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RESEARCH PAPER · Inorganic Chemistry · 2019

K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges

Xueyan Zhang, Hongping Wu, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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K9[B4O5(OH)4]3(CO3)X·7H2O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff EdgesOriginalCation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material18Spectrally uncorrelated biphotons generated from “the family of BBO crystal”15Comprehensive Density Functional Theory Studies of Vibrational Spectra of Carbonates63Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11Sr5(CO3)2(BO3)2: A new family member of isostructural mixed borate and carbonate Ba4M(BO3)2(CO3)2 (M = Ba, Sr) with isolated BO3 and CO3 groups7Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution33An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution1M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10(C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems5M 3 MoO 4 (HCO 3 ) (M = Rb and Cs): cation-tuned synthesis of two noncentrosymmetric molybdate-carbonates with isolated [MoO 4 ] and [HCO 3 ] groups0Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates4Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance0

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  1. Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)

    Inorganic Chemistry · 2019-09-18

    Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  2. NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material

    Inorganic Chemistry · 2019-12-17

    Fenghua Ding, Weilong Zhang, Matthew Lander Nisbet, Weiguo Zhang, P. Shiv Halasyamani, Zhihua Yang, Shilie Pan, Kenneth Reinhard Poeppelmeier

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  3. Spectrally uncorrelated biphotons generated from “the family of BBO crystal”

    Quantum Engineering · 2020-05-16

    Rui‐Bo Jin, Wu‐Hao Cai, Chunling Ding, Feng Mei, Guang‐Wei Deng, Ryosuke Shimizu, Qiang Zhou

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  4. Comprehensive Density Functional Theory Studies of Vibrational Spectra of Carbonates

    Nanomaterials · 2020-11-17

    Yu. N. Zhuravlev, Victor V. Atuchin∥⊥

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  5. Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Kening Sun, Guo‐Yu Yang

    Read original paper ↗ ·

  6. Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

    Read original paper ↗ ·

  7. Sr5(CO3)2(BO3)2: A new family member of isostructural mixed borate and carbonate Ba4M(BO3)2(CO3)2 (M = Ba, Sr) with isolated BO3 and CO3 groups

    Journal of Molecular Structure · 2021-08-28

    Jiongquan Chen, Zhihua Yang, Kui Wu, Yun Mo Yang, Shilie Pan

    Read original paper ↗ ·

  8. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

    Inorganica Chimica Acta · 2022-10-19

    Aixin Zhu, Jianbang Chen, Yanhui Zhang, Zhi Guo Su

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  9. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  10. An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution

    Angewandte Chemie International Edition · 2024-04-25

    Shuai Liu, Xingxing Jiang, Qi Lu, Yilei Hu, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  11. An Unprecedented [BO2]‐Based Deep‐Ultraviolet Transparent Nonlinear Optical Crystal by Superhalogen Substitution

    Angewandte Chemie · 2024-04-25

    Shuai Liu, Xingxing Jiang, Qi Lu, Yilei Hu, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·

  12. M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion

    Inorganic Chemistry · 2024-05-09

    Weifeng Chen, Mei-Jun Zou, Jinɡjinɡ Li, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  13. (C 8 H 7 N 2 O 2 ) 2 [Bi 2 Br 8 ]·2H 2 O and (C 8 H 7 N 2 O 2 ) 6 [Bi 2 Cl 10 ]Cl 2 ·2H 2 O: Exploring Birefringent Crystals in Hybrid Halide Systems

    Inorganic Chemistry · 2024-05-10

    Mingliang Ding, Qiong Sen Wu, Yaoguo Shen, Jinquan Hong, Guofa Dong, Liang Ma

    Read original paper ↗ ·

  14. M 3 MoO 4 (HCO 3 ) (M = Rb and Cs): cation-tuned synthesis of two noncentrosymmetric molybdate-carbonates with isolated [MoO 4 ] and [HCO 3 ] groups

    Journal of Materials Chemistry C · 2025-01-01

    Jianlong Huang, Wenhu Wang, JuanJuan Lu, Feng Yu

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  15. Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates

    Advanced Optical Materials · 2025-09-15

    Shuai An, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  16. Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance

    Journal of the American Chemical Society · 2026-09-11

    Wenbin Zhang, Ruonan Zhang, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

    Read original paper ↗ ·
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