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RESEARCH PAPER · Coordination Chemistry Reviews · 2018

The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups

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The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groupsOriginalBaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response129Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material93The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336Physical Properties of a Promising Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F15A review on the development of infrared nonlinear optical materials with triangular anionic groups38Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks12Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation27Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges3Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework61Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15Abrupt Structural Transformation in Asymmetric ABPO4F (A = K, Rb, Cs)21BeO6 Trigonal Prism with Ultralong Be–O Bonds Observed in a Deep Ultraviolet Optical Crystal Li13BeBe6B9O2712Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates268Ba10In6Zn7S26-nZnS: An Inorganic Composite System with Interface Phase-Matching Tuned for High-Performance Infrared Nonlinear Optical Materials13BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O545KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Ba2M(C3N3O3)2 (M = Sr, Pb): Band Engineering from p−π Interaction via Homovalent Substitution in Metal Cyanurates Containing Planar π-Conjugated Groups39Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response35Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Facile Growth of an Ultraviolet Hydroisocyanurate Crystal with Strong Nonlinearity and a Wide Phase-Matching Region from π-Conjugated (HC3N3O3)2– Groups45K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 483Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O721Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs22Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook145NaK 15 [B 4 O 5 (OH) 4 ] 6 (NO 2 ) 2 (CO 3 )·7H 2 O: assembly of an unprecedented mixed anion inorganic compound via a facile hydrothermal route4Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles146Charge transfer and nonlinear optical properties of anthraquinone D-π-A dyes in relation with the DFT based molecular descriptors and perturbational potential41Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials37Facile synthesis, characterization and intensity-dependent nonlinear absorption of Ni-doped (γ and β)-BaB2O4 nanostructures10Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit75Aliovalent-substituted synthesis for a non-centrosymmetric phosphate with enhanced nonlinear-optical response5A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides113Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Borates as promising electrode materials for rechargeable batteries92Anomalous mechanical materials squeezing three-dimensional volume compressibility into one dimension28Mechanochemical Synthesis of an Ionic Cocrystal with Large Birefringence Resulting from Neutral Planar π-Conjugated Groups26Borates: A Rich Source for Optical Materials1089Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11To improve the key properties of nonlinear optical crystals assembled with tetrahedral functional building units46BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]9A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra13Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials111Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application167Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application18Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1From Centrosymmetry to Noncentrosymmetry: Tailoring the Structural Arrangements of Carbonates with Strong Nonlinear Optical Response through Partial Anion Substitution33Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching31Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect14Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family11Analysis of physical and mechanical traits and nuclear radiation transmission aspects of Gallium(III) trioxide constituting Bi2O3-B2O3 glasses20Chalcogen Bond Involving Zinc(II)/Cadmium(II) Carbonate and Its Enhancement by Spodium Bond9Enhancement of band gap and birefringence induced via π -conjugated chromophore with “tail effect”28Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold17Guanidinium Fluorooxoborates as Efficient Metal-free Short-Wavelength Nonlinear Optical Crystals140A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency33Linear unit BN 2 : a novel birefringence-enhanced fundamental module with sp orbital hybridization9LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence16Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate33Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence0Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects37Synergistic effect of 2 [V 2 P 2 O 14 ] ∞ layers and hydrogen bonds inducing large birefringence in M(VO) 2 (PO 4 ) 2 ·4H 2 O (M = Ca, Sr, Ba) systems4Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs17New double nonlinear-optical borate Rb3SmB6O12: Synthesis, structure and spectroscopic properties26The dependence of crystal structure and ultraviolet nonlinear optical property of KBe2BO3F2 by density functional theory and π-conjugate confinement2Advances in second-order nonlinear optical sulfates38Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)212Strong Nonlinearity Induced by Coaxial Alignment of Polar Chain and Dense [BO3] Units in CaZn2(BO3)2212One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Enhanced Interlayer Interaction and Second-Harmonic-Generation Response in a KBe 2 BO 3 F 2 -Type Inorganic–Organic Hybrid Zinc Borate33Orbital projection technique to explore the materials genomes of optical susceptibilities5A Theoretical Perspective to Study the Optical Properties of Tetrafluoroborates4Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters9Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters139Cation Regulation to Investigate the Chalcogenide Borate RE6Nb2MgSB8O26 (RE = La–Nd) Family12Yin–Yang Complementarity Strategy Achieving Giant Optical Anisotropy in a Metal-free Birefringent Material C(NH2)3(HC4O4)14Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response50The Microscopic Origin of Second Harmonic Generation Response: The Spatial Structure of Instantaneous Dipole Moments in Electron Excitation8The Microscopic Origin of Second Harmonic Generation Response: The Spatial Structure of Instantaneous Dipole Moments in Electron Excitation1Dual-Ligand-Oriented Design of Noncentrosymmetric Complexes with Nonlinear-Optical Activity11NaK5Zn2(B5O10)2 and β-K3ZnB5O10: Two Zincoborates with Deep-UV Cutoff Edge9Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence91Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence18Borate-Based Compounds as Mixed Polyanion Cathode Materials for Advanced Batteries22Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials128Enhanced Second-Harmonic-Generation Response in a KH2PO4-Type Calcium Nitrate Carboxylate with Unusual Three-Dimensional Inorganic and Organic Connections3Ba 3 (BS 3 )(PS 4 ): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS 3 ] units8Compounds consisting of coplanar π-conjugated B3O6-typed structures: An emerging source of ultraviolet nonlinear optical materials20Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformation13Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0Facile hydrothermal synthesis of N-doped fluorescent carbon dots for selective detection of insecticide parathion3Polymorphism of LiCdBO3: Crystal structures, phase transitions and optical characterizations10Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses5Expanding gaudefroyite family to Sr2MBi(REEO)3(BO3)4 (M = Ca, Sr, Ba; REE = Y, Eu) borates with large second harmonic generation responses8SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation5Possibility of lithium sulfate borate-based glass doping with Ni and Mn ions in energy storage application5Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates17Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials18Nonlinear optical crystals KPb3(3-C5H4NCOO)2Br5 and KPb3(3-C5H4NCOO)2Cl3Br2 with new Pb-centered nitrogen-halide polyhedrons obtained by the halide anionic substitution4Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route8“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36Host–Guest Symmetry and Charge Matching in Glycine-Templated Metal Sulfate–Oxalates Obtained by a Solvent-Free Method9Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks15The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Halide-Induced Band Gap Enhancement from Ba2SnSe4 to KBa2SnSe4Cl2Electronic Structure Modulation of Nanographenes for Second Order Nonlinear Optical Molecular Materials3Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties3Breaking the Inherent Interarrangement of [B3O6] Clusters for Nonlinear Optics with Orbital Hybridization Enhancement142Ba 4 B 14 O 25 : A Deep Ultraviolet Transparent Nonlinear Optical Crystal with Strong Second Harmonic Generation Response Achieved by a Boron‐Rich Closed‐Loop Strategy12Compositional Deformations, Absorption Spectroscopy, and Low-Temperature X-Ray Diffraction of Sr1 – xBaxBi2B2O7 Solid Solutions2(C(NH2)3)2(I2O5F)(IO3)(H2O) and C(NH2)3IO2F2: Two Guanidine Fluorooxoiodates with Wide Band Gap and Large Birefringence20“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8A highly birefringent metal-free crystal assembled by cooperative non-covalent interactions30Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Solvent-free synthesis and optical properties of two open-framework metal oxalates with zeolitic ABW and diamondoid topologies3Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80[C(NH2)3][B(C2O2H4)2]: An Organic–Inorganic Hybrid Borate Containing Nonlinear-Optical Active Unit [B(C2O2H4)2]− with Solar-Blind-Region Optical Nonlinearity16A perspective on deep-ultraviolet nonlinear optical materials13

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  1. BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance

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  2. Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response

    Chemical Science · 2018-01-01

    Guohong Zou, Zhien Lin, Hongmei Zeng, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  3. Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material

    Journal of Materials Chemistry C · 2018-01-01

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  4. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

    Dalton Transactions · 2018-01-01

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  5. Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials

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  6. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

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  7. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

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  8. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

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  9. A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)3

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  10. Physical Properties of a Promising Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F

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  11. A review on the development of infrared nonlinear optical materials with triangular anionic groups

    Journal of Solid State Chemistry · 2018-11-22

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  12. Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks

    Inorganic Chemistry · 2018-12-31

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  13. Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2

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  14. K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal

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  16. Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges

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  17. Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

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  18. Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response

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  20. BeO6 Trigonal Prism with Ultralong Be–O Bonds Observed in a Deep Ultraviolet Optical Crystal Li13BeBe6B9O27

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  21. Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates

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  22. Ba10In6Zn7S26-nZnS: An Inorganic Composite System with Interface Phase-Matching Tuned for High-Performance Infrared Nonlinear Optical Materials

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  23. BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge

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  24. Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O5

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  25. KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active

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  26. Ba2M(C3N3O3)2 (M = Sr, Pb): Band Engineering from p−π Interaction via Homovalent Substitution in Metal Cyanurates Containing Planar π-Conjugated Groups

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  27. Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response

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  29. Facile Growth of an Ultraviolet Hydroisocyanurate Crystal with Strong Nonlinearity and a Wide Phase-Matching Region from π-Conjugated (HC3N3O3)2– Groups

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  30. K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound

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  31. KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 4

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  32. Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O7

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  33. Emergent Deep‐Ultraviolet Nonlinear Optical Candidates

    Angewandte Chemie International Edition · 2019-12-10

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  34. Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich

    Angewandte Chemie · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  35. Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs

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  36. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance

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  37. Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook

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  38. NaK 15 [B 4 O 5 (OH) 4 ] 6 (NO 2 ) 2 (CO 3 )·7H 2 O: assembly of an unprecedented mixed anion inorganic compound via a facile hydrothermal route

    New Journal of Chemistry · 2020-01-01

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  39. Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles

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