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RESEARCH PAPER · Nature Communications · 2021

Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden–Popper phases

Youngjae Hong, Pilgyu Byeon, Jumi Bak, Yoon Seong Heo, Hye‐Sung Kim, Hyung Bin Bae, Sung‐Yoon Chung

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Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden–Popper phasesOriginalFormation mechanism of Ruddlesden–Popper faults in compressive-strained ABO 3 perovskite superlattices14Comparison of Fe-enhanced oxygen evolution electrocatalysis in amorphous and crystalline nickel oxides to evaluate the structural contribution84Manifestation of the Jahn–Teller effect subject to quadratic T ⊗ e + t 2 problem in ultrasonic attenuation. Case study of CaF2:Cr crystal with isovalent and aliovalent substitution5Cuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering20Anion‐Dependent Polarization and Piezoelectric Power Generation in Hybrid Halide MAPbX3 (X = I, Br, and Cl) Thin Films with Out‐of‐Plane Structural Adjustments16Multifunctional catalyst-assisted sustainable reformation of lignocellulosic biomass into environmentally friendly biofuel and value-added chemicals29Atomic-scale observation of premelting at 2D lattice defects inside oxide crystals21Direct Probing of Lattice‐Strain‐Induced Oxygen Release in LiCoO 2 and Li 2 MnO 3 without Electrochemical Cycling20Metal Ions versus Protons: Tracking of Charge‐Carrier Insertion into a Cathode Oxide in Aqueous Rechargeable Batteries34Linking stability with molecular geometries of perovskites and lanthanide richness using machine learning methods16Electron-Beam-Induced Formation of Oxygen Vacancies in Epitaxial LaCoO3 Thin Films2La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide29Electrochemically Engineered Lanthanum Nickelate as a Promising Transparent Hole-Transport Layer for Bulk Heterojunction Polymer Solar Cells: An Experimental and DFT Study23Effects of heterovalent ions doping-induced oxygen octahedral distortion and defect chemical change on piezoelectric characteristics and thermal stability of PHT-PIN ceramics33Atomic Imaging of Multi‐Dimensional Ruddlesden–Popper Interfaces in Lead‐Halide Perovskites7Local electronic structures of annealing induced phases in cobalt doped TiO 2 nanoparticles: a combined study of transmission electron microscopy and x-ray absorption fine structure spectroscopy7In-situ electric field-tailored exchange bias in the manganite/ferroelectric multiferroic heterostructures6Unit‐Cell‐Thickness Electron Confinement by Geometrically Constrained Antipolar Ordering2Comparing the Impacts of Strain Types on Oxygen-Vacancy Formation in a Perovskite Oxide via Nanometer-Scale Strain Fields18Atomic‐Level Observation of Potential‐Dependent Variations at the Surface of an Oxide Catalyst during Oxygen Evolution Reaction21Tunable 5d-t2g Mott State and Monoatomic Layer Two-Dimensional Electron Gas Realized in Spin–Orbit-Coupled SrIrO3 through Heterostructuring1Deciphering the Atomic-Scale Structural Origin for Photoluminescence Quenching in Tin–Lead Alloyed Perovskite Nanocrystals6Hybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures10Gigantic-oxidative atomic-layer-by-layer epitaxy for artificially designed complex oxides14Microwave shock-driven thermal engineering of unconventional cubic 2D LaMnO 3 for efficient oxygen evolution17Pyrolytic reduction roasting of used ternary lithium-ion battery cathode powder using coconut shell powder for selective recovery of lithium53A tellurium iodide perovskite structure enabling eleven-electron transfer in zinc ion batteries24Dissociative adsorption of in-situ grown NiBi with oxygen enabling lower friction and wear of nickel-based composite coating at elevated temperature3Direct Correlation of the Crystalline Phases of La 0.9 Sr 0.1 Co 1– y Fe y O 3−δ with the Partial Oxidation of Methane via In Situ Neutron and Synchrotron Diffraction5Large electrostrictive response in W-Mg co-doped Na0.5Bi0.5TiO3-based ceramics via defect complex designing0Effect of ionic-bonding d0 cations on structural durability in barium iridates for oxygen evolution electrocatalysis11Complex Iridate Solid Solutions for Catalyzing Oxygen Evolution Reaction: Comparison of Elemental Leaching and Stability Numbers9Atomic insights into topochemical fluorination and strong octahedral tilt in La2CoO42Large magnetodielectric coupling in layered perovskite Eu 2 Ti O 41Unraveling metastable perovskite oxides insights from structural engineering to synthesis paradigms17Ruddlesden–Popper Defects Act as a Free Surface: Role in Formation and Photophysical Properties of CsPbI 39Near Room‐Temperature Ferromagnetic Phase Achieved in 4 d Ruthenate via Interfacial Ferrimagnetic Coupling and Octahedral Rotation Engineering0Oxygen vacancy distribution in different regions of La1−xSrxGa1−yMgyO3−δ1Microstructure Optimization via Grain‐Boundary Segregation to Enhance DC Bias Dielectric Performance of BaTiO 3 Multilayer Ceramic Capacitors3Lattice-controlled Fe-exsolved perovskite anodes for high-performance and durable ammonia-powered electrochemical systems4Effect of Ni‐Doped Induced Stacking Faults on the NTC Properties and Aging Stability of La 0.9 Nd 0.1 Al 1‐x Ni x O 3 Ceramics2Jahn‐Teller Effect: Impact of Distortion on Oxygen Electrocatalysis28Directly Visualizing the Formation of Artificial Structures and Their Charge in Oxides by Electron Microscopy0Quasi–two-dimensional ferroelectricity with multiple switchable polarization states in N-H coinjected perovskite manganites5A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity8Jahn–Teller distortion in the oxygen evolution reaction: from fundamental insights to catalyst design9Oxygen-vacancy-enabled charge separation in distorted orthorhombic YFeO 37Asymmetric oxygen displacement-induced contrast modulation and multi-state ferroelectricity in distorted perovskite oxides1Controlling the competition between polar and antipolar structures by rumpling in Ruddlesden–Popper layered nitride La3W2N70Enhanced electron–phonon coupling due to layered-perovskites octahedral tilting in hole doped cuprate superconductor0Pb(Mg 1/3 Nb 2/3 )O 3 -induced oxygen octahedral distortions and domain growth for concurrent enhancement of multiple parameters in PNN–PZT0Entropy-engineered perovskite heterointerfaces suppress lattice-distortion-induced carrier localization and operational fatigue0Operando multiscale microscopy visualizes the ionic liquid guided structural evolution of α-MnO2 cathodes for stable zinc batteries1Enhanced Energy-Storage Performance of High-Entropy (1 − x )(NaBiBa)0.205(SrCa)0.1925TiO3- x Bi(Zn2/3Ta1/3)O3 Ceramic under Moderate Electric Field0Microwave-Accelerated Reduction of Sr2CoTi0.7Nb0.3O6–δ: Impact of Sr Non-Stoichiometry on Redox Performance and Limitations for Steam Reoxidation0Mechanistic insight into low-temperature densification and enhanced piezoelectric properties of glass-free PIN-PHT ceramics with LBC composite additive0An Atomic-Scale Chemical Switch for Oxide Ferroelectricity0

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  1. Formation mechanism of Ruddlesden–Popper faults in compressive-strained ABO 3 perovskite superlattices

    Nanoscale · 2021-01-01

    Haoyuan Qi, Xiaodan Chen, E. Benckiser, Meng Qiang Wu, G. Christiani, Gennady Yu. Logvenov, B. Keimer, Ute A. Kaiser

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  2. Comparison of Fe-enhanced oxygen evolution electrocatalysis in amorphous and crystalline nickel oxides to evaluate the structural contribution

    Energy & Environmental Science · 2021-10-27

    Jumi Bak, Tae Gyu Yun, Ji‐Sang An, Hyung Bin Bae, Sung‐Yoon Chung

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  3. Manifestation of the Jahn–Teller effect subject to quadratic T ⊗ e + t 2 problem in ultrasonic attenuation. Case study of CaF2:Cr crystal with isovalent and aliovalent substitution

    Journal of Physics Condensed Matter · 2022-02-09

    Maksim N. Sarychev, Wessam A L Hosseny, Irina V Zhevstovskikh, Vladimir A Ulanov, Gilman S Shakurov, Aleksandr V Egranov, Vladimir T Surikov, Nikita S. Averkiev, Vladimir V Gudkov

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  4. Cuprate Oxyfluorides La2Cu0.8Ni0.2O3F2 and La2CuO3F2 with “Channel-like” Anion Ordering

    Inorganic Chemistry · 2022-10-18

    Jonas Jacobs, James Hester, Stefan G. Ebbinghaus

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  5. Anion‐Dependent Polarization and Piezoelectric Power Generation in Hybrid Halide MAPbX3 (X = I, Br, and Cl) Thin Films with Out‐of‐Plane Structural Adjustments

    Advanced Science · 2022-12-01

    Da Bin Kim, Kyeong Su Jo, Kwan Sik Park, Yong Soo Cho

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  6. Multifunctional catalyst-assisted sustainable reformation of lignocellulosic biomass into environmentally friendly biofuel and value-added chemicals

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    Muhammad Naeem, Muhammad Imran, Shoomaila Latif, Adnan Ashraf, Nazim Hussain, Grzegorz Boczkaj, Wojciech Smułek, Teofil Jesionowski, Muhammad Bilal

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  7. Atomic-scale observation of premelting at 2D lattice defects inside oxide crystals

    Nature Communications · 2023-04-20

    Hye‐Sung Kim, Ji‐Sang An, Hyung Bin Bae, Sung‐Yoon Chung

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  8. Direct Probing of Lattice‐Strain‐Induced Oxygen Release in LiCoO 2 and Li 2 MnO 3 without Electrochemical Cycling

    Advanced Materials · 2023-05-02

    Dongho Kim, Jaejin Hwang, Pilgyu Byeon, Wonsik Kim, Dong Gyu Kang, Hyung Bin Bae, Sang‐Gil Lee, Seung Min Han, Jaekwang Lee, Sung‐Yoon Chung

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  9. Metal Ions versus Protons: Tracking of Charge‐Carrier Insertion into a Cathode Oxide in Aqueous Rechargeable Batteries

    Advanced Functional Materials · 2023-06-25

    Changmin Lee, Youngjae Hong, Dongho Kim, Younghwan Lim, Jang Wook Choi, Sung‐Yoon Chung

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  10. Linking stability with molecular geometries of perovskites and lanthanide richness using machine learning methods

    Computational Materials Science · 2023-10-26

    Sampreeti Bhattacharya, Arkaprava Roy

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  11. Electron-Beam-Induced Formation of Oxygen Vacancies in Epitaxial LaCoO3 Thin Films

    Electronic Materials Letters · 2023-10-30

    Seung Jo Yoo, Tae Gyu Yun, Jae Hyuck Jang, Jihyun Lee, Chang-Hyun Park, Sung‐Yoon Chung

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  12. La 2 SrSc 2 O 7 : A -Site Cation Disorder Induces Ferroelectricity in Ruddlesden–Popper Layered Perovskite Oxide

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  13. Electrochemically Engineered Lanthanum Nickelate as a Promising Transparent Hole-Transport Layer for Bulk Heterojunction Polymer Solar Cells: An Experimental and DFT Study

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  14. Effects of heterovalent ions doping-induced oxygen octahedral distortion and defect chemical change on piezoelectric characteristics and thermal stability of PHT-PIN ceramics

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  15. Atomic Imaging of Multi‐Dimensional Ruddlesden–Popper Interfaces in Lead‐Halide Perovskites

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  16. Local electronic structures of annealing induced phases in cobalt doped TiO 2 nanoparticles: a combined study of transmission electron microscopy and x-ray absorption fine structure spectroscopy

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  17. In-situ electric field-tailored exchange bias in the manganite/ferroelectric multiferroic heterostructures

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  18. Unit‐Cell‐Thickness Electron Confinement by Geometrically Constrained Antipolar Ordering

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  19. Comparing the Impacts of Strain Types on Oxygen-Vacancy Formation in a Perovskite Oxide via Nanometer-Scale Strain Fields

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  20. Atomic‐Level Observation of Potential‐Dependent Variations at the Surface of an Oxide Catalyst during Oxygen Evolution Reaction

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  21. Tunable 5d-t2g Mott State and Monoatomic Layer Two-Dimensional Electron Gas Realized in Spin–Orbit-Coupled SrIrO3 through Heterostructuring

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  22. Deciphering the Atomic-Scale Structural Origin for Photoluminescence Quenching in Tin–Lead Alloyed Perovskite Nanocrystals

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  23. Hybrid improper ferroelectricity in La2Sr (Sc1− x Fe x )2O7 ceramics with double-layered Ruddlesden–Popper structures

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  24. Gigantic-oxidative atomic-layer-by-layer epitaxy for artificially designed complex oxides

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  25. Microwave shock-driven thermal engineering of unconventional cubic 2D LaMnO 3 for efficient oxygen evolution

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  28. Dissociative adsorption of in-situ grown NiBi with oxygen enabling lower friction and wear of nickel-based composite coating at elevated temperature

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  29. Direct Correlation of the Crystalline Phases of La 0.9 Sr 0.1 Co 1– y Fe y O 3−δ with the Partial Oxidation of Methane via In Situ Neutron and Synchrotron Diffraction

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  30. Large electrostrictive response in W-Mg co-doped Na0.5Bi0.5TiO3-based ceramics via defect complex designing

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  31. Effect of ionic-bonding d0 cations on structural durability in barium iridates for oxygen evolution electrocatalysis

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  32. Complex Iridate Solid Solutions for Catalyzing Oxygen Evolution Reaction: Comparison of Elemental Leaching and Stability Numbers

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  33. Atomic insights into topochemical fluorination and strong octahedral tilt in La2CoO4

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  34. Large magnetodielectric coupling in layered perovskite Eu 2 Ti O 4

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  36. Ruddlesden–Popper Defects Act as a Free Surface: Role in Formation and Photophysical Properties of CsPbI 3

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  38. Oxygen vacancy distribution in different regions of La1−xSrxGa1−yMgyO3−δ

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  39. Microstructure Optimization via Grain‐Boundary Segregation to Enhance DC Bias Dielectric Performance of BaTiO 3 Multilayer Ceramic Capacitors

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  40. Lattice-controlled Fe-exsolved perovskite anodes for high-performance and durable ammonia-powered electrochemical systems

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  41. Effect of Ni‐Doped Induced Stacking Faults on the NTC Properties and Aging Stability of La 0.9 Nd 0.1 Al 1‐x Ni x O 3 Ceramics

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  42. Jahn‐Teller Effect: Impact of Distortion on Oxygen Electrocatalysis

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  44. Quasi–two-dimensional ferroelectricity with multiple switchable polarization states in N-H coinjected perovskite manganites

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  45. A-Site Cation Disorder Engineering in Ruddlesden–Popper Layered Perovskite Oxide La 2 (Ba,Sr)In 2 O 7 for Hybrid Improper Ferroelectricity

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  46. Jahn–Teller distortion in the oxygen evolution reaction: from fundamental insights to catalyst design

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  47. Oxygen-vacancy-enabled charge separation in distorted orthorhombic YFeO 3

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  48. Asymmetric oxygen displacement-induced contrast modulation and multi-state ferroelectricity in distorted perovskite oxides

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  49. Controlling the competition between polar and antipolar structures by rumpling in Ruddlesden–Popper layered nitride La3W2N7

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  50. Enhanced electron–phonon coupling due to layered-perovskites octahedral tilting in hole doped cuprate superconductor

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