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RESEARCH PAPER · Chemical Science · 2020

Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material

Guang Peng, Yi Jin Yang, Tao Yan, Dan Zhao, Bingxuan Li, Ge Zhang, Zheshuai Lin, Ning Ye

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Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional materialOriginalBa 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics26Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12Complex coordinated functional groups: A great genes for nonlinear optical materials64Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering28PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties57ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)10Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response4Recent advances in F-containing iodate nonlinear optical materials6Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions5A survey of stereoactive oxysalts for linear and nonlinear optical applications40Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Promoting NIR‐Driven Luminescence Activity of Calcium zinc galliumate via Energy Transfer from Mn4+ to Ho3+ for Second Biological Window3Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates0Multifactorial directed regulation of anionic units in praseodymium-contained iodates1Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1Two {B 6 }-Based Borates: From 1D Chain to 3D Framework1

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  1. Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution

    Chemical Communications · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yu Huang, Jiang‐Gao Mao

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  2. From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics

    Journal of Materials Chemistry C · 2021-01-01

    Tianhui Wu, Xingxing Jiang, Chao Wu, Hongyuan Sha, Zujian Wang, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  3. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  4. A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance

    Chemistry of Materials · 2021-04-07

    Xiaohan Zhang, Bing‐Ping Yang, Chun‐Li Hu, Jin Chen, Q. Huang, Jiang‐Gao Mao

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  5. M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion

    Crystal Growth & Design · 2021-11-18

    Yiyi Xu, Yuqiao Zhou, Chensheng Lin, Bingxuan Li, Xia Hao, Ning Ye, Min Luo

    Read original paper ↗ ·

  6. Complex coordinated functional groups: A great genes for nonlinear optical materials

    Chinese Chemical Letters · 2021-12-03

    Weikang Wang, Dajiang Mei, Shaoguo Wen, Jian Wang, Yuandong Wu

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  7. Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

    Chemical Communications · 2022-01-01

    Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

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  8. Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering

    Chemical Science · 2022-01-01

    Yilei Hu, Xingxing Jiang, Tianhui Wu, Yanyan Xue, Chao Wu, Zhipeng Huang, Zheshuai Lin, Jun Qiang Xu, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  9. PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties

    Inorganic Chemistry · 2022-09-19

    Ying‐Jie Jia, Xingyu Zhang, Xingyu Zhang, Yi-Gang Chen, Xingxing Jiang, Jia-Neng Song, Zheshuai Lin, Xian‐Ming Zhang, Xian‐Ming Zhang

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  10. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  11. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  12. A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)

    Dalton Transactions · 2023-01-01

    Xueying Zhang, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

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  13. Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response

    Journal of Materials Chemistry C · 2023-01-01

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  14. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  15. Single-Crystalline Li2Sn(IO3)6 Microwires: Combining Optical-Waveguiding and Frequency-Doubling Functions

    Inorganic Chemistry · 2023-06-05

    Xiang Xu, Bowen Chen, Bowen Chen, Chan Zheng, Li Huang, Bigeng Chen, Bigeng Chen, Jiang‐Gao Mao

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  16. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  17. Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties

    Inorganic Chemistry · 2023-09-07

    Nan Ma, Yu Hong Huang, Chun‐Li Hu, Mingzhi Zhang, Bingxuan Li, Jiang‐Gao Mao

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  18. Promoting NIR‐Driven Luminescence Activity of Calcium zinc galliumate via Energy Transfer from Mn4+ to Ho3+ for Second Biological Window

    European Journal of Inorganic Chemistry · 2024-01-09

    Yan Ping Fan, Zhengzhang Li, Shaoan Zhang, Naif Mohammed Al‐Hada, Xiaohui Lin, Chonghui Li, Yang Lv

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  19. Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates

    SSRN Electronic Journal · 2025-01-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  20. Multifactorial directed regulation of anionic units in praseodymium-contained iodates

    Journal of Molecular Structure · 2025-09-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Lehui Liu, Xingxing Jiang, Hongming Liu, Hongming Liu

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  21. Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals

    Chemistry - A European Journal · 2025-10-09

    Ying‐Jie Jia, Yi-Gang Chen, Bingbing Zhang, Yao Guo, Xian‐Ming Zhang

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  22. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  23. From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap

    Inorganic Chemistry Frontiers · 2026-01-01

    Xue-Ying Zhang, Peng-Fei Chen, Bing‐Ping Yang, Jiang‐Gao Mao

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  24. Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation

    Chinese Journal of Chemistry · 2026-03-12

    Xiaohui Zhang, Ye Tao, Qianshuang Lu, J. N. Tan, Chenglong Xu, Yingjie Li, Yi Chen, Jianke Pan, F. H. Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Xiujun Yu, Xiaopeng Li

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  25. Two {B 6 }-Based Borates: From 1D Chain to 3D Framework

    Inorganic Chemistry · 2026-04-10

    Jin-Ni Zhao, Xiao-Shuang Sun, Juan Chen, Xinwei Li, Guo‐Yu Yang

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