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RESEARCH PAPER · Journal of the American Chemical Society · 2018

Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window

Weiqun Lu, Zeliang Gao, Xitao Liu, Xiangxin Tian, Qian Wu, Conggang Li, Youxuan Sun, Yang Liu, Xutang Tao

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Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency WindowOriginalPb 2 GaF 2 (SeO 3 ) 2 Cl: Band Engineering Strategy by Aliovalent Substitution for Enlarging Bandgap while Keeping Strong Second Harmonic Generation Response178A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23Ba3(C3N3O3)2: A New Phase of Barium Cyanurate Containing Parallel π-Conjugated Groups as a Birefringent Material Replacement for Calcite62A new ultraviolet transparent hydra-cyanurate K 2 (C 3 N 3 O 3 H) with strong optical anisotropy from delocalized π-bonds56A rich structural chemistry in π-conjugated hydroisocyanurates: layered structures of A 2 B(H 2 C 3 N 3 O 3 ) 4 · n H 2 O (A = K, Rb, Cs; B = Mg, Ca; n = 4, 10) with high ultraviolet transparency and strong optical anisotropy47Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Chloride carbodiimide K 12 Pb 51 (CN 2 ) 30 Cl 54 with an unprecedented 45 Å unit cell axis and a large birefringence7Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18The electrical enhancement and reversible manipulation of near-infrared luminescence in Nd doped ferroelectric nanocomposites for optical switches38Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO617Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design114A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design25Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range66Cs3Na(H2C3N3O3)4·3H2O: A Mixed Alkali‐Metal Hydroisocyanurate Nonlinear Optical Material Containing π‐Conjugated Six‐Membered‐Ring Units68Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals12Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands9MWCNTs/BaTiO3 metacomposite with negative permittivity behavior and electric percolation phenomenon in radio frequency2One-step synthesis of Zn2GeO4/CNT-O hybrid with superior cycle stability for supercapacitor electrodes27Construction of Spatial Charge Separation Facets on BaTaO2N Crystals by Flux Growth Approach for Visible-Light-Driven H2 Production65LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337Rb4Li2TiOGe4O12: A Titanyl Nonlinear Optical Material with the Widest Transparency Range68Rb4Li2TiOGe4O12: A Titanyl Nonlinear Optical Material with the Widest Transparency Range29K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114A series of Er3+-activated SrLaGa3O7 single crystal fibers for mid-infrared laser application18Li2K4TiOGe4O12: A Stable Mid-Infrared Nonlinear Optical Material69M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering157Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58Investigation of the Thermal Properties and Crystal Growth of the Nonlinear Optical Crystals AgGaS 2 and AgGaGeS 434A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)30A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)86Pb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties165Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties29Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups75Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups22Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation34Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region24The YMgB 5 O 10 crystal preparation and attractive multi-wavelength emission characteristics of doping Nd 3+ ions34Optimized growth and anisotropic properties of Li 2 ZrTeO 6 nonlinear optical crystals8Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy18A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence17Titanium Iodates with a Second-Harmonic-Generation Response8CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Sr2Pb(BeB5O10)(BO3): An Excellent Ultraviolet Nonlinear-Optical Beryllium Borate by the Pb-Modified Construction of a Conjugated System and Lone-Pair Effect14KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response10A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation63A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response10Ca3(TeO3)2(MO4) (M = Mo, W): Mid-Infrared Nonlinear Optical Tellurates with Ultrawide Transparency Ranges and Superhigh Laser-Induced Damage Thresholds46Growth, Optical, and Spectroscopic Properties of Pure and Nd3+-Doped GdSr3(PO4)3 Crystals with Disordered Structure14LiNbTeO5: A High-Performance Multifunctional Crystal Material with a Very Large Second-Harmonic Generation Response and Piezoelectric Coefficient52Methodological Approach to the High-Pressure Synthesis of Nonmagnetic Li2B4+B′6+O6 Oxides19Band gap modulation and nonlinear optical properties of quaternary tellurates Li 2 GeTeO 613Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups8Growth, structural, thermal, and optical properties of a GaNbO 4 single crystal6Tellurate polymorphs with high-performance nonlinear optical switch property and wide mid-IR transparency19Temperature dependence of LiNbO3 dislocation density in the near-surface layer7Pb 4 SeBr 6 : A Congruently Melting Mid‐Infrared Nonlinear Optical Material with Excellent Comprehensive Performance39Crystallographic Insights into the Crystal Structure and Intrinsic Properties of Ca12Al14O33-Type Rb3LiZn2(MoO4)4Single Crystals1Isotropically Dyed Single Crystals Produced via Gel-Incorporation20Preparation, characterization and photocatalytic studies of parent and ion-doped Li2TiTeO64Bi3TeBO9: A Promising Mid-Infrared Nonlinear Optical Crystal with a Large Laser Damage Threshold6Crystal Growth and Chirality - Technologies and Applications12[Ba2F2][Ge2O3S2]: An Unprecedented Heteroanionic Infrared Nonlinear Optical Material Containing Three Typical Anions47Growth, Structure and Optical Characterization of Rb3Ti3P5O20 Single Crystal2Transparent Lead‐Free Ferroelectric (K, Na)NbO3 Single Crystal with Giant Second Harmonic Generation and Wide Mid‐Infrared Transparency Window21Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Enhancements of Second Harmonic Generation and Birefringence in Traditional RbTiOPO4‐Type Crystals by Aliovalent Substitution of Ti Site1Mid-infrared nonlinear optical heptachlorodigallate AGa2Cl7 (A = Ga+, In+) with a unique second harmonic generation mechanism induced by monovalent cations17New lead-iodide formates with a strong second-harmonic generation response and suitable birefringence obtained by the substitution strategy8Growth, Structure, and Optical Properties of a Nonlinear Optical Niobium Borate Crystal CsNbOB2O5 with Distorted NbO5 Square Pyramids13Speciation of Tellurium(VI) in Aqueous Solutions: Identification of Trinuclear Tellurates by 17O, 123Te, and 125Te NMR Spectroscopy1Recent Advances in Infrared Nonlinear Optical Crystal7Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21KNa 2 La 2 (BO 3 ) 3 : a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO 3 ] triangles and distorted [LaO 9 ] polyhedra26LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence21Shedding light on intrinsic characteristics and optical properties of novel selenite and tellurite crystals ZrSe 2 O 6 , HfSe 2 O 6 and HfTe 3 O 87Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates7Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112Organic Nonlinear Optical Crystals for Highly Efficient Terahertz-Wave Generation36Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles13Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability40Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27Ultra-high melting point Ho3+, Yb3+ co-doped HfO2 single-crystal fibers for high-precision and robust ratiometric thermometry towards harsh environments9A survey of stereoactive oxysalts for linear and nonlinear optical applications40Continuous‐Wave Raman Lasing from Metal‐Linked Organic Dimer Microcrystals3Continuous‐Wave Raman Lasing from Metal‐Linked Organic Dimer Microcrystals2Synthesis, characterization and photocatalytic studies of visible light responsive K3MTe3O12 (M = Cr, Fe and Ga)1Preparation and Optical Properties of Nd:Bi2Ti2O7 Laser Crystal with Disordered Structure and Attractive Multiwavelength Emission Characteristics6A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps27YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19A defect pyrochlore-like acentric cubic lead titanium-tellurate crystal exhibiting strong second harmonic generation activity and an extended transparent window4A-site cation manipulation of exemplary second harmonic generation response and optical anisotropy in rare-earth borates18Investigation of nonlinear optical properties in α-A 2 BB′O 6 (A = Li, Na, K; B = Ti, Zr, Hf; B′ = Se, Te) by first-principles calculations3Novel laser crystal Lu 2 TeO 6 : crystal growth, thermal properties, and spectral analysis0Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Dual-Anion Strategy Induces Dual Enhancement Toward Ultrashort Phase-Matching Wavelength in Deep-UV Transparent d0 Transition Metal Oxyfluorides21Crystal Growth, Optical, Thermal, DFT and Z‐Scan Studies of Imidazolium Hydrogen Fumarate Crystal for Nonlinear Optical Applications3Structural Engineering Enables Suppressed Ion Migration and Enhanced Hard X‐Ray Detection Performance in Novel Oxide Single Crystals20Efficient second‐harmonic generation of quasi‐bound states in the continuum in lithium niobate thin film enhanced by Bloch surface waves20Combining rigid and deformable groups to construct a robust birefringent crystal for compact polarization components25Double-perovskite compound Na2ZrTeO6: Synthesis, structure and self-activated near-infrared luminescence12Data-Driven High-Throughput Screening and Experimental Realization of Ag2B(IV)B′(VI)O6 under Negative Chemical-Pressure1Directional growth and composition design of the highly disordered Yb3+ doped Ca(Gd1-xLux)AlO4 crystals for ultrafast lasers4Oxide Lu 2 TeO 6 single crystals for X-ray detection with an ultralow detection limit5Zn2MnSbO6 and Zn2FeSbO6: Two New Polar High-Pressure Ordered Corundum-Type Compounds2Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Crystal Structural Editing: Novel Biaxial MgTe2O5 Crystal as Zero‐Order Waveplates10Nonlinear Optical Effects Modulated by Distinctive Monovalent Cations with Lone Electron Pairs in AGaI 4 (A = Ga + , In + )4La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap18La3ZrGa5O14: Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap1Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10Mechanism on failure of cooled infrared detector illuminated by CW laser0Flexible Chiral Molecular Crystal with Reversible Single‐Crystal‐to‐Single‐Crystal Phase Transition for Second Harmonic Generation4Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy34NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence20NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence6La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Optimized growth and anisotropic physical properties of a promising mid-infrared nonlinear optical crystal Li2TiTeO63Vacancy-driven tetrahedral distortion leading to exceptional second harmonic generation3Growth, structure and optical properties of PbBi3PO8 crystals0SrZnGeSe4: An Infrared Nonlinear Optical Crystal Material with Wide Transmission Range and Large SHG Response6Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides33Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0Spatial Distribution of the Second Harmonic Emission of a Bent Organic Crystal2Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Chiral Lead-Oxyiodide Nonlinear Optical Crystals Constructed on l -Malate Groups5Achieving record birefringence in metal-free semiorganic sulfate crystals via tetrahedral anionic group substitution0Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates4Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates0Ruthenium Materials: Synthesis, Characterization, Optical, Antioxidant, and Anticancer Applications0Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities1K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2High-performance photocatalytic water splitting for hydrogen production, amplified solar cell efficiency, and energy harvesting in X@Na-doped Na2ZrTeO6 (X = K, Rb, and Cs)2A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response0

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  1. Pb 2 GaF 2 (SeO 3 ) 2 Cl: Band Engineering Strategy by Aliovalent Substitution for Enlarging Bandgap while Keeping Strong Second Harmonic Generation Response

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  2. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

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  3. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

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  4. Ba3(C3N3O3)2: A New Phase of Barium Cyanurate Containing Parallel π-Conjugated Groups as a Birefringent Material Replacement for Calcite

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  5. A new ultraviolet transparent hydra-cyanurate K 2 (C 3 N 3 O 3 H) with strong optical anisotropy from delocalized π-bonds

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  6. A rich structural chemistry in π-conjugated hydroisocyanurates: layered structures of A 2 B(H 2 C 3 N 3 O 3 ) 4 · n H 2 O (A = K, Rb, Cs; B = Mg, Ca; n = 4, 10) with high ultraviolet transparency and strong optical anisotropy

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  7. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

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  8. Chloride carbodiimide K 12 Pb 51 (CN 2 ) 30 Cl 54 with an unprecedented 45 Å unit cell axis and a large birefringence

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  9. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

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  11. The electrical enhancement and reversible manipulation of near-infrared luminescence in Nd doped ferroelectric nanocomposites for optical switches

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  12. Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO6

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  13. Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response

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  14. A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design

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  15. A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design

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  16. Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties

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  17. MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range

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  18. Cs3Na(H2C3N3O3)4·3H2O: A Mixed Alkali‐Metal Hydroisocyanurate Nonlinear Optical Material Containing π‐Conjugated Six‐Membered‐Ring Units

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  19. Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals

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  20. Variable Chains Found in Mixed Transition Metal Oxyfluorides with Heterocyclic Ligands

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  21. MWCNTs/BaTiO3 metacomposite with negative permittivity behavior and electric percolation phenomenon in radio frequency

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  22. One-step synthesis of Zn2GeO4/CNT-O hybrid with superior cycle stability for supercapacitor electrodes

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  23. Construction of Spatial Charge Separation Facets on BaTaO2N Crystals by Flux Growth Approach for Visible-Light-Driven H2 Production

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  24. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

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  25. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

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  26. Rb4Li2TiOGe4O12: A Titanyl Nonlinear Optical Material with the Widest Transparency Range

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  27. Rb4Li2TiOGe4O12: A Titanyl Nonlinear Optical Material with the Widest Transparency Range

    Angewandte Chemie · 2019-10-09

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  28. K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold

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  29. A series of Er3+-activated SrLaGa3O7 single crystal fibers for mid-infrared laser application

    Journal of Rare Earths · 2019-12-27

    Yan Wang, Yingshu Lian, Yanping Zhang, Chaoyang Tu, Dongfeng Xue

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  30. Li2K4TiOGe4O12: A Stable Mid-Infrared Nonlinear Optical Material

    Chemistry of Materials · 2019-12-27

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  31. M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework

    Chemical Communications · 2020-01-01

    Yi-Gang Chen, Chunyu Yang, Fang Wang, Yao Guo, Xingxing Jiang, Xian‐Ming Zhang

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  32. Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer

    Journal of Materials Chemistry C · 2020-01-01

    Weimin Dong, Yingjie Sun, Qian Yao, Qingbo Wang, Hang Wen, Jing Li, Xinguang Xu, Jiyang Wang

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  33. BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering

    Journal of the American Chemical Society · 2020-02-25

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  34. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2020-03-11

    Xinglong Chen, Hongil Jo, Kang Min Ok

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  35. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

    Angewandte Chemie · 2020-03-11

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  36. Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution

    Chemistry of Materials · 2020-03-16

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  37. Investigation of the Thermal Properties and Crystal Growth of the Nonlinear Optical Crystals AgGaS 2 and AgGaGeS 4

    Crystal Growth & Design · 2020-03-19

    Jun Wu, Wei Huang, Hong-Gang Liu, Z. Y. He, Baojun Chen, Shifu Zhu, Beijun Zhao, Yuxing Lei, Xiaonan Zhou

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  38. A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)

    Angewandte Chemie · 2020-04-17

    Rui‐An Li, Zhengyang Zhou, Yu‐Kun Lian, Fei Jia, Xingxing Jiang, Mingcong Tang, Li‐Ming Wu, Junliang Sun, Ling Chen

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  39. A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)

    Angewandte Chemie International Edition · 2020-04-17

    Rui‐An Li, Zhengyang Zhou, Yu‐Kun Lian, Fei Jia, Xingxing Jiang, Mingcong Tang, Li‐Ming Wu, Junliang Sun, Ling Chen

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  40. Pb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2020-09-02

    Xinglong Chen, Qun Jing, Kang Min Ok

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  41. Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties

    Angewandte Chemie · 2020-09-02

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  42. Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm

    Chemistry - An Asian Journal · 2020-09-21

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  43. Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie International Edition · 2020-10-14

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

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  44. Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie · 2020-10-15

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

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  45. Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation

    ACS Applied Materials & Interfaces · 2020-10-22

    Lin Lin, Xingxing Jiang, Chao Wu, Longhua Li, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  46. Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region

    Inorganic Chemistry Frontiers · 2020-10-29

    Jiankang Wang, Binkai Xiong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  47. The YMgB 5 O 10 crystal preparation and attractive multi-wavelength emission characteristics of doping Nd 3+ ions

    Journal of Materials Chemistry C · 2020-12-23

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  48. Optimized growth and anisotropic properties of Li 2 ZrTeO 6 nonlinear optical crystals

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  49. Zn(NH 3 )CO 3 : a “three-in-one” UV nonlinear optical crystal built by a polar molecule bonding strategy

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  50. A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence

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