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RESEARCH PAPER · Inorganic Chemistry · 2022

d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

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d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)OriginalRevisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure10Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)10Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties2Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 81Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)7Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se81Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)3Synthesis, crystal growth, and optical and magnetic properties of three bimetallic thiocyanates TBi(SCN) 5 (T = Mn, Cd) and FeBi(SCN) 61Synthesis, Crystal Growth, and Optical and Magnetic Properties of Three Bimetallic Thiocyanates: Na 2 Zn(NCS) 4 ·8H 2 O, K 2 Zn(NCS) 4 ·3H 2 O, and (NH 4 ) 2 Co(NCS) 4 ·3H 2 O4Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Isothermal sections Tl2Se–CdSe–DIVSe2 (DIV – Si, Ge), quasi-binary systems Tl2DIVSe3–CdSe, Tl2CdGeSe4–GeSe2 and the crystal structure, electronic and optical properties of novel quaternary selenides Tl2CdDIV3Se80

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  1. Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

    CrystEngComm · 2023-01-01

    Craig Cropek, Bingheng Ji, Arka Sarkar, Fei Wang, Tajamul Hussain Syed, Wei Wei, Sheng‐Ping Guo, Jian Wang

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  2. Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure

    CrystEngComm · 2023-01-01

    Gary Cicirello, Andrew Swindle, Jian Wang

    Read original paper ↗ ·
  3. Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties

    Chemistry of Materials · 2023-08-14

    Zixian Jiao, Osvaldo Medina Mireles, Kevin Ensz, Fei Wang, Mingli Liang, P. Shiv Halasyamani, Bingbing Zhang, D. Paul Rillema, Jian Wang

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  4. Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)

    Dalton Transactions · 2023-12-15

    Zixian Jiao, Jasmine Quah, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Fei Wang, Jian Wang

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  5. Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties

    Journal of Alloys and Compounds · 2023-12-29

    Mengran Sun, Haojian Su, Wenhao Liu, Jiyong Yao

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  6. Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 8

    CrystEngComm · 2024-01-01

    Jia-Ting Liu, Abdusalam Ablez, Qianqian Hu, Jun-Hao Tang, Chuan Lv, Lu Yang, Mei‐Ling Feng, Xiao‐Ying Huang

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  7. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  8. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  9. Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)

    Inorganic Chemistry · 2024-09-19

    Karishma Prasad, Dinesh Upreti, Md Rafique Un Nabi, Richeal Oppong, Fei Wang, Manish Shinde, Jin Hu, Jian Wang

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  10. Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds

    Dalton Transactions · 2025-01-01

    Guili Wang, Bohui Xu, Chunxiao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao

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  11. Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se8

    SSRN Electronic Journal · 2025-01-01

    Lyudmyla Piskacz, Andrii Selezen, Lyubomyr Gulay, Yuri M. Kogut, Dmytro Ivanyuk, G.L. Myronchuk, Stepan V. Syrotyuk, Yu. V. Klysko, Svitlana Bolshanina, Oleksiy Synelnychenko, Oleg Yu Khyzhun

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  12. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  13. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)

    Crystal Growth & Design · 2025-12-30

    Vivian Nguyen, Chu Chu, Monique Sutherlin, Bingbing Zhang, Jian Wang

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  15. Synthesis, crystal growth, and optical and magnetic properties of three bimetallic thiocyanates TBi(SCN) 5 (T = Mn, Cd) and FeBi(SCN) 6

    Dalton Transactions · 2026-01-01

    David Rich, Khusbu Rai, Dinesh Upreti, Jin Hu, Fei Wang, Jian Wang

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  16. Synthesis, Crystal Growth, and Optical and Magnetic Properties of Three Bimetallic Thiocyanates: Na 2 Zn(NCS) 4 ·8H 2 O, K 2 Zn(NCS) 4 ·3H 2 O, and (NH 4 ) 2 Co(NCS) 4 ·3H 2 O

    Inorganic Chemistry · 2026-02-26

    David Rich, Dinesh Upreti, Eric A. Gabilondo, P. Shiv Halasyamani, Jin Hu, Fei Wang, Mrittika Sarkar, Jian Wang

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  17. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  18. Isothermal sections Tl2Se–CdSe–DIVSe2 (DIV – Si, Ge), quasi-binary systems Tl2DIVSe3–CdSe, Tl2CdGeSe4–GeSe2 and the crystal structure, electronic and optical properties of novel quaternary selenides Tl2CdDIV3Se8

    Journal of Alloys and Compounds · 2026-07-22

    Л.В. Піскач, Andrii Selezen, Lubomir D. Gulay, Yuri M. Kogut, Dmytro Ivanyuk, Galyna Myronchuk, Stepan V. Syrotyuk, Yu. V. Klysko, Svitlana Bolshanina, Oleksiy Synelnychenko, Oleg Khyzhun

    Read original paper ↗ ·