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RESEARCH PAPER · Chinese Journal of Structural Chemistry · 2023

Recent progress of newly developed functional building units and corresponding nonlinear optical materials

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Recent progress of newly developed functional building units and corresponding nonlinear optical materialsOriginalPolysulfide Anions [S x ] 2− ( x = 2, 3, 4, 5): Promising Functional Building Units for Infrared Nonlinear Optical Materials22K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy14Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10[C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance8A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering1CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS1NaGa2PS6: A Noncentrosymmetric Thiophosphate with Wide Band Gap and High Laser-Induced Damage Threshold0

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  1. Polysulfide Anions [S x ] 2− ( x = 2, 3, 4, 5): Promising Functional Building Units for Infrared Nonlinear Optical Materials

    Small · 2024-01-23

    Miao Song, Yan Xiao, Daqing Yang, Ying Wang, Bingbing Zhang

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  2. K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy

    Inorganic Chemistry · 2024-09-12

    Chao Yang Feng, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  3. Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective

    Advanced Functional Materials · 2024-12-15

    Miriding Mutailipu, Junjie Li, Shilie Pan

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  4. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  5. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

    Inorganic Chemistry · 2025-05-23

    Lehui Liu, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

    Read original paper ↗ ·
  6. [C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance

    Inorganic Chemistry · 2025-06-02

    Jiayin Tang, Xin Wen, Huili Zhang, Yuchen Yan, Jindong Chen, Shihui Ma, Min Luo, Chensheng Lin, Ning Ye, Guang Peng

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  7. A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps

    Inorganic Chemistry · 2025-07-10

    Zhi Bing Deng, Qiu-Yang Du, Fang-Xu Tian, Zong-Ze Li, Mingyang Li, Mao‐Yin Ran, Wenlong Liu, Sheng‐Ping Guo

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  8. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  9. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

    Zhi Bing Deng, Rui Xiao, Mao‐Yin Ran, Ao Guo, Xiang Chen, Wenlong Liu, Sheng‐Ping Guo

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  10. CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties

    Inorganic Chemistry · 2025-08-21

    Chengbo Li, Haipeng Zhou, Y. Q. Chen, Jinfeng Liu, Xiu Zhu, Guisheng Xu, Jiankang Wang

    Read original paper ↗ ·
  11. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

    Read original paper ↗ ·
  12. Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering

    Inorganic Chemistry · 2025-09-20

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  13. CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS

    Inorganic Chemistry · 2026-03-26

    Hongbo Zhang, Haixia Wang, Aoya He, Jiaze Sun, Jindou Hu, G. L. Li

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  14. NaGa2PS6: A Noncentrosymmetric Thiophosphate with Wide Band Gap and High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2026-09-15

    Jiaze Sun, Aoya He, Hongbo Zhang, Yali Cao, Guangmao Li

    Read original paper ↗ ·