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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2018

Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances

Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performancesOriginalNaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13BaB2S4: An Efficient and Air-Stable Thioborate as Infrared Nonlinear Optical Material with High Laser Damage Threshold85Ba10Zn7M6Q26: Two New Mid-infrared Nonlinear Optical Crystals with T2 Supertetrahedron 3D Framework11Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)36ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Quaternary semiconductor Ba 8 Zn 4 Ga 2 S 15 featuring unique one-dimensional chains and exhibiting desirable yellow emission24Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Ba10In6Zn7S26-nZnS: An Inorganic Composite System with Interface Phase-Matching Tuned for High-Performance Infrared Nonlinear Optical Materials13Growth and physicochemical investigations on wide bandgap 2D polymeric amino acetic acid sulfato dilithium metal–organic framework1Solvothermal Syntheses and Characterizations of Four Quaternary Copper Sulfides BaCu3MS4 (M = In, Ga) and BaCu2MS4 (M = Sn, Ge)27One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se828Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds34β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement46Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy22Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response27Solvothermal syntheses, crystal structures, and photocurrent responses of quaternary sulfides RbAgZnS2 and Cs2Ag2Zn2S45MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra2NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13Synthesis, crystal structure and optical properties of the first Hg-based polyselenide Ba2HgSe51Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Salt-inclusion sulfides [K 4 Cl][M II 11 In 9 S 26 ] (M II = Zn, Cd) displaying robust nonlinear optical activity4Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations4Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations29Discovering Pseudo-Supertetrahedral Functional Units in Salt-Inclusion Nonlinear Optical Material [Ba22(SO4)5][Zn14Ga18S58]14SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold4

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  1. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  2. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

    Read original paper ↗ ·

  3. BaB2S4: An Efficient and Air-Stable Thioborate as Infrared Nonlinear Optical Material with High Laser Damage Threshold

    Chemistry of Materials · 2018-10-16

    Hao Li, Guangmao Li, Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  4. Ba10Zn7M6Q26: Two New Mid-infrared Nonlinear Optical Crystals with T2 Supertetrahedron 3D Framework

    Crystal Growth & Design · 2018-12-14

    Yanyan Li, Hui Wang, Bo-Wen Sun, Qinqin Ruan, Yan-Ling Geng, Pengfei Liu, Lei Wang, Li‐Ming Wu

    Read original paper ↗ ·

  5. Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)

    Inorganic Chemistry Frontiers · 2018-12-20

    Ming Wen, Hongping Wu, Shichao Cheng, Jun Sun, Zhihua Yang, Xiaohong Wu, Shilie Pan

    Read original paper ↗ ·

  6. ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences

    Chemical Communications · 2019-01-01

    Ailijiang Abudurusuli, Kui Wu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  7. Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 4

    New Journal of Chemistry · 2019-01-01

    Yi Huang, Xiaowen Wu, Sadeh Beysen

    Read original paper ↗ ·

  8. Quaternary semiconductor Ba 8 Zn 4 Ga 2 S 15 featuring unique one-dimensional chains and exhibiting desirable yellow emission

    Chemical Communications · 2019-01-01

    Yanyan Li, Pengfei Liu, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

    Read original paper ↗ ·

  9. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  10. Ba10In6Zn7S26-nZnS: An Inorganic Composite System with Interface Phase-Matching Tuned for High-Performance Infrared Nonlinear Optical Materials

    Inorganic Chemistry · 2019-03-01

    Anyi Zhou, Weilong Zhang, Chensheng Lin, Fang-Yu Yuan, Yongyu Pang, Hao Zhang, Wen‐Dan Cheng, Jing Zhu, Guoliang Chai

    Read original paper ↗ ·

  11. Growth and physicochemical investigations on wide bandgap 2D polymeric amino acetic acid sulfato dilithium metal–organic framework

    Journal of Materials Science Materials in Electronics · 2019-04-01

    Vadivel Sasikala, Jeyaperumal Kalyana Sundar, Muppudathi Anna Lakshmi

    Read original paper ↗ ·

  12. Solvothermal Syntheses and Characterizations of Four Quaternary Copper Sulfides BaCu3MS4 (M = In, Ga) and BaCu2MS4 (M = Sn, Ge)

    Inorganic Chemistry · 2019-11-04

    Yan Liu, Xuedan Song, Ren‐Chun Zhang, Fengyi Zhou, Jiangwei Zhang, Xiao‐Ming Jiang, Min Ji, Yong‐Lin An

    Read original paper ↗ ·

  13. One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy

    Inorganic Chemistry · 2020-01-30

    Ya Feng Yang, Kui Wu, Bingbing Zhang, Xiaowen Wu, Ming‐Hsien Lee

    Read original paper ↗ ·

  14. Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se8

    Inorganic Chemistry · 2020-12-23

    Xiao Ji, Hongping Wu, Bingbing Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  15. Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system

    Dalton Transactions · 2021-01-01

    Huanhuan Cheng, Abudukadi Tudi, Peng Wang, Kewang Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  16. Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 3

    Dalton Transactions · 2021-01-01

    Hongbo Gao, Ruijiao Chen, Kewang Zhang, Ailijiang Abudurusuli, Kangrong Lai, Junjie Li

    Read original paper ↗ ·

  17. Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks

    Unknown journal · 2021-04-19

    Hua Lin, Xin‐Tao Wu, Qi‐Long Zhu

    Read original paper ↗ ·

  18. AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds

    Inorganic Chemistry · 2021-06-17

    Man-Man Chen, Shenghua Zhou, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  19. β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement

    Journal of Materials Chemistry C · 2021-11-29

    Zhen Qian, Qiang Bian, Hongping Wu, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  20. Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Chao Zhang, Shenghua Zhou, Yu Xiao, Hua Lin, Yi Liu

    Read original paper ↗ ·

  21. Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response

    Inorganic Chemistry · 2022-08-10

    Xiao Fen Huang, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  22. Solvothermal syntheses, crystal structures, and photocurrent responses of quaternary sulfides RbAgZnS2 and Cs2Ag2Zn2S4

    Journal of Solid State Chemistry · 2022-08-10

    Yan Liu, Dejun Xuan, Zhangbin Song, Lingqi Geng, Bin Zhang, Tong Liu

    Read original paper ↗ ·

  23. MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li, Feng Yu

    Read original paper ↗ ·

  24. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

    Materials Today Chemistry · 2023-09-20

    Pengcheng Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  25. Synthesis, crystal structure and optical properties of the first Hg-based polyselenide Ba2HgSe5

    Journal of Solid State Chemistry · 2023-12-02

    Jinlong Shi, Mengran Sun, Chunxiao Li, Jiyong Yao

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  26. Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Ning Zhao, Dazhi Lu, Jingjing Xu, Kui Wu, Haohai Yu, Huaijin Zhang

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  27. Salt-inclusion sulfides [K 4 Cl][M II 11 In 9 S 26 ] (M II = Zn, Cd) displaying robust nonlinear optical activity

    Materials Chemistry Frontiers · 2024-01-01

    Yangping Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  28. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie · 2025-03-18

    Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  29. Expanding the Spectral Range in T2‐Supertetrahedral Nonlinear Optical Chalcogenides via Incorporating Inorganic Polycations

    Angewandte Chemie International Edition · 2025-03-18

    Shao‐Min Pei, Xiaoming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  30. Discovering Pseudo-Supertetrahedral Functional Units in Salt-Inclusion Nonlinear Optical Material [Ba22(SO4)5][Zn14Ga18S58]

    ACS Materials Letters · 2025-03-21

    Jia-Xiang Zhang, Mao‐Yin Ran, A-Yang Wang, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  31. SrZnGeSe 4 : a promising infrared nonlinear optical material with strong second harmonic generation and high laser-induced damage threshold

    Optics Express · 2025-03-27

    Hongshan Wang, Ran An, Yi Du, Shilie Pan, Junjie Li

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