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RESEARCH PAPER · Inorganic Chemistry Communications · 2019

Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response

Meng Wang, Dequan Wei, Lanju Liang, Xin Pei Yan, Kaikai Lv

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Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical responseOriginalTwo new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate8Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)47Polymorphism, polytypism and modular aspect of compounds with the general formula A 2 M 3(TO4)4 (A = Na, Rb, Cs, Ca; M = Mg, Mn, Fe3+, Cu2+; T = S6+, P5+): order–disorder, topological description and DFT calculations11Advances in second-order nonlinear optical sulfates38M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates26A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency7Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence8Analysis and evaluation of machine learning applications in materials design and discovery33Crystal growth, structural and DFT study of novel single crystal (E)-N’-(2-chlorobenzylidene)-4-fluorobenzohydrazide for nonlinear optical applications6Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal16Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)31Computational study of Be, Mg and Ca decorated Si12B12 nanocages with proficient nonlinear optical properties0YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal11Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)6Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy11K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence2Crystal Structure of a High-Temperature Modification of Cs2SO40CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10Thermal Evolution and Crystal Structure Features of Cs2SO4 and Cs2Ca3(SO4)4 Sulfates2A structural origin of both positive and negative thermal expansion in langbeinite-, arcanite- and metathenardite-type and related Rb2SO4 and Rb2Ca2(SO4)3 compounds3Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1Crystal Growth, Structure and Optical Properties of (NH 4 ) 2 Mg(SO 4 ) 2 ·6H 2 O: A Crystal With a Wide Deep Ultraviolet Window0The crystal chemistry and topology of modular structures. II. Heteropolyhedral substitutions and “blocky isomorphism” in inorganic compounds0Rb2Ca3(SO4)4: Crystal Structure, Thermal Expansion, Phase Transformations and Comparison with Cs2Ca3(SO4)4 and Langbeinite Structure Type0(CN 4 H 7 )(NH 2 SO 3 ): A Solar‐Blind Ultraviolet Nonlinear Optical Crystal With Short UV Cutoff Edge and Full‐Wavelength Phase‐Matching0Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0

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  1. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019-01-01

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  2. Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate

    Inorganic Chemistry Communications · 2020-03-20

    Yaoguo Shen, Xiaoling Xue, Renwen Yan, Hong Lin

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  3. Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge

    New Journal of Chemistry · 2021-01-01

    Yuchen Yan, Yanna Chen, Bao Jiang, Qun Jing, Jun Zhang

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  4. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  5. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  6. HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response

    Journal of Alloys and Compounds · 2022-01-11

    Yinglei Han, Xin Lei Zhao, Feng Xu, Bingxuan Li, Ning Ye, Min Luo

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  7. Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)4

    Crystals · 2022-01-18

    P. Fang, Wenyue Tang, Yaoguo Shen, Jinquan Hong, Yongming Li, Junrong Jia

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  8. Polymorphism, polytypism and modular aspect of compounds with the general formula A 2 M 3(TO4)4 (A = Na, Rb, Cs, Ca; M = Mg, Mn, Fe3+, Cu2+; T = S6+, P5+): order–disorder, topological description and DFT calculations

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2022-01-25

    Sergey M. Aksenov, Andrey Antonov, Dina Deyneko, Sergey Krivovichev, Stefano Merlino

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  9. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  10. M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates

    Inorganic Chemistry · 2022-12-12

    Danyang Dou, Bingjie Cai, Bingbing Zhang, Ying Wang

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  11. A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency

    Dalton Transactions · 2023-01-01

    Zilong Geng, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  12. Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence

    Journal of Materials Chemistry C · 2023-01-01

    Wen Dong Song, Jinxuan Ren, Jinwen Tan, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  13. Analysis and evaluation of machine learning applications in materials design and discovery

    Materials Today Communications · 2023-01-25

    Mahsa Golmohammadi, Masoud Aryanpour

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  14. Crystal growth, structural and DFT study of novel single crystal (E)-N’-(2-chlorobenzylidene)-4-fluorobenzohydrazide for nonlinear optical applications

    Optical Materials · 2023-02-22

    P. Sangeetha, D. Barathi, M. Uthayakumar, A. Dhandapani, Muthaiyan Xavier Suresh, Vandana P. Shinde

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  15. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

    Chinese Journal of Structural Chemistry · 2023-02-24

    Chen Xu, Yanqiang Li, Junhua Luo, Sangen Zhao

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  16. Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal

    Crystal Growth & Design · 2023-06-27

    Wen Zhi Yang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  17. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  18. Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

    Journal of Structural Chemistry · 2023-10-01

    Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, D. А. Banaru, Sergey N. Volkov, Д. В. Дейнеко, Alexey N. Kuznetsov∥, Рамиза Кераровна Расцветаева, Н. В. Чуканов, B. B. Shkurskii, N. A. Yamnova

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  19. Computational study of Be, Mg and Ca decorated Si12B12 nanocages with proficient nonlinear optical properties

    Physica Scripta · 2023-10-05

    Muhammad Rashid, Junaid Yaqoob, Muhammad Usman Khan, Saad M. Alshehri, Sajid Ali

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  20. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  21. Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal

    Inorganic Chemistry · 2024-05-31

    Yunqi Zhao, Yipeng Song, Yanqiang Li, Wei Liu, Zhou Yang, Weiqi Huang, Junhua Luo, Sangen Zhao, Belal Ahmed

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  22. Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)

    Inorganic Chemistry · 2024-07-31

    Yuqi Chen, Han Luo, Zeqiao Yin, Xuehua Dong, Daojiang Gao, Yuqiao Zhou, Ling Huang, Liling Cao, Guohong Zou

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  23. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

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  24. Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy

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  25. K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence

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  26. Crystal Structure of a High-Temperature Modification of Cs2SO4

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  27. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

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  28. Thermal Evolution and Crystal Structure Features of Cs2SO4 and Cs2Ca3(SO4)4 Sulfates

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  29. A structural origin of both positive and negative thermal expansion in langbeinite-, arcanite- and metathenardite-type and related Rb2SO4 and Rb2Ca2(SO4)3 compounds

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  30. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

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  31. Crystal Growth, Structure and Optical Properties of (NH 4 ) 2 Mg(SO 4 ) 2 ·6H 2 O: A Crystal With a Wide Deep Ultraviolet Window

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  32. The crystal chemistry and topology of modular structures. II. Heteropolyhedral substitutions and “blocky isomorphism” in inorganic compounds

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  33. Rb2Ca3(SO4)4: Crystal Structure, Thermal Expansion, Phase Transformations and Comparison with Cs2Ca3(SO4)4 and Langbeinite Structure Type

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  34. (CN 4 H 7 )(NH 2 SO 3 ): A Solar‐Blind Ultraviolet Nonlinear Optical Crystal With Short UV Cutoff Edge and Full‐Wavelength Phase‐Matching

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