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RESEARCH PAPER · Crystal Growth & Design · 2018

Exploring Potential Beryllium-free, Deep-Ultraviolet Optical Crystals in the Rare Earth Fluoride Carbonate–Water System

Qian Wang, Fangfang He, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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Exploring Potential Beryllium-free, Deep-Ultraviolet Optical Crystals in the Rare Earth Fluoride Carbonate–Water SystemOriginalCation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response129Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution66Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Rb 3 SbF 3 (NO 3 ) 3 : an excellent antimony nitrate nonlinear optical material with a strong second harmonic generation response fabricated by a rational multi-component design44RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores79Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework61Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties24Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O545Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design302Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design51K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence61A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters50The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties98CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure49Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)10Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Facile synthesis of a sandwiched Ti3C2Tx MXene/nZVI/fungal hypha nanofiber hybrid membrane for enhanced removal of Be(II) from Be(NH) complexing solutions97Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps7KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence15Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)14Solid state structures and solution behaviour of tetranuclear lanthanide( iii ) carbonate-bridged coordination compounds of chiral 3 + 3 amine macrocycle4Beryllium contamination and its risk management in terrestrial and aquatic environmental settings63Extracting Beryllium from Beryllium Fluoride by Magnesiothermic Reduction9LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2From strategic critical metal to hazardous solid waste: integrated management of beryllium-containing wastes and environmental risk assessment0

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  1. Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties

    Dalton Transactions · 2018-01-01

    Fangfang He, Lei Wang, Cuifang Hu, Jing Wen Zhou, Qian Li, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  2. Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response

    Chemical Science · 2018-01-01

    Guohong Zou, Zhien Lin, Hongmei Zeng, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  3. Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities

    Crystal Growth & Design · 2018-09-11

    Fangfang He, Qian Wang, Cuifang Hu, Wen Jun He, Xueying Luo, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  4. A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)3

    Inorganic Chemistry · 2018-10-09

    Yaoguo Shen, Yi Jin Yang, Sangen Zhao, Xianfeng Li, Qingran Ding, Yanqiang Li, Shuai Liu, Zheshuai Lin, Junhua Luo

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  5. An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution

    Journal of Materials Chemistry C · 2019-01-01

    Fei Yang, Lijuan Huang, Lijuan Huang, Xiaoyu Zhao, Ling Huang, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  6. Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size

    Inorganic Chemistry Frontiers · 2019-01-01

    Qian Wang, Lei Wang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  7. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  8. Rb 3 SbF 3 (NO 3 ) 3 : an excellent antimony nitrate nonlinear optical material with a strong second harmonic generation response fabricated by a rational multi-component design

    Dalton Transactions · 2019-01-01

    Lei Wang, Fei Yang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  9. RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores

    Journal of Materials Chemistry C · 2019-01-01

    Fangfang He, Yalan Deng, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  10. Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

    Chemical Communications · 2019-01-01

    Yiting Zhang, Ying Long, Xuehua Dong, Lei Wang, Ling Huang, Hongmei Zeng, Zhien Lin, Xin Wang, Guohong Zou

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  11. Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties

    Inorganic Chemistry · 2019-02-13

    Qi Wei, Chao He, Bang‐Di Ge, Meng-Xin Wan, Li Wei, Guo‐Ming Wang

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  12. Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O5

    Inorganic Chemistry · 2019-04-09

    Qian Wang, Fei Yang, Xing Wang, Jing Wen Zhou, Jia Ju, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  13. Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 12

    Dalton Transactions · 2019-12-30

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  14. (NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization

    Chemical Communications · 2020-01-01

    Yalan Deng, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  15. Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design

    Chemical Science · 2020-01-01

    Guohong Zou, Kang Min Ok

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  16. Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design

    Dalton Transactions · 2020-01-01

    Fangfang He, Yuwei Ge, Xiaoyu Zhao, Jing He, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  17. K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence

    Journal of Alloys and Compounds · 2020-04-15

    Fei Yang, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  18. A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters

    Inorganic Chemistry · 2020-05-22

    Xuehua Dong, Ying Long, Xiaoyu Zhao, Ling Huang, Hongmei Zeng, Zhien Lin, Xin Wang, Guohong Zou

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  19. The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties

    Coordination Chemistry Reviews · 2020-08-08

    Fei Yang, Lei Wang, Ling Huang, Guohong Zou

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  20. CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure

    Inorganic Chemistry · 2020-08-26

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  21. Hydrogen-Bond-Assisted Alignment of [MCu(SeO 3 ) 4 Cl(H 2 O)] 4– (M = Fe, Ga) Anionic Layers to Form Two Polar Oxychlorides: Pb 2 MCu(SeO 3 ) 4 Cl(H 2 O)

    Inorganic Chemistry · 2020-12-30

    Lei Geng, Chang‐Yu Meng, Hong‐Yan Lu

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  22. Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O

    Journal of Solid State Chemistry · 2021-02-28

    Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

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  23. Facile synthesis of a sandwiched Ti3C2Tx MXene/nZVI/fungal hypha nanofiber hybrid membrane for enhanced removal of Be(II) from Be(NH) complexing solutions

    Chemical Engineering Journal · 2021-04-08

    Runhua Chen, Yuying Cheng, Ping Wang, Yangyang Wang, Qingwei Wang, Zhihui Yang, Congjian Tang, Siyuan Xiang, Siyuan Luo, Shunhong Huang, Changqing Su

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  24. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  25. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

    Journal of Alloys and Compounds · 2021-11-24

    Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  26. Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps

    Inorganic Chemistry Frontiers · 2021-11-26

    Yunqiao Guo, Yalan Deng, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  27. KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuan Hua Lin, Chun‐Li Hu, Zhi Gang Fang, Jin Chen, Weijie Xie, Yan Chen, Jianpu Wang, Jiang‐Gao Mao

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  28. Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)

    Crystal Growth & Design · 2022-06-10

    Hongmei Wang, Qiang Wang, Qin Wang, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  29. Solid state structures and solution behaviour of tetranuclear lanthanide( iii ) carbonate-bridged coordination compounds of chiral 3 + 3 amine macrocycle

    Dalton Transactions · 2023-01-01

    Karol Wydra, Vasyl Kinzhybalo, Jerzy Lisowski

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  30. Beryllium contamination and its risk management in terrestrial and aquatic environmental settings

    Environmental Pollution · 2023-01-13

    Shiv Shankar Bolan, Shiv Bolan, Hasintha Wijesekara, Mohsin Tanveer, Vanessa L. Boschi, Lokesh P. Padhye, Madhuni Madhushika Wijesooriya, Lei Wang, Tahereh Jasemizad, Chensi Wang, Tao Zhang, Jörg Rinklebe, Hailong Wang, Su Shiung Lam, Kadambot H. M. Siddique, M.B. Kirkham, Nanthi Sirangie Bolan

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  31. Extracting Beryllium from Beryllium Fluoride by Magnesiothermic Reduction

    Metallurgical and Materials Transactions B · 2024-03-25

    Qinghua Tian, Chao Wang, Hao Li, Dawei Yu, Xueyi Guo, Junjie Wang, Pengfei Liu

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  32. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  33. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

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  34. From strategic critical metal to hazardous solid waste: integrated management of beryllium-containing wastes and environmental risk assessment

    Separation and Purification Technology · 2026-07-06

    Jiangjie Fang, Wenjun Fu, Yongdian Yue, Chuanxi Peng, Xinzhuang Fu, Y P Chen, Wei Sun, Tong Yue

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