang, Kang Min Ok

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  11. Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)

    Journal of Alloys and Compounds · 2020-08-28

    Hye‐Eun Lee, Hongil Jo, Min Hyung Lee, Kang Min Ok

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  12. Cs3B3O3F6 with a Deep-Ultraviolet Cutoff Edge and a Suitable Birefringence as the Potential Zero-Order Waveplate Material

    Inorganic Chemistry · 2020-09-11

    Meng Cheng, Wenqi Jin, Zhihua Yang, Shilie Pan

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  13. Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Lei Wang, Hongmei Wang, Die Zhang, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  14. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

    European Journal of Inorganic Chemistry · 2021-02-13

    Qiqi Zhang, Fangfang Zhang, Fuming Li, Shujuan Han, Zhihua Yang, Shilie Pan

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  15. Order and Disorder: Toward the Thermodynamically Stable α-BaMoO2F4 from the Metastable Polymorph

    Chemistry of Materials · 2021-02-25

    Hongil Jo, Min Hyung Lee, Kang Min Ok

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  16. Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)3

    Journal of Alloys and Compounds · 2021-11-11

    Jee Yoon Chung, Seongbeom Yeon, Hongsun Ryu, Tae‐Soo You, Joon Ik Jang, Kang Min Ok

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  17. Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

    Dalton Transactions · 2021-12-20

    Huaiyu Hu, Junben Huang, Zhiyong Guo, Min Zhang, Zhihua Yang, Shilie Pan

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  18. Turning UV Light-Active BiOF into Visible Light-Active BiOF by Forming a Heterojunction with g-C3N4 and Its Photoelectrochemical Water Splitting Performance in Reverse Osmosis-Rejected Wastewater

    The Journal of Physical Chemistry C · 2021-12-29

    Vinoth Selvaraj, Alagarsamy Pandikumar

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  19. Metal oxyhalides: an emerging family of nonlinear optical materials

    Chemical Science · 2022-01-01

    Xinglong Chen, Kang Min Ok

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  20. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  21. Hybrid Germanium Bromide Perovskites with Tunable Second Harmonic Generation

    Angewandte Chemie International Edition · 2022-08-31

    Yang Liu, Ya-Ping Gong, Shining Geng, Mei‐Ling Feng, Despoina Manidaki, Zeyu Deng, Constantinos C. Stoumpos, Pieremanuele Canepa, Zewen Xiao, Wei‐Xiong Zhang, Lingling Mao

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  22. Hybrid Germanium Bromide Perovskites with Tunable Second Harmonic Generation

    Angewandte Chemie · 2022-08-31

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  23. Enhanced Second-Harmonic-Generation Response in a KH2PO4-Type Calcium Nitrate Carboxylate with Unusual Three-Dimensional Inorganic and Organic Connections

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    Shuxian Guo, Xuehua Dong, Lindong Luan, Hongmei Zeng, Guohong Zou, Zhien Lin

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  24. Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 2

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  25. Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution

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  26. 2D Bismuth Oxyfluorides: A New Member of Cationic Nanosheets

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  27. Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence

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  28. Towards the design of oxychalcogenide materials as candidates for solar water- splitting photocatalysis

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  29. Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range

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  30. Recent advances in bismuth oxyfluoride-based photocatalysts for energy and environmental remediation

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  31. The doping effect on the linear and nonlinear optical behaviors of nickel oxide films for multiple optoelectronic applications

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  32. Synthesis Methods of Mixed-anion Compounds

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  33. Synthesis Methods of Mixed-anion Compounds

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  34. Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media

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  35. Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations

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  37. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

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