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RESEARCH PAPER · Chemistry of Materials · 2018

Cation Exchange as a Mechanism To Engineer Polarity in Layered Perovskites

Tong Zhu, Guru Khalsa, Dana M. Havas, Alexandra S. Gibbs, Weiguo Zhang, P. Shiv Halasyamani, Nicole A. Benedek, Michael A. Hayward

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Cation Exchange as a Mechanism To Engineer Polarity in Layered PerovskitesOriginalDesign of Mixed‐Cation Tri‐Layered Pb‐Free Halide Perovskites for Optoelectronic Applications27A -site cation size effect on oxygen octahedral rotations in acentric Ruddlesden-Popper alkali rare-earth titanates11Competing Polar and Antipolar Structures in the Ruddlesden–Popper Layered Perovskite Li2SrNb2O740Structural, optical and magnetic behaviour of Cr doped BaSnO3 perovskite nanostructures47Surveying polar materials in the Inorganic Crystal Structure Database to identify emerging structure types11Complex Structural Phase Transitions of the Hybrid Improper Polar Dion–Jacobson Oxides RbNdM 2 O 7 and CsNdM 2 O 7 (M = Nb, Ta)35Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion–Jacobson Layered Perovskites, A′Cd2Nb3O10 (A′ = Rb, Cs)12Exploring the A2BX3 Family for New Functional Materials Using Crystallographic Database Mining and First-Principles Calculations5Polar Structures of KNdNb2O7and KNdTa2O710Hybrid improper antiferroelectricity—New insights for novel device concepts2The influence of the 6s 2 configuration of Bi 3+ on the structures of A′BiNb 2 O 7 (A′ = Rb, Na, Li) layered perovskite oxides10Materials, photophysics and device engineering of perovskite light-emitting diodes96Switching between Proper and Hybrid-Improper Polar Structures via Cation Substitution in A2La(TaTi)O7(A = Li, Na)17Layered Double Perovskites75Directed synthesis of a hybrid improper magnetoelectric multiferroic material25Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden–Popper phases57Review of experimental progress of hybrid improper ferroelectricity in layered perovskite oxides36Developing new antiferroelectric and ferroelectric oxides and chalcogenides within the A2BX3 family10The crystal and defect structures of polar KBiNb 2 O 71Designing new polar materials1Hybrid Improper Ferroelectricity: A Theoretical, Computational, and Synthetic Perspective45Interplay between Oxygen Octahedral Rotation and Deformation in the Acentric ARTiO4 Series toward Negative Thermal Expansion19MnCaTa2O7─A Magnetically Ordered Polar Phase Prepared via Cation Exchange4La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide29Boosting selective Cs+ uptake through the modulation of stacking modes in layered niobate-based perovskites30Synthesis, Structure, and Properties of Dion–Jacobson Double‐Layered Perovskites A′SmNb2O7 (A′=Rb, K, Na, Li, H)4Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 78Cation Exchange as a Route to Introduce Magnetism to Hybrid-Improper Polar Phases0Chemistry and physics of layered oxychalcogenides containing an anti-cuprate type square lattice2Revival of Layered Ferroelectrics in Thin Films2Synthesis of the Double Infinite-Layer Ni(I) Phase La 3 Ni 2 O 5 F via Sequential Topochemical Reactions2Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides0Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O70

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33 direct citing papers saved.

  1. Design of Mixed‐Cation Tri‐Layered Pb‐Free Halide Perovskites for Optoelectronic Applications

    Advanced Electronic Materials · 2019-05-06

    Zhun Liu, Xingang Zhao, Alex Zunger, Lijun Zhang

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  2. A -site cation size effect on oxygen octahedral rotations in acentric Ruddlesden-Popper alkali rare-earth titanates

    Physical Review Materials · 2019-06-10

    Hirofumi Akamatsu, Koji Fujita, Toshihiro Kuge, Arnab Sen Gupta, James M. Rondinelli, Isao Tanaka, Katsuhisa Tanaka, Venkatraman Gopalan

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  3. Competing Polar and Antipolar Structures in the Ruddlesden–Popper Layered Perovskite Li2SrNb2O7

    Chemistry of Materials · 2019-06-12

    Ritesh Uppuluri, Hirofumi Akamatsu, Arnab Sen Gupta, Huaiyu Hugo Wang, Craig M. Brown, Kleyser Agueda Lopez, Nasim Alem, Venkatraman Gopalan, Thomas E. Mallouk

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  4. Structural, optical and magnetic behaviour of Cr doped BaSnO3 perovskite nanostructures

    Physica B Condensed Matter · 2019-06-12

    M. Avinash, Munisamy Muralidharan, K. Sivaji

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  5. Surveying polar materials in the Inorganic Crystal Structure Database to identify emerging structure types

    Journal of Solid State Chemistry · 2019-11-05

    Joseph W. Bennett

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  6. Complex Structural Phase Transitions of the Hybrid Improper Polar Dion–Jacobson Oxides RbNdM 2 O 7 and CsNdM 2 O 7 (M = Nb, Ta)

    Chemistry of Materials · 2020-04-23

    Tong Zhu, Alexandra S. Gibbs, Nicole A. Benedek, Michael A. Hayward

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  7. Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion–Jacobson Layered Perovskites, A′Cd2Nb3O10 (A′ = Rb, Cs)

    Inorganic Chemistry · 2020-05-28

    Shalu Atri, Meenakshi Pokhriyal, S. Uma

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  8. Exploring the A2BX3 Family for New Functional Materials Using Crystallographic Database Mining and First-Principles Calculations

    The Journal of Physical Chemistry C · 2020-08-12

    Joseph W. Bennett

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  9. Polar Structures of KNdNb2O7and KNdTa2O7

    Chemistry of Materials · 2020-08-25

    Subhadip Mallick, Alexandra S. Gibbs, Weiguo Zhang, P. Shiv Halasyamani, Nicole A. Benedek, Michael A. Hayward

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  10. Hybrid improper antiferroelectricity—New insights for novel device concepts

    MRS Advances · 2020-12-01

    Xue‐Zeng Lu, James M. Rondinelli

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  11. The influence of the 6s 2 configuration of Bi 3+ on the structures of A′BiNb 2 O 7 (A′ = Rb, Na, Li) layered perovskite oxides

    Dalton Transactions · 2021-01-01

    Subhadip Mallick, Guru Khalsa, Jeffrey Z. Kaaret, Weiguo Zhang, Maria Batuk, Alexandra S. Gibbs, Joke Hadermann, P. Shiv Halasyamani, Nicole A. Benedek, Michael A. Hayward

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  12. Materials, photophysics and device engineering of perovskite light-emitting diodes

    Reports on Progress in Physics · 2021-03-17

    Ziming Chen, Zhenchao Li, Thomas R. Hopper, Artem A. Bakulin, Hin‐Lap Yip

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  13. Switching between Proper and Hybrid-Improper Polar Structures via Cation Substitution in A2La(TaTi)O7(A = Li, Na)

    Chemistry of Materials · 2021-03-31

    Subhadip Mallick, Andrew Dominic Fortes, Weiguo Zhang, P. Shiv Halasyamani, Michael A. Hayward

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  14. Layered Double Perovskites

    Annual Review of Materials Research · 2021-05-05

    Hayden A. Evans, Lingling Mao, Ram Seshadri, Anthony Kevin Cheetham

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  15. Directed synthesis of a hybrid improper magnetoelectric multiferroic material

    Nature Communications · 2021-08-16

    Tong Zhu, Fabio Orlandi, Pascal Manuel, Alexandra S. Gibbs, Weiguo Zhang, P. Shiv Halasyamani, Michael A. Hayward

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  16. Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden–Popper phases

    Nature Communications · 2021-09-20

    Youngjae Hong, Pilgyu Byeon, Jumi Bak, Yoon Seong Heo, Hye‐Sung Kim, Hyung Bin Bae, Sung‐Yoon Chung

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  17. Review of experimental progress of hybrid improper ferroelectricity in layered perovskite oxides

    Journal of Physics D Applied Physics · 2021-10-22

    Bi Hui Zhang, Xiao Qiang Liu, Xiang Ming Chen

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  18. Developing new antiferroelectric and ferroelectric oxides and chalcogenides within the A2BX3 family

    Journal of materials research/Pratt's guide to venture capital sources · 2021-10-28

    Aaliyah Khan, Autumn S. Cook, Joshua A. Leginze, Joseph W. Bennett

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  19. The crystal and defect structures of polar KBiNb 2 O 7

    Dalton Transactions · 2022-01-01

    Subhadip Mallick, Weiguo Zhang, Maria Batuk, Alexandra S. Gibbs, Joke Hadermann, P. Shiv Halasyamani, Michael A. Hayward

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  20. Designing new polar materials

    Elsevier eBooks · 2022-01-28

    Emma E. McCabe

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  21. Hybrid Improper Ferroelectricity: A Theoretical, Computational, and Synthetic Perspective

    Annual Review of Materials Research · 2022-07-01

    Nicole A. Benedek, Michael A. Hayward

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  22. Interplay between Oxygen Octahedral Rotation and Deformation in the Acentric ARTiO4 Series toward Negative Thermal Expansion

    Chemistry of Materials · 2022-07-11

    Suguru Yoshida, Hirofumi Akamatsu, Alexandra S. Gibbs, Shogo Kawaguchi, Venkatraman Gopalan, Katsuhisa Tanaka, Koji Fujita

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  23. MnCaTa2O7─A Magnetically Ordered Polar Phase Prepared via Cation Exchange

    Chemistry of Materials · 2023-09-09

    Subhadip Mallick, Fabio Orlandi, Pascal Manuel, Weiguo Zhang, P. Shiv Halasyamani, Michael A. Hayward

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  24. La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide

    Journal of the American Chemical Society · 2024-02-06

    Wei Yi, Tatsushi Kawasaki, Yang Zhang, Hirofumi Akamatsu, Ryo Ota, Shuki Torii, Koji Fujita

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  25. Boosting selective Cs+ uptake through the modulation of stacking modes in layered niobate-based perovskites

    Nature Communications · 2024-10-07

    Haiyan Sun, Zhihua Chen, Bing Hu, Jun-Hao Tang, Lu Yang, Yanling Guo, Yuexin Yao, Mei‐Ling Feng, Xiao‐Ying Huang

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  26. Synthesis, Structure, and Properties of Dion–Jacobson Double‐Layered Perovskites A′SmNb2O7 (A′=Rb, K, Na, Li, H)

    European Journal of Inorganic Chemistry · 2024-10-23

    О. В. Крашенинникова, E.V. Syrov, Ilya Sorokin, Sergei Smirnov, Dmitry N. Titaev

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  27. Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 7

    Chemistry of Materials · 2025-05-22

    Y. L. Wei, Zhe Guo, Zheng Duan Zhang, Jiamin Lin, Diming Xu, Yu Huang, Xue‐Zeng Lu, Xiao Qiang Liu, Xiang Ming Chen

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  28. Cation Exchange as a Route to Introduce Magnetism to Hybrid-Improper Polar Phases

    Inorganic Chemistry · 2025-06-20

    Rachel Conway, Fabio Orlandi, Pascal Manuel, Yujie Zhang, P. Shiv Halasyamani, Michael A. Hayward

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  29. Chemistry and physics of layered oxychalcogenides containing an anti-cuprate type square lattice

    Solid State Sciences · 2025-09-25

    Nicola D. Kelly

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  30. Revival of Layered Ferroelectrics in Thin Films

    Small Science · 2026-01-01

    Elzbieta Gradauskaite

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  31. Synthesis of the Double Infinite-Layer Ni(I) Phase La 3 Ni 2 O 5 F via Sequential Topochemical Reactions

    Journal of the American Chemical Society · 2026-02-04

    Romain Wernert, Robert D. Smyth, Michael A. Hayward

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  32. Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides

    Inorganic Chemistry · 2026-06-23

    Daichi Kato, Shuhei Ueda, Tong Zhu, Hiroki Ubukata, Hikaru Takeuchi, Takashi Honda, Yusuke Nambu, Tatsuya Tsumori, Kotaro Nakai, Cédric Tassel, Itaru Oikawa, Hitoshi Takamura, Teruki Motohashi, Miwa Saito, Yusuke Asai, Ryotaro Aso, Koji Fujita, Hiroshi Kageyama

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  33. Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O7

    Solids · 2026-10-01

    Anamika Poduval, Mark Granier, Roshni Bhuvan, Levon A. LeBan, C. Merry Harpin, Steven W. Rick, John B. Wiley

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