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RESEARCH PAPER · Annual Review of Materials Research · 2021

Layered Double Perovskites

Hayden A. Evans, Lingling Mao, Ram Seshadri, Anthony Kevin Cheetham

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Layered Double PerovskitesOriginalBismuth/Silver-Based Two-Dimensional Iodide Double and One-Dimensional Bi Perovskites: Interplay between Structural and Electronic Dimensions66A first-principles study on the phase stability and physical properties of a B-site ordered Nd 2 CrFeO 6 double perovskite23The Oxygen Electrode Bifunctionality Studies: La2fenio6 Double Perovskite Nanoparticles14Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics12Chemical Control of Magnetic Ordering in Hybrid Fe–Cl Layered Double Perovskites582021 NIST Center for Neutron Research accomplishments and opportunities2The Renaissance of Functional Hybrid Transition-Metal Halides96Hybrid Layered Double Perovskite Halides of Transition Metals661H Detected Relayed Dynamic Nuclear Polarization15Critical phonon frequency renormalization and dual phonon coexistence in layered Ruddlesden-Popper inorganic perovskites37Factors Constituting Proton Trapping in BaCeO3 and BaZrO3 Perovskite Proton Conductors in Fuel Cell Technology: A Review59Opto-electro-mechanical properties of lead-free hybrid double perovskites Cs2AgSbX6 (X = Cl, Br, I) for solar cells: A first-principles study62An Effective Strategy of Introducing Chirality to Achieve Multifunctionality in Rare‐Earth Double Perovskite Ferroelectrics34Metal Oxynitrides for the Electrocatalytic Reduction of Nitrogen to Ammonia30Analog Memristor of Lead‐Free Cs4CuSb2Cl12 Layered Double Perovskite Nanocrystals as Solid‐State Electronic Synapse for Neuromorphic Computing30Novel Nb5+-doped hexagonal perovskite Ba5In2Al2ZrO13 (structure, hydration, electrical conductivity)6First-principles study on photoelectric properties of all-inorganic two-dimensional double perovskite Cs 3 AgBiBr 711A room-temperature nitrite-based hybrid bimetal molecular ferroelectric material: [( R )-3-quinuclidinol] 2 [LiCo(NO 2 ) 6 ]5Challenges and future prospects2Elucidating the Mn2+ Dopant Sites in Two-Dimensional Na–In Halide Perovskite15Investigation of thermoelectric response, mechanical stability and thermodynamic behavior of Sr2MgPdO6 and Sr2MgPtO6 double perovskites: A DFT insights4Hybrid Double Perovskite Derived Halides Based on Bi and Alkali Metals (K, Rb): Diverse Structures, Tunable Optical Properties and Second Harmonic Generation Responses52Hybrid Double Perovskite Derived Halides Based on Bi and Alkali Metals (K, Rb): Diverse Structures, Tunable Optical Properties and Second Harmonic Generation Responses5Two-Dimensional Halide Pb-Perovskite–Double Perovskite Epitaxial Heterostructures55Protonic transport in the novel complex oxide Ba5Y0.5In1.5Al2ZrO13 with intergrowth structure13Testing the limits of the global instability index19Wide‐Bandgap Perovskite‐Inspired Materials: Defect‐Driven Challenges for High‐Performance Optoelectronics65Energetic Stability and Band-Edge Orbitals of Layered Inorganic Perovskite Compounds for Solar Energy Applications20D Pyramid‐intercalated 2D Bimetallic Halides with Tunable Electronic Structures and Enhanced Emission under Pressure180D Pyramid‐intercalated 2D Bimetallic Halides with Tunable Electronic Structures and Enhanced Emission under Pressure1Hybrid Iodide Perovskites of Divalent Alkaline Earth and Lanthanide Elements16Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation28A reflection on ‘The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA) 2 KBiCl 6 (MA = methylammonium)’4High Luminescence in Layered Double Perovskite via Formation of Terbium Intercalation Complex9Spin glass states in multicomponent layered perovskites10Chemical Control of Optical Band Gap and Magnetic Properties in Fe-Alloyed Na–In Halide Layered Perovskites4Investigating structural, phonons, optoelectronics, and thermodynamic properties of lead-free double perovskites of A-site cation ordering in LiXTl2Cl6 (X= Sc and Y) compounds for green energy applications2New Lead‐free Hybrid Layered Double Perovskite Halides: Synthesis, Structural Transition and Ultralow Thermal Conductivity5New Lead‐free Hybrid Layered Double Perovskite Halides: Synthesis, Structural Transition and Ultralow Thermal Conductivity20Three-Dimensional Bimetallic Ammonium K–Eu Nitrate with a Rare (6,6)-Connected Ion Topology Exhibiting Structural Phase Transition and Photoluminescence Properties8A double perovskite BaSrTiMnO6: Synthesis, microstructural, transport and optical properties for NTC thermistor applications18Electrocatalysis in Solid Oxide Fuel Cells and Electrolyzers141Multi-physical channels response in a novel layered perovskite: (trans-4-methylcyclohexylammonium)2[CuCl4]4Pb2MgXO6 (X = W and Te) Double Perovskites: New Insights into Their Electronic, Elastic, Optic and Thermoelectric Properties5Insight view of thermal, mechanical and structural behavior of novel double perovskites Ba2XSbO6 (X = Sc, Y): A DFT based study9Exploring Aqueous Solution‐Processed Pseudohalide Rare‐Earth Double Perovskite Ferroelectrics toward X‐Ray Detection with High Sensitivity6Exploring Aqueous Solution‐Processed Pseudohalide Rare‐Earth Double Perovskite Ferroelectrics toward X‐Ray Detection with High Sensitivity25Boosting selective Cs+ uptake through the modulation of stacking modes in layered niobate-based perovskites30Layered and Low-Dimensional Lead, Silver, and Bismuth Halide Perovskites Directed by Halogen-Substituted Spacer Cations12Iodide Double Perovskites and the Limits of their Structural Stability8Constructing dual-mode optical thermometry based on Mn4+/Eu3+ luminescence intensity ratio and lifetime for double perovskite Ca2ScNbO6 phosphors26Comprehensive impedance spectroscopy, Raman, and infrared studies of the ferroelectric properties and application of BiFeWO 63Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities39High-throughput screening of Ruddlesden–Popper perovskites with layer-dependent mechanical and thermal properties using DFT calculations6Thermally Controlled A-site Cation Ordering and Coupled Polarity in Double Perovskite NaLaZr2O62Research progress of perovskite/carbon composites in the field of electrocatalysis4Correlated percolation and disordered Ising magnetism in doped double perovskites0Graphene-Based Catalysis in Wastewater Treatment: Electrocatalytic and Photocatalytic Innovations for Sustainable Development3Facet-specific nitrogen vacancy engineering in BaMO2N (M = Ta, Nb) for enhanced electrochemical ammonia production: Insights from first-principles calculations0X-ray Emission Spectropolarimetry of Strongly Anisotropic Single Crystal Systems Using a Rowland Circle Geometry0DFT driven insights into physical, opto-electronic attributes of novel layered Sr2MO4 (M = Hf, Ti, V) perovskites for advanced solar cell applications0Resolving 209Bi sites in mixed-halide double perovskites at 28 T2A Tb 3+ -Based Hybrid Rare-Earth Double Perovskite with Ferroelastic Switching and Long Photoluminescence Lifetime6An abnormal decrease in Curie temperature in pseudohalide rare-earth double perovskite ferroelastics driven by lanthanide contraction0Applications of Perovskite Materials in Energy Storage and Efficiency Systems3Deciphering cation-driven structure–property correlations in 0D hybrid ruthenium halide perovskites0Na 2 Cu 2 TeO 6 : a potential material for high solar cell efficiency and superior energy-harvesting performance0A review of cobalt-free positrodes for protonic ceramic cells: bridging fundamental insights and technological development1A Three-Dimensional Organic–Inorganic Hybrid Perovskite-Type Molecular Ferroelectric Material [3.2.2-H 2 dabcn]Rb(NO 3 ) 30Quantifying hybrid lead halide perovskites from multiple viewpoints: a human-guided machine learning approach1Perpendicular switching of polarization in layered ferroelectrics1Challenges and Opportunities for Layered Double Perovskite Solar Cells0

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  2. A first-principles study on the phase stability and physical properties of a B-site ordered Nd 2 CrFeO 6 double perovskite

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  3. The Oxygen Electrode Bifunctionality Studies: La2fenio6 Double Perovskite Nanoparticles

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  4. Symmetry Analysis of Magnetoelectric Effects in Perovskite-Based Multiferroics

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  5. Chemical Control of Magnetic Ordering in Hybrid Fe–Cl Layered Double Perovskites

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  6. 2021 NIST Center for Neutron Research accomplishments and opportunities

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  7. The Renaissance of Functional Hybrid Transition-Metal Halides

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  8. Hybrid Layered Double Perovskite Halides of Transition Metals

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  9. 1H Detected Relayed Dynamic Nuclear Polarization

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  10. Critical phonon frequency renormalization and dual phonon coexistence in layered Ruddlesden-Popper inorganic perovskites

    Physical review. B./Physical review. B · 2022-05-13

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  11. Factors Constituting Proton Trapping in BaCeO3 and BaZrO3 Perovskite Proton Conductors in Fuel Cell Technology: A Review

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  12. Opto-electro-mechanical properties of lead-free hybrid double perovskites Cs2AgSbX6 (X = Cl, Br, I) for solar cells: A first-principles study

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    Maryam Babaei, Vahid Ahmadi, Ghafar Darvish

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  13. An Effective Strategy of Introducing Chirality to Achieve Multifunctionality in Rare‐Earth Double Perovskite Ferroelectrics

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  14. Metal Oxynitrides for the Electrocatalytic Reduction of Nitrogen to Ammonia

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  15. Analog Memristor of Lead‐Free Cs4CuSb2Cl12 Layered Double Perovskite Nanocrystals as Solid‐State Electronic Synapse for Neuromorphic Computing

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  16. Novel Nb5+-doped hexagonal perovskite Ba5In2Al2ZrO13 (structure, hydration, electrical conductivity)

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  17. First-principles study on photoelectric properties of all-inorganic two-dimensional double perovskite Cs 3 AgBiBr 7

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  18. A room-temperature nitrite-based hybrid bimetal molecular ferroelectric material: [( R )-3-quinuclidinol] 2 [LiCo(NO 2 ) 6 ]

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  19. Challenges and future prospects

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  20. Elucidating the Mn2+ Dopant Sites in Two-Dimensional Na–In Halide Perovskite

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  21. Investigation of thermoelectric response, mechanical stability and thermodynamic behavior of Sr2MgPdO6 and Sr2MgPtO6 double perovskites: A DFT insights

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  22. Hybrid Double Perovskite Derived Halides Based on Bi and Alkali Metals (K, Rb): Diverse Structures, Tunable Optical Properties and Second Harmonic Generation Responses

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  23. Hybrid Double Perovskite Derived Halides Based on Bi and Alkali Metals (K, Rb): Diverse Structures, Tunable Optical Properties and Second Harmonic Generation Responses

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  24. Two-Dimensional Halide Pb-Perovskite–Double Perovskite Epitaxial Heterostructures

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  25. Protonic transport in the novel complex oxide Ba5Y0.5In1.5Al2ZrO13 with intergrowth structure

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  28. Energetic Stability and Band-Edge Orbitals of Layered Inorganic Perovskite Compounds for Solar Energy Applications

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  29. 0D Pyramid‐intercalated 2D Bimetallic Halides with Tunable Electronic Structures and Enhanced Emission under Pressure

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  30. 0D Pyramid‐intercalated 2D Bimetallic Halides with Tunable Electronic Structures and Enhanced Emission under Pressure

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  31. Hybrid Iodide Perovskites of Divalent Alkaline Earth and Lanthanide Elements

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  32. Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation

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  33. A reflection on ‘The synthesis, structure and electronic properties of a lead-free hybrid inorganic–organic double perovskite (MA) 2 KBiCl 6 (MA = methylammonium)’

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  34. High Luminescence in Layered Double Perovskite via Formation of Terbium Intercalation Complex

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  35. Spin glass states in multicomponent layered perovskites

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  36. Chemical Control of Optical Band Gap and Magnetic Properties in Fe-Alloyed Na–In Halide Layered Perovskites

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  37. Investigating structural, phonons, optoelectronics, and thermodynamic properties of lead-free double perovskites of A-site cation ordering in LiXTl2Cl6 (X= Sc and Y) compounds for green energy applications

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  38. New Lead‐free Hybrid Layered Double Perovskite Halides: Synthesis, Structural Transition and Ultralow Thermal Conductivity

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  40. Three-Dimensional Bimetallic Ammonium K–Eu Nitrate with a Rare (6,6)-Connected Ion Topology Exhibiting Structural Phase Transition and Photoluminescence Properties

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  41. A double perovskite BaSrTiMnO6: Synthesis, microstructural, transport and optical properties for NTC thermistor applications

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  42. Electrocatalysis in Solid Oxide Fuel Cells and Electrolyzers

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  43. Multi-physical channels response in a novel layered perovskite: (trans-4-methylcyclohexylammonium)2[CuCl4]

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  44. Pb2MgXO6 (X = W and Te) Double Perovskites: New Insights into Their Electronic, Elastic, Optic and Thermoelectric Properties

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  45. Insight view of thermal, mechanical and structural behavior of novel double perovskites Ba2XSbO6 (X = Sc, Y): A DFT based study

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  46. Exploring Aqueous Solution‐Processed Pseudohalide Rare‐Earth Double Perovskite Ferroelectrics toward X‐Ray Detection with High Sensitivity

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  47. Exploring Aqueous Solution‐Processed Pseudohalide Rare‐Earth Double Perovskite Ferroelectrics toward X‐Ray Detection with High Sensitivity

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  48. Boosting selective Cs+ uptake through the modulation of stacking modes in layered niobate-based perovskites

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  49. Layered and Low-Dimensional Lead, Silver, and Bismuth Halide Perovskites Directed by Halogen-Substituted Spacer Cations

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  50. Iodide Double Perovskites and the Limits of their Structural Stability

    Chemistry - A European Journal · 2024-11-06

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