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RESEARCH PAPER · Journal of the American Chemical Society · 2024

La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide

Wei Yi, Tatsushi Kawasaki, Yang Zhang, Hirofumi Akamatsu, Ryo Ota, Shuki Torii, Koji Fujita

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La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite OxideOriginalHybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures10Effects of doping with magnetic cations on the hybrid improper ferroelectricity in Sr3Sn2O73Suppression of Ferroelectric Transitions by Symmetry Trapping in Dion–Jacobson-Layered Perovskites Cs(La,Nd)Nb2O74Interplay between A-site and oxygen-vacancy ordering, and mixed electron/oxide-ion conductivity in n = 1 Ruddlesden–Popper perovskite Sr 2 Nd 2 Zn 2 O 77Recent Progress of Hybrid Improper Ferroelectrics with Ruddlesden-Popper Structure1Structural, dielectric and magnetic properties of Sb/Cr-doped CaCu3Ti4O12 quadruple perovskite oxides3Intermediate temperature structural modulation and properties of CoIn 20Ruddlesden-Popper tolerance factor: An indicator predicting stability of 2D Ruddlesden-Popper phases17Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 78A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity8Growth and structure of La-doped Sr3Fe2O7 thin films on SrTiO3(001) by pulsed laser deposition1Exploring a route to induce ferromagnetism on Sr3Sn2O7 by co-doping with non-Jahn-Teller-distorted Mn3+ and La3+ cations1Hybrid improper ferroelectricity and phase transition in La2Sr(Sc1− x In x )2O7 ceramics2Boosting the OER via the metal–support interaction and H-bond network: amorphous RuO x on fluorinated Ruddlesden–Popper perovskites0Revival of Layered Ferroelectrics in Thin Films2Tunable polarization and band gap in ferroelectric nitride perovskites via superlattice design0Controlling the competition between polar and antipolar structures by rumpling in Ruddlesden–Popper layered nitride La3W2N70Kinetic control of A-site cation disorder and its impact on the ferroelectric phase transition in La2SrSc2O7 layered perovskite oxide3Ultralow-Barrier Antiferroelectric–Ferroelectric Transition Enabled by Competing Polar Distortion in Two-Dimensional Ruddlesden–Popper Nitride Perovskites2Atomic-Scale Visualization of Competing Polar Orders in Dion–Jacobson Layered Perovskites2Hybrid Improper Ferroelectricity in Ho 2/3 Ta 2 O 6 Ceramics With A ‐site‐Deficient Double‐Perovskite Structures0Optoelectronic, solar cell and multiferroic analysis of the Ruddlesden–Popper perovskite MnCaTa 2 O 7 : A first principles study0Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides0Hybrid improper ferroelectricity and complex phase evolution in Eu2SrSc2O7 ceramics1Magnetotransport and temperature coefficient of resistance in high-entropy manganite (La0.25Pr0.25Sm0.25Gd0.25)1-xCaxMnO3 (x=0.0, 0.1) ceramics0Record‐Low Coercive Field and Stable Curie Temperature in Bulk Hybrid Improper Ferroelectrics via Synergistic A / B ‐Site Co‐Substitution0Hybrid improper ferroelectricity and enhanced Curie temperature in co-substituted La2SrSc2O7-based ceramics0Magnetoelectric coupling effect in the electrocatalytic water splitting0

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  1. Hybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures

    Applied Physics Letters · 2024-07-22

    Zhe Guo, Zheng Duan Zhang, Xiao Qiang Liu, Xiang Ming Chen

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  2. Effects of doping with magnetic cations on the hybrid improper ferroelectricity in Sr3Sn2O7

    Journal of Alloys and Compounds · 2024-08-24

    J. Blasco, David Gracia, Sara Lafuerza, Vera Cuartero, Gloria Subías

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  3. Suppression of Ferroelectric Transitions by Symmetry Trapping in Dion–Jacobson-Layered Perovskites Cs(La,Nd)Nb2O7

    Inorganic Chemistry · 2024-11-27

    Zhen‐Tao Lu, Kai Nishioka, Yang Zhang, Koji Fujita, Katsuro Hayashi, Hirofumi Akamatsu

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  4. Interplay between A-site and oxygen-vacancy ordering, and mixed electron/oxide-ion conductivity in n = 1 Ruddlesden–Popper perovskite Sr 2 Nd 2 Zn 2 O 7

    Chemical Science · 2024-12-17

    Di Li, Guangxiang Lu, Zien Cheng, Maxim Avdeev, Jungu Xu, Zhengyang Zhou, Rihong Cong, Tao Yang, Pengfei Jiang

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  5. Recent Progress of Hybrid Improper Ferroelectrics with Ruddlesden-Popper Structure

    Journal of Inorganic Materials · 2025-01-01

    ZHANG Bihui, Liu Xiaoqiang, Xiangming Chen

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  6. Structural, dielectric and magnetic properties of Sb/Cr-doped CaCu3Ti4O12 quadruple perovskite oxides

    Journal of Physics Condensed Matter · 2025-01-02

    Jie Feng Ding, Xinhua Zhu

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  7. Intermediate temperature structural modulation and properties of CoIn 2

    Physical Review Materials · 2025-03-18

    A. Sabovic, S. Villanova, A. Portillo, Yaping Li, Y. Janssen, Brian O. Patrick, M. C. Aronson, Jack W. Simonson

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  8. Ruddlesden-Popper tolerance factor: An indicator predicting stability of 2D Ruddlesden-Popper phases

    Acta Materialia · 2025-04-02

    Hyo Gyeong Shin, Eun Ho Kim, Jaeseon Kim, H.T. Kim, Donghwa Lee

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  9. Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 7

    Chemistry of Materials · 2025-05-22

    Y. L. Wei, Zhe Guo, Zheng Duan Zhang, Jiamin Lin, Diming Xu, Yu Huang, Xue‐Zeng Lu, Xiao Qiang Liu, Xiang Ming Chen

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  10. A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity

    Chemistry of Materials · 2025-10-21

    Takumi Terauchi, Wei Yi, R. Takada, Hirofumi Akamatsu, Ryo Ota, Shuki Torii, Koji Fujita

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  11. Growth and structure of La-doped Sr3Fe2O7 thin films on SrTiO3(001) by pulsed laser deposition

    Journal of Crystal Growth · 2025-11-01

    Jiaxin Li, Xunqing Yin, Mengjia Wang, S. Ma, Bo Zhang, Sheng Huang, Feng Liu, Pengfei Jiao, Guohua Wang, Dong Qian

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  12. Exploring a route to induce ferromagnetism on Sr3Sn2O7 by co-doping with non-Jahn-Teller-distorted Mn3+ and La3+ cations

    Journal of Alloys and Compounds · 2025-11-20

    J. Blasco, Vera Cuartero, Sara Lafuerza, David Gracia, Inés Puente‐Orench, José Alberto Rodríguez-Velamazán, Javier Herrero‐Martín, R. Torchio, Olivier Mathon, Gloria Subías

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  13. Hybrid improper ferroelectricity and phase transition in La2Sr(Sc1− x In x )2O7 ceramics

    Applied Physics Letters · 2025-12-08

    Wei Yi Huang, Zheng Duan Zhang, Zhe Guo, Shu Ya Wu, Xiao Qiang Liu, Xiang Ming Chen

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  14. Boosting the OER via the metal–support interaction and H-bond network: amorphous RuO x on fluorinated Ruddlesden–Popper perovskites

    Nanoscale · 2026-01-01

    Ziye Feng, Zijie Peng, Yang Xu, Ming Zhang, Junfang Cheng

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  15. Revival of Layered Ferroelectrics in Thin Films

    Small Science · 2026-01-01

    Elzbieta Gradauskaite

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  16. Tunable polarization and band gap in ferroelectric nitride perovskites via superlattice design

    Physical review. B./Physical review. B · 2026-01-29

    Yixin Jiao, Lixiang Rao, Zuolong Jia, Xiao Xie, Zun‐Yi Deng, Bonan Zhu, Gang Tang, Jiawang Hong

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  17. Controlling the competition between polar and antipolar structures by rumpling in Ruddlesden–Popper layered nitride La3W2N7

    Applied Physics Letters · 2026-02-16

    Zun‐Yi Deng, Gang Tang, Jiawang Hong

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  18. Kinetic control of A-site cation disorder and its impact on the ferroelectric phase transition in La2SrSc2O7 layered perovskite oxide

    Applied Physics Letters · 2026-03-02

    Yang Zhang, Tatsushi Kawasaki, Shogo Kawaguchi, Wei Yi, Koji Fujita

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  19. Ultralow-Barrier Antiferroelectric–Ferroelectric Transition Enabled by Competing Polar Distortion in Two-Dimensional Ruddlesden–Popper Nitride Perovskites

    Nano Letters · 2026-04-08

    Shuyi Lin, Qiong Lei, Jun Li Yin

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  20. Atomic-Scale Visualization of Competing Polar Orders in Dion–Jacobson Layered Perovskites

    Chemistry of Materials · 2026-04-21

    Shu Morita, Keita Nishibashi, Keito Niwa, Makoto Kobayashi, Eisuke Yamamoto, Rubén Cantón-Vitoria, Daisuke Urushihara, Toru Asaka, Hidetaka Kasai, Shigeo Mori, Minoru Osada

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  21. Hybrid Improper Ferroelectricity in Ho 2/3 Ta 2 O 6 Ceramics With A ‐site‐Deficient Double‐Perovskite Structures

    Journal of the American Ceramic Society · 2026-05-01

    Cang Huan Ye, Zhe Guo, Zheng Duan Zhang, Xiao Qiang Liu, Z.V. Gareeva, Xiang Ming Chen

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  22. Optoelectronic, solar cell and multiferroic analysis of the Ruddlesden–Popper perovskite MnCaTa 2 O 7 : A first principles study

    Modern Physics Letters B · 2026-05-25

    Israr Ahmad, Zahid Ali, Saif Ullah, Iftikhar Ahmad

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  23. Redox-Neutral Interstitial Hydride Incorporation in Ruddlesden–Popper Oxides

    Inorganic Chemistry · 2026-06-23

    Daichi Kato, Shuhei Ueda, Tong Zhu, Hiroki Ubukata, Hikaru Takeuchi, Takashi Honda, Yusuke Nambu, Tatsuya Tsumori, Kotaro Nakai, Cédric Tassel, Itaru Oikawa, Hitoshi Takamura, Teruki Motohashi, Miwa Saito, Yusuke Asai, Ryotaro Aso, Koji Fujita, Hiroshi Kageyama

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  24. Hybrid improper ferroelectricity and complex phase evolution in Eu2SrSc2O7 ceramics

    Applied Physics Letters · 2026-07-06

    Cang Huan Ye, Zhe Guo, Zheng Duan Zhang, Xiao Qiang Liu, Z.V. Gareeva, Xiang Ming Chen

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  25. Magnetotransport and temperature coefficient of resistance in high-entropy manganite (La0.25Pr0.25Sm0.25Gd0.25)1-xCaxMnO3 (x=0.0, 0.1) ceramics

    Journal of Materials Science Materials in Electronics · 2026-08-01

    Xiaolei Chen, Zhongwen Li

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  26. Record‐Low Coercive Field and Stable Curie Temperature in Bulk Hybrid Improper Ferroelectrics via Synergistic A / B ‐Site Co‐Substitution

    Advanced Functional Materials · 2026-08-11

    Zhe Guo, Jia Ling Li, Jia Min Lin, Tulai Sun, Yu Huang, Xiao Li Zhu, Xiao Qiang Liu, Xiang Ming Chen

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  27. Hybrid improper ferroelectricity and enhanced Curie temperature in co-substituted La2SrSc2O7-based ceramics

    Journal of Applied Physics · 2026-09-01

    Wei Yi Huang, Zheng Duan Zhang, Zhe Guo, Shu Ya Wu, Xiao Qiang Liu, Xiang Ming Chen

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  28. Magnetoelectric coupling effect in the electrocatalytic water splitting

    Coordination Chemistry Reviews · 2026-09-11

    Yingshan Xue, Zibo Zhao, Fende Zhou, Cheng Yang, Yibin Hou, Zhigang Qiao, Xin Zhang, Zhenxing Li

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