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RESEARCH PAPER · Journal of Physics D Applied Physics · 2021

Review of experimental progress of hybrid improper ferroelectricity in layered perovskite oxides

Bi Hui Zhang, Xiao Qiang Liu, Xiang Ming Chen

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Review of experimental progress of hybrid improper ferroelectricity in layered perovskite oxidesOriginalDion–Jacobson A′M iii NaNb 3 O 10 (A′ = Rb, Cs; M( iii ) = Sm, Bi) and RbSmNa 2 Nb 4 O 13 layered perovskites and their luminescent function8Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics12Distortion modes and ferroelectric properties in hybrid improper ferroelectric Sr3(Sn,Zr)2O7 ceramics7Superior hybrid improper ferroelectricity and enhanced ferromagnetism of Ca3(Ti1-xCox)2O7 ceramics through the superexchange interaction8Significantly enhanced hybrid improper ferroelectricity of Ca3Ti2O7 ceramics by the oxygen vacancy engineering11Oxygen Deficiency and Migration-Mediated Electric Polarization in Magnetic Fe,Co-Substituted SrTiO3−δ1Research progress of synthesis of high-performance perovskites and its derivatives based on polyhedral distortion0Second Harmonic Generation in the Polar A′SmNb2O7 (A′ = Rb, Cs) Dion–Jacobson Layered Perovskites11Chemical Trends of Surface Reconstruction and Band Positions of Nonmetallic Perovskite Oxides from First Principles19Pressure-Induced Phase Transformations of Quasi-2D Sr3Hf2O73Achieving ultralow coercive electric field in (Ca1-1.5Gd )3Ti2O7 ceramics via dual inhibitory effects on oxygen vacancies12D-Perovskite Multiferroics: Interface-Induced Magnetoelectric Effect in Perovskite-Based Multiferroic Superlattices3Crystal structure and magnetization reversal in single-layered Ruddlesden–Popper CaEuFeO4 ceramics3Energy Storage Characteristics and Ferroelectric Properties of La-Doped Bi2sio5 Thin Films0La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide29Effect of Ca2MnO4 on the magnetic and electric properties in Ca3Mn2O7 ceramics prepared with different sintering temperature2Hybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures10Theoretical and data-driven approaches to semiconductors and dielectrics: from prediction to experiment2Hybrid improper ferroelectricity in a Si-compatible CeO2/HfO2 artificial superlattice2Recent Progress of Hybrid Improper Ferroelectrics with Ruddlesden-Popper Structure1Dion–Jacobson (n = 2) Layered Perovskites (A′SmTa2O7; A′ = Rb, Cs) As Potential Ferroelectric Materials6Structural distortions leading to potential polar materials in n $=$ 3 and 4 Dion–Jacobson-layered perovskite series1Significantly enhanced stability of hybrid improper ferroelectricity in Sr 3 Zr 2 O 7 by isovalent Ca substitution1Structural Distortions and Uniaxial Negative Thermal Expansion in the Polar Dion–Jacobson Oxide RbNdTa 2 O 70Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 78Phase Formation of Rubidium Bismuth Titanoniobates Based Solid Solutions0Correlation of Structural Properties and Ferroelectricity in Cobalt and Iron Co‐Doped Aurivillius Ceramics Based on Rietveld Refinement Analysis4Magnetic compensation and preferential substitution site for Ag in Mn 4 − x Ag x N epitaxial thin films4Structural Phase Transitions in Layered Perovskite CsFeF4${\rm CsFeF}_{4}$ and Weak Polar Response in CsFeF4${\rm CsFeF}_{4}$/RbFeF4${\rm RbFeF}_{4}$ Superlattice0Interlayer Switching of NiO 6 Octahedra Tilt via Interstitial Oxygen in La n + 1 Ni n O 3n + 1 ( n = 1, 2, 3)2A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity8Hybrid improper ferroelectricity and phase transition in La2Sr(Sc1− x In x )2O7 ceramics2A study focusing on the influence of multiple cationic substitutions in Dion–Jacobson ( n = 2) layered perovskite oxides0Revival of Layered Ferroelectrics in Thin Films2Hybrid improper ferroelectricity and enhanced Curie temperature in co-substituted La2SrSc2O7-based ceramics0Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O70

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  1. Dion–Jacobson A′M iii NaNb 3 O 10 (A′ = Rb, Cs; M( iii ) = Sm, Bi) and RbSmNa 2 Nb 4 O 13 layered perovskites and their luminescent function

    Journal of Materials Chemistry C · 2022-01-01

    Sachin Pal, Subrata K. Das, R. Nagarajan, S. Uma

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  2. Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics

    Materials · 2022-01-13

    Z. V. Gareeva, Anatoly K. Zvezdin, Konstantin A. Zvezdin, Xiangming Chen

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  3. Distortion modes and ferroelectric properties in hybrid improper ferroelectric Sr3(Sn,Zr)2O7 ceramics

    Journal of Applied Physics · 2022-05-13

    Q. S. Chen, B. H. Zhang, B. H. Chen, Xiao Qiang Liu, Xiang Ming Chen

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  4. Superior hybrid improper ferroelectricity and enhanced ferromagnetism of Ca3(Ti1-xCox)2O7 ceramics through the superexchange interaction

    Ceramics International · 2022-08-23

    Dakai Chen, Hongdi Wu, Wei Hua Cai, Chuang Zhou, Rongli Gao, Xiaoling Deng, Gang Chen, Zhenhua Wang, Xiang Lei, Chunlin Fu

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  5. Significantly enhanced hybrid improper ferroelectricity of Ca3Ti2O7 ceramics by the oxygen vacancy engineering

    Materials Today Chemistry · 2022-10-29

    Hongdi Wu, Ziyan Gao, Wei Hua Cai, Rongli Gao, Dakai Chen, G. Chen, Xiaoling Deng, Z. Wang, Xiang Lei, X. Wang, Chunlin Fu

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  6. Oxygen Deficiency and Migration-Mediated Electric Polarization in Magnetic Fe,Co-Substituted SrTiO3−δ

    Magnetochemistry · 2022-11-01

    Emilio A. Cortés Estay, Shyue Ping Ong, Caroline Anne Ross, Juan M. Florez

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  7. Research progress of synthesis of high-performance perovskites and its derivatives based on polyhedral distortion

    Acta Physica Sinica · 2023-01-01

    Cheng Fang, Hong Wang, Siqi Shi

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  8. Second Harmonic Generation in the Polar A′SmNb2O7 (A′ = Rb, Cs) Dion–Jacobson Layered Perovskites

    Chemistry of Materials · 2023-01-23

    Sachin Pal, R. Nagarajan, S. Uma

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  9. Chemical Trends of Surface Reconstruction and Band Positions of Nonmetallic Perovskite Oxides from First Principles

    Chemistry of Materials · 2023-02-21

    Yasuhide Mochizuki, Ha‐Jun Sung, Tomoya Gake, Fumiyasu Oba

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  10. Pressure-Induced Phase Transformations of Quasi-2D Sr3Hf2O7

    The Journal of Physical Chemistry C · 2023-08-01

    Márcia C. Barbosa, Da Silva, P. Neenu Lekshmi, Michel L. Marcondes, L. V. C. Assali, Helena Maria Petrilli, A. M. L. Lopes, João P. Araújo

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  11. Achieving ultralow coercive electric field in (Ca1-1.5Gd )3Ti2O7 ceramics via dual inhibitory effects on oxygen vacancies

    Materials Science in Semiconductor Processing · 2023-08-09

    Dakai Chen, Wei Hua Cai, Mingchao Du, Chuang Zhou, Xiuqi Li, Zeping Rao, Rongli Gao, Gang Chen, Xiaoling Deng, Chunlin Fu

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  12. 2D-Perovskite Multiferroics: Interface-Induced Magnetoelectric Effect in Perovskite-Based Multiferroic Superlattices

    Crystals · 2023-09-21

    Z. V. Gareeva, Ildus F. Sharafullin, Anatoly K. Zvezdin

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  13. Crystal structure and magnetization reversal in single-layered Ruddlesden–Popper CaEuFeO4 ceramics

    Ceramics International · 2023-11-03

    Zhidong Zhang, Z.J. Wu, B.H. Zhang, Xiao Qiang Liu, X.M. Chen

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  14. Energy Storage Characteristics and Ferroelectric Properties of La-Doped Bi2sio5 Thin Films

    SSRN Electronic Journal · 2024-01-01

    Eunmi Lee, Ahmed I. Ali, Jong Yeog Son

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  15. La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide

    Journal of the American Chemical Society · 2024-02-06

    Wei Yi, Tatsushi Kawasaki, Yang Zhang, Hirofumi Akamatsu, Ryo Ota, Shuki Torii, Koji Fujita

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  16. Effect of Ca2MnO4 on the magnetic and electric properties in Ca3Mn2O7 ceramics prepared with different sintering temperature

    Solid State Communications · 2024-05-08

    Shuhai Lin, Li‐Min Zheng, Haoyu Jia, Shaoxing Sun, Changcai Chen, Xiaohua Luo, Chunsheng Fang, Shengcan Ma

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  17. Hybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures

    Applied Physics Letters · 2024-07-22

    Zhe Guo, Zheng Duan Zhang, Xiao Qiang Liu, Xiang Ming Chen

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  18. Theoretical and data-driven approaches to semiconductors and dielectrics: from prediction to experiment

    Science and Technology of Advanced Materials · 2024-11-04

    Fumiyasu Oba, Takayuki Nagai, Ryoji Katsube, Yasuhide Mochizuki, Masatake Tsuji, Guillaume Deffrennes, Kota Hanzawa, Akitoshi Nakano, Akira Takahashi, Kei Terayama, Ryo Tamura, Hidenori Hiramatsu, Yoshitaro Nose, Hiroki Taniguchi

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  19. Hybrid improper ferroelectricity in a Si-compatible CeO2/HfO2 artificial superlattice

    npj Computational Materials · 2024-12-19

    Pawan Kumar, Jun Hee Lee

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  20. Recent Progress of Hybrid Improper Ferroelectrics with Ruddlesden-Popper Structure

    Journal of Inorganic Materials · 2025-01-01

    ZHANG Bihui, Liu Xiaoqiang, Xiangming Chen

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  21. Dion–Jacobson (n = 2) Layered Perovskites (A′SmTa2O7; A′ = Rb, Cs) As Potential Ferroelectric Materials

    The Journal of Physical Chemistry C · 2025-03-11

    Vandana Yadav, Sachin Pal, S. Uma

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  22. Structural distortions leading to potential polar materials in n $$=$$ 3 and 4 Dion–Jacobson-layered perovskite series

    Journal of Chemical Sciences · 2025-04-15

    Sachin Pal, S. Uma

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  23. Significantly enhanced stability of hybrid improper ferroelectricity in Sr 3 Zr 2 O 7 by isovalent Ca substitution

    Physical review. B./Physical review. B · 2025-05-14

    Q. Luo, Yang-Shun Lan, H. G. Zhang, P. Wang, C. F. Li, Z. B. Yan, Jun‐Ming Liu

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  24. Structural Distortions and Uniaxial Negative Thermal Expansion in the Polar Dion–Jacobson Oxide RbNdTa 2 O 7

    Chemistry of Materials · 2025-05-15

    P. Neenu Lekshmi, Da Silva, Pedro Rocha‐Rodrigues, John S. O. Evans, J.H. Belo, Pedro Silva de Sousa, Alicia Maria Manjón-Sanz, A. M. dos Santos, A. M. L. Lopes, João P. Araújo

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  25. Competing Octahedral Modes in the Hybrid Improper Ruddlesden–Popper Ferroelectric Ln 2 SrSc 2 O 7

    Chemistry of Materials · 2025-05-22

    Y. L. Wei, Zhe Guo, Zheng Duan Zhang, Jiamin Lin, Diming Xu, Yu Huang, Xue‐Zeng Lu, Xiao Qiang Liu, Xiang Ming Chen

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  26. Phase Formation of Rubidium Bismuth Titanoniobates Based Solid Solutions

    Russian Journal of Applied Chemistry · 2025-06-01

    Anna Vladimirovna Mitrofanova, I. S. Puzikov, M. D. Krutaya, Zhibin Huang, Elena A. Fortalnova, М. Г. Сафроненко

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  27. Correlation of Structural Properties and Ferroelectricity in Cobalt and Iron Co‐Doped Aurivillius Ceramics Based on Rietveld Refinement Analysis

    Crystal Research and Technology · 2025-06-13

    Mahmoud S. Alkathy, Vitor F. Barbosa, Ricardo Pereira Bonini, Marcio Daldin Teodoro, Fábio L. Zabotto, J. A. Eiras

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  28. Magnetic compensation and preferential substitution site for Ag in Mn 4 − x Ag x N epitaxial thin films

    Physical Review Materials · 2025-06-13

    Yuki Sobukawa, Tomohiro Yasuda, Kenta Amemiya, Takashi Suemasu

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  29. Structural Phase Transitions in Layered Perovskite CsFeF4${\rm CsFeF}_{4}$ and Weak Polar Response in CsFeF4${\rm CsFeF}_{4}$/RbFeF4${\rm RbFeF}_{4}$ Superlattice

    Advanced Theory and Simulations · 2025-06-16

    Subhajit Sau, H. Paredes Gutiérrez, Andrés Camilo Garcia-Castro, G. Vaitheeswaran, V. Kanchana

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  30. Interlayer Switching of NiO 6 Octahedra Tilt via Interstitial Oxygen in La n + 1 Ni n O 3n + 1 ( n = 1, 2, 3)

    Advanced Materials · 2025-08-21

    Xi Chen, Ningning Wang, Qinghua Zhang, Boya Wang, Gang Wang, Bosen Wang, Jinguang Cheng, Yi Xu

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  31. A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity

    Chemistry of Materials · 2025-10-21

    Takumi Terauchi, Wei Yi, R. Takada, Hirofumi Akamatsu, Ryo Ota, Shuki Torii, Koji Fujita

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  32. Hybrid improper ferroelectricity and phase transition in La2Sr(Sc1− x In x )2O7 ceramics

    Applied Physics Letters · 2025-12-08

    Wei Yi Huang, Zheng Duan Zhang, Zhe Guo, Shu Ya Wu, Xiao Qiang Liu, Xiang Ming Chen

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  33. A study focusing on the influence of multiple cationic substitutions in Dion–Jacobson ( n = 2) layered perovskite oxides

    Dalton Transactions · 2026-01-01

    Vandana Yadav, S. Uma

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  34. Revival of Layered Ferroelectrics in Thin Films

    Small Science · 2026-01-01

    Elzbieta Gradauskaite

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  35. Hybrid improper ferroelectricity and enhanced Curie temperature in co-substituted La2SrSc2O7-based ceramics

    Journal of Applied Physics · 2026-09-01

    Wei Yi Huang, Zheng Duan Zhang, Zhe Guo, Shu Ya Wu, Xiao Qiang Liu, Xiang Ming Chen

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  36. Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O7

    Solids · 2026-10-01

    Anamika Poduval, Mark Granier, Roshni Bhuvan, Levon A. LeBan, C. Merry Harpin, Steven W. Rick, John B. Wiley

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