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RESEARCH PAPER · Chemistry of Materials · 2017

Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)

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Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)OriginalK 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties33New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90Thioaluminogermanate M(AlS2)(GeS2)4 (M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27Al and 23Na NMR Spectroscopy9SnI 4 ⋅(S 8 ) 2 : A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal184SnI4⋅(S8)2: A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal45Second-order nonlinear optical crystals with mixed anions250Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba6Li2ZnSn4S16 vs Ba6Ag2ZnSn4S16 vs Ba6Li2.67Sn4.33S1625Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations4Monoclinic gallium selenide: an AgGaS 2 -type structure variant with balanced infrared nonlinear optical performance43Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of (K 0.38 Ba 0.81 )Ga 2 Se 495Photoresponsive sulfone-based molecules: photoinduced electron transfer and heat/air-stable radicals in the solid state3Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15Tris(ethylenediamine)nickel(II) thio-hydroxogermanate monohydrate: Synthesis, crystal structure, 1H NMR, EPR, optical and magnetic properties18Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Targeted Synthesis of Uranium(IV) Thiosilicates9Sn2Ga2S5: A Type of IR Nonlinear-Optical Material22Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family32Enhanced Photoinduced Electron Transfer and Stability of Diradicals in Neutral Extended Pyridine N -Oxides21Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O721BaGe 2 Pn 2 (Pn = P, As): Two Congruent-Melting Non-chalcopyrite Pnictides as Mid- and Far-Infrared Nonlinear Optical Materials Exhibiting Large Second Harmonic Generation Effects54Strong nonlinear optical effect attained by atom-response-theory aided design in the Na 2 M II MIV2Q 6 (M II = Zn, Cd; M IV = Ge, Sn; Q = S, Se) chalcogenide system27Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32[ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering270Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131Finding Optimal Mid-Infrared Nonlinear Optical Materials in Germanates by First-Principles High-Throughput Screening and Experimental Verification79α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra21A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation39Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation1Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5α-Ca2CdP2 and β-Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps30AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58Ba4GeSb2Se11: An Infrared Nonlinear Optical Crystal with a V-Shaped Se32– Group Possessing a Large Contribution to the SHG Response8Noncentrosymmetric Ba6In2Q10 (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity11Shedding light on the optical and nonlinear optical properties of superalkali-doped borophene16Material research from the viewpoint of functional motifs103Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property6Planar Viologen-Based Crystalline Compounds Showing Heat-Induced Electron Transfer and Thermochromism25Polychalcogen molecules, ligands, and ions Part 2: Catenated acyclic molecules, ions, and p-block element derivatives0Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity4NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties4Synthesis, Crystal Structure, and Optical Properties of a New Quaternary Tin Polychalcogenide K2BaSnSe50

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  1. K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties

    Journal of Materials Chemistry C · 2018-01-01

    Zhuang Li, Xingxing Jiang, Changjiang Yi, Molin Zhou, Yangwu Guo, Xiaoyu Luo, Zheshuai Lin, Yicheng Wu, Youguo Shi, Jiyong Yao

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  2. New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold

    Chemical Science · 2018-01-01

    Shu‐Fang Li, Xiao‐Ming Jiang, Yuhang Fan, Bin‐Wen Liu, Hui‐Yi Zeng, Guo‐Cong Guo

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  3. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

    Dalton Transactions · 2018-01-01

    Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·
  4. Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System

    Chemistry of Materials · 2018-01-18

    Min Zhang, Cong Hu, Tushagu Abudouwufu, Zhihua Yang, Shilie Pan

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  5. Thioaluminogermanate M(AlS2)(GeS2)4 (M = Na, Ag, Cu): Synthesis, Crystal Structures, Characterization, Ion-Exchange and Solid-State 27Al and 23Na NMR Spectroscopy

    Inorganic Chemistry · 2018-03-14

    Fatimah Alahmari, Bambar Davaasuren, Abdul-Hamid M. Emwas, A. Rothenberger

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  6. SnI 4 ⋅(S 8 ) 2 : A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2018-05-06

    Sheng‐Ping Guo, Yang Chi, Huaiguo Xue

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  7. SnI4⋅(S8)2: A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal

    Angewandte Chemie · 2018-05-07

    Sheng‐Ping Guo, Yang Chi, Huaiguo Xue

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  8. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  9. Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba6Li2ZnSn4S16 vs Ba6Ag2ZnSn4S16 vs Ba6Li2.67Sn4.33S16

    Crystal Growth & Design · 2018-08-16

    Ruihuan Duan, Rui‐An Li, Pengfei Liu, Hua Lin, Yue Wang, Li‐Ming Wu

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  10. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2018-08-23

    Sheng‐Ping Guo, Zongdong Sun, Yang Chi, Huaiguo Xue

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  11. PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units

    Inorganic Chemistry · 2018-08-30

    Yun‐Xiang Ma, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  12. Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations

    Solid State Sciences · 2018-09-07

    Zongdong Sun, Yang Chi, Sheng‐Ping Guo

    Read original paper ↗ ·
  13. Monoclinic gallium selenide: an AgGaS 2 -type structure variant with balanced infrared nonlinear optical performance

    Journal of Materials Chemistry C · 2019-01-01

    Qian-Ting Xu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·
  14. Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of (K 0.38 Ba 0.81 )Ga 2 Se 4

    Chemical Communications · 2019-01-01

    Yanan Li, Yang Chi, Zongdong Sun, Huaiguo Xue, Nian‐Tzu Suen, Sheng‐Ping Guo

    Read original paper ↗ ·
  15. Photoresponsive sulfone-based molecules: photoinduced electron transfer and heat/air-stable radicals in the solid state

    New Journal of Chemistry · 2019-01-01

    Ning‐Ning Zhang, Ming‐Sheng Wang, Guo‐Cong Guo

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  16. Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response

    Inorganic Chemistry · 2019-01-14

    Lingyun Dong, Ying Wang, Bingbing Zhang, Zhihua Yang, Xusheng Ge, Kai Liu, Shigang Shen

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  17. Tris(ethylenediamine)nickel(II) thio-hydroxogermanate monohydrate: Synthesis, crystal structure, 1H NMR, EPR, optical and magnetic properties

    Inorganica Chimica Acta · 2019-01-18

    Fatimah Alahmari, Bambar Davaasuren, Abdul-Hamid M. Emwas, Pedro M. F. J. Costa, A. Rothenberger

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  18. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

    Inorganic Chemistry · 2019-03-15

    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  19. Targeted Synthesis of Uranium(IV) Thiosilicates

    Inorganic Chemistry · 2019-06-10

    Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  20. Sn2Ga2S5: A Type of IR Nonlinear-Optical Material

    Inorganic Chemistry · 2019-08-28

    Zhi‐Hui Shi, Yang Chi, Zongdong Sun, Wenlong Liu, Sheng‐Ping Guo

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  21. Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family

    Crystal Growth & Design · 2019-09-09

    Yangwu Guo, Fei Liang, Zhuang Li, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  22. Enhanced Photoinduced Electron Transfer and Stability of Diradicals in Neutral Extended Pyridine N -Oxides

    The Journal of Physical Chemistry C · 2019-09-12

    Ning‐Ning Zhang, Yong‐Fang Han, Cai Sun, Ming‐Sheng Wang, Guo‐Cong Guo

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  23. Structural Origin of Thermally Induced Second Harmonic Generation Enhancement in RbNaMgP2O7

    Chemistry of Materials · 2019-11-07

    Xiaoyan Yang, Sangen Zhao, Shipeng Geng, Li Yang, Qingzhen Huang, Xiaojun Kuang, Junhua Luo, Xianran Xing

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  24. BaGe 2 Pn 2 (Pn = P, As): Two Congruent-Melting Non-chalcopyrite Pnictides as Mid- and Far-Infrared Nonlinear Optical Materials Exhibiting Large Second Harmonic Generation Effects

    Chemistry of Materials · 2019-11-21

    Jindong Chen, Chensheng Lin, Guang Peng, Feng Xu, Min Luo, Shunda Yang, Shuangshuang Shi, Yingshuang Sun, Tao Yan, Bingxuan Li, Ning Ye

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  25. Strong nonlinear optical effect attained by atom-response-theory aided design in the Na 2 M II MIV2Q 6 (M II = Zn, Cd; M IV = Ge, Sn; Q = S, Se) chalcogenide system

    Journal of Materials Chemistry C · 2020-01-01

    Run Ye, Xiyue Cheng, Bin‐Wen Liu, Xiao‐Ming Jiang, Long‐Qi Yang, Shuiquan Deng, Guo‐Cong Guo

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  26. Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior

    Chemistry of Materials · 2020-01-21

    Ya Feng Yang, Kui Wu, Bingbing Zhang, Xiaowen Wu, Ming‐Hsien Lee

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  27. LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold

    Inorganic Chemistry · 2020-04-04

    Ailijiang Abudurusuli, Junjie Li, Tinghao Tong, Zhihua Yang, Shilie Pan

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  28. [ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering

    Journal of the American Chemical Society · 2020-05-29

    Bin‐Wen Liu, Xiao‐Ming Jiang, Hui‐Yi Zeng, Guo‐Cong Guo

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  29. Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt

    Inorganic Chemistry · 2020-05-29

    Zhen‐Tao Lu, Wenjing Fan, Zhiqian Wang, Ning Gu, Zeng-Hao Yue, Huaiguo Xue, Sheng‐Ping Guo

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  30. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  31. Finding Optimal Mid-Infrared Nonlinear Optical Materials in Germanates by First-Principles High-Throughput Screening and Experimental Verification

    ACS Applied Materials & Interfaces · 2020-09-14

    Jin Yu, Bingbing Zhang, Xiaodong Zhang, Ying Wang, Kui Wu, Ming‐Hsien Lee

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  32. α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra

    Chemistry of Materials · 2020-11-25

    Jindong Chen, Chensheng Lin, Feng Xu, Shunda Yang, Yingshuang Sun, Xin Lei Zhao, Xiaotian Jiang, Bingxuan Li, Tao Yan, Ning Ye

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  33. A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer

    Chemical Communications · 2021-01-01

    Zhen‐Tao Lu, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

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  34. Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation

    Angewandte Chemie International Edition · 2021-03-22

    Xiao‐Ming Jiang, Shujuan Lin, Chao He, Bin‐Wen Liu, Guo‐Cong Guo

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  35. Uncovering a Functional Motif of Nonlinear Optical Materials by In Situ Electron Density and Wavefunction Studies Under Laser Irradiation

    Angewandte Chemie · 2021-03-22

    Xiao‐Ming Jiang, Shujuan Lin, Chao He, Bin‐Wen Liu, Guo‐Cong Guo

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  36. Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks

    Unknown journal · 2021-04-19

    Hua Lin, Xin‐Tao Wu, Qi‐Long Zhu

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  37. α-Ca2CdP2 and β-Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps

    Inorganic Chemistry · 2021-05-03

    Yingshuang Sun, Chensheng Lin, Jindong Chen, Feng Xu, Shunda Yang, Bingxuan Li, Guangsai Yang, Min Luo, Ning Ye

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  38. AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−

    Advanced Optical Materials · 2021-05-20

    Wenhao Xing, Chunlan Tang, Naizheng Wang, Chunxiao Li, Ece Uykur, Jieyun Wu, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  39. Ba4GeSb2Se11: An Infrared Nonlinear Optical Crystal with a V-Shaped Se32– Group Possessing a Large Contribution to the SHG Response

    Inorganic Chemistry · 2021-09-30

    Fang-Yu Yuan, Yi‐Zhi Huang, Hao Zhang, Chensheng Lin, Guoliang Chai, Wen‐Dan Cheng

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  40. Noncentrosymmetric Ba6In2Q10 (Q = S, Se): Structural Chemistry and Nonlinear-Optical Activity

    Inorganic Chemistry · 2021-11-05

    Xiao Fen Huang, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

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  41. Shedding light on the optical and nonlinear optical properties of superalkali-doped borophene

    Journal of Molecular Modeling · 2022-01-26

    Muhammad Hussnain, Rao Aqil Shehzad, Shabbir Muhammad, Javed Iqbal M, Abdullah Godran Al-Sehemi, Saleh S. Alarfaji, Khurshid Ayub, Muhammad Shahzad Yaseen

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  42. Material research from the viewpoint of functional motifs

    National Science Review · 2022-02-10

    Xiao‐Ming Jiang, Shuiquan Deng, Myung‐Hwan Whangbo, Guo‐Cong Guo

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  43. Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property

    Journal of Solid State Chemistry · 2022-06-02

    Weikang Wang, Wangzhu Cao, Ling‐Yun Zhang, Guobao Li, Yuandong Wu, Shaoguo Wen, Dajiang Mei

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  44. Planar Viologen-Based Crystalline Compounds Showing Heat-Induced Electron Transfer and Thermochromism

    Crystal Growth & Design · 2022-08-22

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  45. Polychalcogen molecules, ligands, and ions Part 2: Catenated acyclic molecules, ions, and p-block element derivatives

    Elsevier eBooks · 2022-10-02

    Risto S. Laitinen, Raija Oilunkaniemi, T. Chivers, Liam J. R. McGeachie, Paul F. Kelly, Roberto S.P. King

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  46. Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity

    Inorganic Chemistry · 2023-08-10

    Jun Li, Wenfeng Zhou, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  47. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

    Materials Today Chemistry · 2023-09-20

    Pengcheng Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  48. Pentanary Oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) Featuring [Ge3O2S8]8– Trimers and {[MGe3O2S8]6–}∞ Chains: Structural Chemistry and Physical Properties

    Inorganic Chemistry · 2024-04-12

    Xinxin Fan, Mei Yang, Wen‐Dong Yao, Wenfeng Zhou, Tengfei Jiang, Wenlong Liu, Sheng‐Ping Guo

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  49. Synthesis, Crystal Structure, and Optical Properties of a New Quaternary Tin Polychalcogenide K2BaSnSe5

    Zeitschrift für anorganische und allgemeine Chemie · 2024-08-08

    Jinlong Shi, Mengran Sun, Chunxiao Li, Jiyong Yao

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