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RESEARCH PAPER · Inorganic Chemistry · 2018

A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)3

Yaoguo Shen, Yi Jin Yang, Sangen Zhao, Xianfeng Li, Qingran Ding, Yanqiang Li, Shuai Liu, Zheshuai Lin, Junhua Luo

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A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)3OriginalCs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra21Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal14Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O72Enhanced luminescence of a new red phosphor Na13Sr2Ta2(PO4)9:Eu3+ by co-doping charge compensators Li+/Na+/K+21Energy transfer, multi-colour emission and high thermal stability behaviour of K 2 Tb 1−x Eu x Hf(PO 4 ) 3 with langbeinite-type structure7Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)26Aliovalent-substituted synthesis for a non-centrosymmetric phosphate with enhanced nonlinear-optical response5A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties9Langbeinite Phosphates KPbM2(PO4)3(M = Cr, Fe): Synthesis, Structure, Thermal Expansion, and Magnetic Properties Investigation25Dual-color upconversion photoluminescence induced by disordered Yb3+-Ti4+ pairs and defects in highly stable langbeinite-type Rb2Ti0.80Yb1.20(PO4)3 single crystal6K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence33A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106Double-site Eu3+ occupation in the langbeinite-type phosphate phosphor toward adjustable emission for pc-WLEDs28Recent advances in nonlinear optical rare earth structures63Crystal growth and structure of a new langbeinite-type phosphate: Pb2CoFe(PO4)33CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection26From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property Enhancement34Co-substitution design: a new glaserite-type rare-earth phosphate K 2 RbSc(PO 4 ) 2 with high structural tolerance6Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Synthesis, structural characterization and magnetic behavior of a novel phosphate: K4(Co0.25Fe0.75)4(PO4)510Synthesis and characterization of a new magnesium molybdates Tl1.85M0.15Mg2(MoO4)3 (M = K, Rb) with a langbeinite type structure3(SO3CF3)−: A Non‐π‐Conjugated Motif for Nonlinear Optical Crystals Transparent into the Deep‐Ultraviolet Region23Hydroxyl-Driven Enhanced Birefringence in Borophosphates3NaZr 2 (PO 4 ) 3 – a cubic langbeinite-type sodium-ion solid conductor12Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )4Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4Two mixed P–O anionic phosphates with a distinctive structural transformation and deep ultraviolet cutoff edge0Synthesis, structural and magnetic investigation of the mixed-metal Langbeinite phosphate Ba2FeCo(PO4)30Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering0Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms3Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition0Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100

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  1. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  2. LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra

    Inorganic Chemistry Frontiers · 2019-01-01

    Qiong Liu, Cong Hu, Xin Su, Maierhaba Abudoureheman, Shilie Pan, Zhihua Yang

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  3. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019-01-01

    Shuaishuai Hu, Zhi Su

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  4. LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal

    Inorganic Chemistry · 2019-05-10

    Yunfei Li, Fei Liang, Huimin Song, Wang Liu, Zheshuai Lin, Guochun Zhang, Yicheng Wu

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  5. Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O7

    Zeitschrift für anorganische und allgemeine Chemie · 2019-07-10

    Lingyun Dong, Xusheng Ge, Pengfei Zhang, Qian Li, Sufang Sun, Shigang Shen

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  6. Enhanced luminescence of a new red phosphor Na13Sr2Ta2(PO4)9:Eu3+ by co-doping charge compensators Li+/Na+/K+

    Journal of Luminescence · 2019-12-17

    Yanan Li, Dan Zhao, Lin‐Ying Shi, Shao-Jie Dai, Yan-Ping Fan, Baozhong Liu, Qingxia Yao

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  7. Energy transfer, multi-colour emission and high thermal stability behaviour of K 2 Tb 1−x Eu x Hf(PO 4 ) 3 with langbeinite-type structure

    CrystEngComm · 2020-01-01

    Dan Zhao, Shirui Zhang, Ruijuan Zhang, Yan-Ping Fan, Baozhong Liu, Lin‐Ying Shi

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  8. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  9. Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)

    Inorganic Chemistry Frontiers · 2020-01-01

    Zhongfu Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  10. Aliovalent-substituted synthesis for a non-centrosymmetric phosphate with enhanced nonlinear-optical response

    Journal of Solid State Chemistry · 2020-04-08

    Yaoguo Shen, Zhiqun Liu, Hualiang Yu, Bi‐Cheng Zhou

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  11. A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties

    Acta Crystallographica Section C Structural Chemistry · 2020-07-22

    Hua Nan, Li Chen, Rui-Juan Zhang, Dan Zhao

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  12. Langbeinite Phosphates KPbM2(PO4)3(M = Cr, Fe): Synthesis, Structure, Thermal Expansion, and Magnetic Properties Investigation

    Inorganic Chemistry · 2020-09-03

    Daneshwaran Balaji, Triveni Rajashekhar Mandlimath, Jie Chen, Yoshitaka Matsushita, Sathasivam Pratheep Kumar

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  13. Dual-color upconversion photoluminescence induced by disordered Yb3+-Ti4+ pairs and defects in highly stable langbeinite-type Rb2Ti0.80Yb1.20(PO4)3 single crystal

    Journal of Alloys and Compounds · 2020-12-07

    Ziqing Li, Pengfei Zhu, Jimin Ding, Yang Chen, Zhenyan Wang, Nianjing Ji, Xiulan Duan, Huaidong Jiang

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  14. K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence

    Inorganic Chemistry Frontiers · 2020-12-30

    Ying Hou, Bingbing Zhang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  15. A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

    Coordination Chemistry Reviews · 2021-01-19

    Junhui Dang, Dajiang Mei, Yuandong Wu, Zheshuai Lin

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  16. Double-site Eu3+ occupation in the langbeinite-type phosphate phosphor toward adjustable emission for pc-WLEDs

    Journal of Alloys and Compounds · 2021-04-13

    Bin Yu, Yuchan Li, Yunjian Wang, Lei Geng

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  17. Recent advances in nonlinear optical rare earth structures

    Journal of Rare Earths · 2021-07-15

    Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

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  18. Crystal growth and structure of a new langbeinite-type phosphate: Pb2CoFe(PO4)3

    Materials Today Proceedings · 2022-01-01

    Fouad Alloun, Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, Ayoub Kaaouass, Lahcen El Ammari

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  19. CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection

    Inorganic Chemistry · 2022-03-01

    Yaoguo Shen, Longjie Huang, Zhifeng Wang, Yingwu Zhou, Xiaoling Xue, Hong Lin, Renwen Yan, Sangen Zhao, Junhua Luo

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  20. From Phosphate Fluoride to Fluorophosphate: Design of Novel Ultraviolet/Deep-Ultraviolet Nonlinear Optical Materials for BePO3F with Optical Property Enhancement

    ACS Applied Materials & Interfaces · 2022-08-18

    Mengfan Wu, Junwei Feng, Congwei Xie, Abudukadi Tudi, Dongdong Chu, Juanjuan Lu, Shilie Pan, Zhihua Yang

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  21. Co-substitution design: a new glaserite-type rare-earth phosphate K 2 RbSc(PO 4 ) 2 with high structural tolerance

    Dalton Transactions · 2023-01-01

    Jingfang Zhou, Pifu Gong, Mingjun Xia, Qian Wu

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  22. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  23. Synthesis, structural characterization and magnetic behavior of a novel phosphate: K4(Co0.25Fe0.75)4(PO4)5

    Solid State Sciences · 2023-03-28

    Fouad Alloun, Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, Abdelilah Lahmar, M. El Marssi, Lahcen El Ammari

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  24. Synthesis and characterization of a new magnesium molybdates Tl1.85M0.15Mg2(MoO4)3 (M = K, Rb) with a langbeinite type structure

    Solid State Sciences · 2023-07-01

    Victoria G. Grossman, Мaxim S. Моlokeev, Баир Гармаевич Базаров, Jibzema G. Bazarova

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  25. (SO3CF3)−: A Non‐π‐Conjugated Motif for Nonlinear Optical Crystals Transparent into the Deep‐Ultraviolet Region

    Advanced Optical Materials · 2023-10-09

    Bohui Xu, Pifu Gong, Fan Liu, Xingyu Zhang, Hao Huo, Zheshuai Lin

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  26. Hydroxyl-Driven Enhanced Birefringence in Borophosphates

    Inorganic Chemistry · 2023-11-22

    Yang Xia, Wen-Bin Zhang, Xueting Pan, Xueling Hou, Shujuan Han

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  27. NaZr 2 (PO 4 ) 3 – a cubic langbeinite-type sodium-ion solid conductor

    Dalton Transactions · 2024-01-01

    Sergey N. Marshenya, Alexey G. Scherbakov, Artem D. Dembitskiy, Alexander A. Golubnichiy, Ivan A. Trussov, Aleksandra A. Savina, Sergey M. Kazakov, Dmitry A. Aksyonov, Evgeny V. Antipov, Stanislav S. Fedotov

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  28. Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )

    Dalton Transactions · 2024-01-01

    Jiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai An

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  29. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  30. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  31. Two mixed P–O anionic phosphates with a distinctive structural transformation and deep ultraviolet cutoff edge

    Dalton Transactions · 2025-01-01

    Lei Wu, Hongyu Huang, Jialong Wang, Qun Jing, Yi Huang, Xuebin Yu, Zhaohui Chen

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  32. Synthesis, structural and magnetic investigation of the mixed-metal Langbeinite phosphate Ba2FeCo(PO4)3

    Inorganic Chemistry Communications · 2025-07-01

    Fouad Alloun, Adam Bouraima, Ayoub Kaaouass, Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, M. El Marssi, Abdelilah Lahmar, Lahcen El Ammari

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  33. Tuning the Anionic Configuration in ASc2(P2O7)2 (A = Ba, Pb) through A-Site Cationic Coordination Engineering

    Inorganic Chemistry · 2025-09-05

    Bao Jiang, Hongheng Chen, Xianmeng He, Lei Wu, Xueyin Fu, Yi Huang, Qun Jing, Zhaohui Chen

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  34. Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms

    Communications Chemistry · 2025-11-27

    Yu Wang, Lanxin Li, Tao Bo, Zhenyu Han, Yongliang Tang, Wenwen Lin, Meng Zhang, Jie Qiu, Lei Zhang

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  35. Sn 4+ /Sn 2+ Aliovalent Substitution: A Strategy for Local Structure Engineering to Enhance Birefringence and Trigger Structural Symmetry Transition

    Inorganic Chemistry · 2026-01-29

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Qun Jing, Yu-hong Su, Zhaohui Chen

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  36. Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 10

    European Journal of Inorganic Chemistry · 2026-09-15

    Jingru Xu, Jiawei Zhao, Paipai Zhang, Juhui Cui, Hong Lei Du, Minqiang Gai

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