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RESEARCH PAPER · Chemistry of Materials · 2016

Understanding the Local and Electronic Structures toward Enhanced Thermal Stable Luminescence of CaAlSiN3:Eu2+

Lei Chen, Mi Fei, Zhao Zhang, Yang Jiang, Shifu Chen, Yongqi Dong, Zhihu Sun, Zhi Zhao, Yibing Fu, Jinhua He, Can Li, Zheng Jiang

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Understanding the Local and Electronic Structures toward Enhanced Thermal Stable Luminescence of CaAlSiN3:Eu2+OriginalFirst-principles and experimental characterization of the electronic properties of CaGaSiN 3 and CaAlSiN 3 : the impact of chemical disorder13Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects1025Synthesis and photoluminescence properties of Mn 4+ -doped magnetoplumbite-related aluminate X-type Ca 2 Mg 2 Al 28 O 46 and W-type CaMg 2 Al 16 O 27 red phosphors33Commendable Eu2+-Doped Oxide-Matrix-Based LiBa12(BO3)7F4 Red Broad Emission Phosphor Excited by NUV Light: Electronic and Crystal Structures, Luminescence Properties75Enhanced photoluminescence property of single-component CaAlSiN3: Ce3+, Eu2+ multicolor phosphor through Ce3+-Eu2+ energy transfer22Synthesis, Crystal Structure, and Luminescence Properties of Tunable Red-Emitting Nitride Solid Solutions (Ca 1– x Sr x ) 16 Si 17 N 34 :Eu 2+ for White LEDs38High temperature degradation mechanism of a red phosphor, CaAlSiN3:Eu for solid-state lighting24Critical Review—Narrow-Band Emission of Nitride Phosphors for Light-Emitting Diodes: Perspectives and Opportunities72Crystal field splitting of 4fn−15d-levels of Ce3+ and Eu2+ in nitride compounds110Thermal Quenching Mechanism of CaAlSiN3:Eu2+ Red Phosphor58Color selective manipulation in Li 2 ZnGe 3 O 8 :Mn 2+ by multiple-cation substitution on different crystal-sites40Simultaneous enhancement of photoluminescence and afterglow luminescence through Bi 3+ co-doping in the Sr 3 Al 2 O 5 Cl 2 :Eu 2+ phosphor16Controllable site occupation of Eu in intricate superstructure of perovskite Sr3Al2O6: Eu, Dy, Li to produce red luminescence4The Enhanced Red Emission and Improved Thermal Stability of CaAlSiN3:Eu2+ Phosphors by Using Nano-EuB6 as Raw Material29Down-Conversion Nitride Materials for Solid State Lighting: Recent Advances and Perspectives794On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors40Preparation, crystal structure and luminescence properties of red-emitting Lu3Al5O12: Mn4+ ceramic phosphor36Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis7A narrow-band blue emitting phosphor Ca 8 Mg 7 Si 9 N 22 :Eu 2+ for pc-LEDs49Failure Mechanism of Phosphors in GaN‐Based White LEDs19Unraveling the Mechanisms of Thermal Quenching of Luminescence in Ce3+-Doped Garnet Phosphors238Synthesis, properties, and package of Eu2+ doped green-yellow Ba(Ca)SiO(N) phosphors in NUV LED9Synthesis, crystal structure, and photoluminescence of Eu2+, Ce3+, Mn2+ doped oxynitride phosphors8Enhanced thermal quenching characteristic via carbon doping in red‐emitting CaAlSiN 3 :Eu 2+ phosphors24Facile fabrication of thermal stable Eu(HCOO)3 red-emitting crystals with high color purity for near-ultraviolet chip triggered white light-emitting diodes17Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu Phosphor221Site‐Selective Occupancy of Eu2+Toward Blue‐Light‐Excited Red Emission in a Rb3YSi2O7:Eu Phosphor102Synthesis and photoluminescence of Yb2+/Dy3+ doped Ca2Si3O2N4 oxynitride phosphors3Improved photoluminescence property by homogeneous deposition-precipitation method for Eu2+ doping in Si–N–O frameworks5Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288Lead-Free Perovskite Narrow-Bandgap Oxide Semiconductors of Rare-Earth Manganates55Design of a CaAlSiN3:Eu/glass composite film: Facile synthesis, high saturation-threshold and application in high-power laser lighting53A high quantum efficiency CaAlSiN3:Eu2+ phosphor-in-glass with excellent optical performance for white light-emitting diodes and blue laser diodes186Optical and reliability properties studies of Sr4Al14O25:Eu2+ film for high-CRI white LEDs7Narrow-band emitters in LED backlights for liquid-crystal displays217Thermally Robust and Color-Tunable Blue-Green-Emitting BaMgSi 4 O 10 :Eu 2+ ,Mn 2+ Phosphor for Warm-White LEDs44A zero-thermal-quenching perovskite-like phosphor with an ultra-narrow-band blue-emission for wide color gamut backlight display applications67High partial thermal conductivity of luminescence sites: a crucial factor for reducing the heat-induced lowering of the luminescence efficiency8Thermal stability of nitride phosphors for light-emitting diodes66A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications41Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor21Enhanced red emission and improved thermal quenching of CaAlSiN 3 :Eu 2+ phosphors via boron doping4Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Reidinger defects induced thermally stable green emission from Eu2+, Mn2+ co-doped Ba0.75Al11O17.25 transparent ceramics16Highly thermally stable red phosphor-in-glass films for high-power laser lighting21Luminescence properties, crystal field and nephelauxetic effect on (NH4)2NaMF6: Mn4+ (M = Al, Ga and In) red phosphors for warm white light-emitting diodes22Ce-doping effect on dosimetric properties of mullite single crystals synthesized by the floating zone method5Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137High brightness and vibronic luminescent behavior of YAG:Mn 4+ /Ca 2+ red phosphor for preparing phosphor-in-glass in white LED12Quantum Dots-Based Light Conversion Strategy for Customized Cultivation of Microalgae0Energy Conversion and Transfer in the Luminescence of CeSc3(BO3)4:Cr3+ Phosphor6Effects of framework dopants on luminescent properties of red nitride phosphors via band structure modelling1Robust white light emission of UV pumped SrCeO3: xSm3+ perovskites for wLEDs9Enhancement of photoluminescence properties in Na+ doped K2BaPO4F:Sm3+ phosphors13Negative Thermal Quenching of Photoluminescence: An Evaluation from the Macroscopic Viewpoint28Quantum dot-based light conversion strategy for customized cultivation of microalgae15Broadband Green-Yellow KGaSi2O6:Eu2+ Phosphor with Excellent Thermal Stability for Near Ultraviolet-Pumped White-Light-Emitting Diodes1Li Substitution Strategy for Enhancing Quantum Efficiency and Improving Thermal Stability of Red‐Light Mn 4+ ‐Activated Fluoride for Wide‐Gamut Displays15Rational Design of Nitride Phosphor-In-Glass with Robust Stability and Photoluminescence Performance6Facile synthesis of rare earth ions doped LiSr4(BN2)3 phosphors for white light-emitting diodes10Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry27Enhancing Down-Shifting Solar Cells by Scattering Particles0Acid Post-Treatment Triggered High-Efficiency Blue-Emitting LiNa2Sr8B12O24F6Cl:Eu2+ Phosphors toward Multipurpose LED Applications0Color‐Tunable Emission via Site‐Selective Occupation of Eu2+ Activators in Silicate Phosphors17Boosting narrow-band near-infrared-emitting efficiency of thulium by lattice modulation for reflective absorption bioimaging20Near-Infrared Phosphor Zn2InGaO5:Cr3+ with a Wide Bandgap Applicable for Light Sources at Low Temperature9Synergistic luminescence enhancement in bi-sensitized praseodymium-doped barium cerates: Implications for white light emission in optoelectronics3Develop Superior Green‐Emitting K‐Rich Eu 2+ ‐Activated Nepheline Phosphors for n‐UV‐Driven Pc‐WLEDs1Mechanisms of photochromism and optical properties in Sm3+-doped K0.5Na0.5NbO3 ceramics0Design of phosphors in glass doped with silver nanocrystals (Sr,Ca)AlSiN 3 :Eu 2+ for sunlight-like lighting excited by violet light chips0Structural and photophysical investigation of gadolinium based Eu3 + doped Gd3GaO6 phosphor: A red emitter with high color purity for WLEDs application6Chemical effects of Cu-group metals on the structural modification of fullerene: a computational study of biosensor for guanine adsorption0Anionic Condensation-Guided Synthesis of LaSi2N3O: A “Missing” Structure in the Ln–Si–N–O Series of Oxonitridosilicate Phosphor Materials0Tunable Luminescence and Energy Transfer of Eu 3+ /Tb 3+ Co‐Activated Inorganic Phosphors for Anti‐Counterfeiting and Information Encryption Applications2Mg2 +‑induced chemical pressure promotes Eu reduction to achieve high color-purity red emission0

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  1. First-principles and experimental characterization of the electronic properties of CaGaSiN 3 and CaAlSiN 3 : the impact of chemical disorder

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  2. Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects

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    Xian Qin, Xiaowang Liu, Xiaowang Liu, Wei Huang, Marco Bettinelli, Xiaogang Liu, Xiaogang Liu

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  3. Synthesis and photoluminescence properties of Mn 4+ -doped magnetoplumbite-related aluminate X-type Ca 2 Mg 2 Al 28 O 46 and W-type CaMg 2 Al 16 O 27 red phosphors

    Ceramics International · 2017-03-01

    Takuya Sasaki, Jun Fukushima, Yamato Hayashi, Hirotsugu Takizawa

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  4. Commendable Eu2+-Doped Oxide-Matrix-Based LiBa12(BO3)7F4 Red Broad Emission Phosphor Excited by NUV Light: Electronic and Crystal Structures, Luminescence Properties

    ACS Applied Materials & Interfaces · 2017-06-27

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  5. Enhanced photoluminescence property of single-component CaAlSiN3: Ce3+, Eu2+ multicolor phosphor through Ce3+-Eu2+ energy transfer

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    Zeqing Hu, Zhiyuan Cheng, Peipei Dong, Han Zhang, Yanjie Zhang

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  6. Synthesis, Crystal Structure, and Luminescence Properties of Tunable Red-Emitting Nitride Solid Solutions (Ca 1– x Sr x ) 16 Si 17 N 34 :Eu 2+ for White LEDs

    Inorganic Chemistry · 2017-08-28

    Hang Chen, Jianyan Ding, Xin Ding, Xicheng Wang, Yaxin Cao, Zhengyan Zhao, Yuhua Wang

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  7. High temperature degradation mechanism of a red phosphor, CaAlSiN3:Eu for solid-state lighting

    Journal of Applied Physics · 2017-09-19

    Masatsugu Oishi, Shohei Shiomi, Takashi Yamamoto, Tomoyuki Ueki, Yoichiro Kai, Shigefusa F. Chichibu, Aiko Takatori, Kazunobu Kojima

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  8. Critical Review—Narrow-Band Emission of Nitride Phosphors for Light-Emitting Diodes: Perspectives and Opportunities

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  9. Crystal field splitting of 4fn−15d-levels of Ce3+ and Eu2+ in nitride compounds

    Journal of Luminescence · 2017-10-26

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  10. Thermal Quenching Mechanism of CaAlSiN3:Eu2+ Red Phosphor

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  11. Color selective manipulation in Li 2 ZnGe 3 O 8 :Mn 2+ by multiple-cation substitution on different crystal-sites

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  12. Simultaneous enhancement of photoluminescence and afterglow luminescence through Bi 3+ co-doping in the Sr 3 Al 2 O 5 Cl 2 :Eu 2+ phosphor

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    Wei Xie, Changwei Zou, Songquan Li, Jianhui Sun, Fengwen Kang, Guohuan Sun

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  13. Controllable site occupation of Eu in intricate superstructure of perovskite Sr3Al2O6: Eu, Dy, Li to produce red luminescence

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  14. The Enhanced Red Emission and Improved Thermal Stability of CaAlSiN3:Eu2+ Phosphors by Using Nano-EuB6 as Raw Material

    Nanomaterials · 2018-01-25

    Wenquan Liu, Dan Wu, Hugejile Chang, Ruxia Duan, Wenjie Wu, Guleng Amu, Kefu Chao, Bao Fu-Quan, Ojiyed Tegus

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  15. Down-Conversion Nitride Materials for Solid State Lighting: Recent Advances and Perspectives

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  16. On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors

    Optical Materials · 2018-04-12

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  17. Preparation, crystal structure and luminescence properties of red-emitting Lu3Al5O12: Mn4+ ceramic phosphor

    Journal of the European Ceramic Society · 2018-08-22

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  18. Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis

    Zeitschrift für Naturforschung B · 2018-11-22

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  19. A narrow-band blue emitting phosphor Ca 8 Mg 7 Si 9 N 22 :Eu 2+ for pc-LEDs

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  20. Failure Mechanism of Phosphors in GaN‐Based White LEDs

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  21. Unraveling the Mechanisms of Thermal Quenching of Luminescence in Ce3+-Doped Garnet Phosphors

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  22. Synthesis, properties, and package of Eu2+ doped green-yellow Ba(Ca)SiO(N) phosphors in NUV LED

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  23. Synthesis, crystal structure, and photoluminescence of Eu2+, Ce3+, Mn2+ doped oxynitride phosphors

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  24. Enhanced thermal quenching characteristic via carbon doping in red‐emitting CaAlSiN 3 :Eu 2+ phosphors

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  25. Facile fabrication of thermal stable Eu(HCOO)3 red-emitting crystals with high color purity for near-ultraviolet chip triggered white light-emitting diodes

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  26. Site‐Selective Occupancy of Eu 2+ Toward Blue‐Light‐Excited Red Emission in a Rb 3 YSi 2 O 7 :Eu Phosphor

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  27. Site‐Selective Occupancy of Eu2+Toward Blue‐Light‐Excited Red Emission in a Rb3YSi2O7:Eu Phosphor

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  28. Synthesis and photoluminescence of Yb2+/Dy3+ doped Ca2Si3O2N4 oxynitride phosphors

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  29. Improved photoluminescence property by homogeneous deposition-precipitation method for Eu2+ doping in Si–N–O frameworks

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  30. Broad-band emission in metal halide perovskites: Mechanism, materials, and applications

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  31. Lead-Free Perovskite Narrow-Bandgap Oxide Semiconductors of Rare-Earth Manganates

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  32. Design of a CaAlSiN3:Eu/glass composite film: Facile synthesis, high saturation-threshold and application in high-power laser lighting

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  33. A high quantum efficiency CaAlSiN3:Eu2+ phosphor-in-glass with excellent optical performance for white light-emitting diodes and blue laser diodes

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  34. Optical and reliability properties studies of Sr4Al14O25:Eu2+ film for high-CRI white LEDs

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  35. Narrow-band emitters in LED backlights for liquid-crystal displays

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  36. Thermally Robust and Color-Tunable Blue-Green-Emitting BaMgSi 4 O 10 :Eu 2+ ,Mn 2+ Phosphor for Warm-White LEDs

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  37. A zero-thermal-quenching perovskite-like phosphor with an ultra-narrow-band blue-emission for wide color gamut backlight display applications

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  38. High partial thermal conductivity of luminescence sites: a crucial factor for reducing the heat-induced lowering of the luminescence efficiency

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  39. Thermal stability of nitride phosphors for light-emitting diodes

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  40. A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications

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  41. Efficient red and broadband near‐infrared luminescence in Mn 2+ /Yb 3+ ‐doped phosphate phosphor

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  42. Enhanced red emission and improved thermal quenching of CaAlSiN 3 :Eu 2+ phosphors via boron doping

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  43. Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications

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  44. Reidinger defects induced thermally stable green emission from Eu2+, Mn2+ co-doped Ba0.75Al11O17.25 transparent ceramics

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  45. Highly thermally stable red phosphor-in-glass films for high-power laser lighting

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  46. Luminescence properties, crystal field and nephelauxetic effect on (NH4)2NaMF6: Mn4+ (M = Al, Ga and In) red phosphors for warm white light-emitting diodes

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  47. Ce-doping effect on dosimetric properties of mullite single crystals synthesized by the floating zone method

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  48. Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure

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  49. High brightness and vibronic luminescent behavior of YAG:Mn 4+ /Ca 2+ red phosphor for preparing phosphor-in-glass in white LED

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  50. Quantum Dots-Based Light Conversion Strategy for Customized Cultivation of Microalgae

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