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RESEARCH PAPER · Journal of Materials Chemistry C · 2022

Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure

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Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structureOriginalAchieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting47An efficient blue-excitable broadband Y 3 ScAl 4 O 12 :Ce 3+ garnet phosphor for WLEDs13High-Efficiency Energy Transfer from Sm3+ to Eu3+ in Red-Emitting Phosphor Ceo2: Sm3+, Eu3+0High-efficiency energy transfer in the strong orange-red-emitting phosphor CeO 2 :Sm 3+ , Eu 3+17Site Occupation Regulation of Eu2+ by the Introduction of (Bo3)3- Group Towards Full-Visible-Spectrum Emission in a Singly Doped K2basr(Po4)2:Eu2+ Phosphor0Thermal-stability synergy improvement of Sm 3+ and Eu 3+ in Ca 3.6 In 3.6 (PO 4 ) 6 : the effect of local symmetry30To achieve tunable-color emission in a novel tri-doped phosphate sulfate phosphor: Tb 3+ as the energy transfer bridge1The Luminescence Properties of the Interstitial Eu2+ in SrB2O4 for UV Light‐Emitting Diode6On the Crystal Chemistry of RE2Si2O7: Revisited Structures, Group–Subgroup Relationship, and Insights of Ce3+-Activated Radioluminescence19A new strategy to improve the thermal stability of (Sr, Ba)2SiO4: Eu2+ phosphors by ion substitution engineering17Novel Red‐Emitting Gd 3 BW 1‐x MoxO 9 : Eu 3+ Phosphor with High Thermal Stability for Application in UV‐Excited WLEDs and Rapid Visualization of Latent Fingerprints0Investigation of gamma-ray sensitivity of YAG:Ce based scintillation structures2Dehydration-Triggered Afterglow Transition in a Mellitate-Based Coordination Polymer16Near‐Infrared Persistent Phosphor‐Mediated Smart Sensing Light‐Emitting Diodes for Advanced Driver Assistance Systems11Near-UV-excitable broadband green-emitting Ca2LaHf2GaAl2O12:Ce3+ garnet-type phosphors for high color rendering warm-white LEDs42Cyan-to-yellow color tunable NaAlSiO4:Eu2+ with high quantum efficiency and thermal stability for white light-emitting diodes14Nano-Coprecipitation Route Synthesis of Highly-Efficient Submicron (Sr,Ba)2SiO4:Eu2+ Phosphors with Enhanced Thermal Stability for MicroLED Color Conversion14Cation defects succeed in triggering super stability of narrow-band blue-emitting phosphors Ca3Sc2Si3O12: Bi3+ for backlighting display application29Enhancing External Quantum Efficiency of Blue-Emitting Phosphor Ba(K)-β-Al2O3:Eu2+ by Lattice Site Engineering for Full-Spectrum Lighting40First-Principles Analysis of the Effects of Covalency and Ionicity on the 4f–5d Transition Energy of Ce3+ in Garnet-Type Oxides5Insights of Peculiar Green-Yellow Emission Occurrence in Ce3+-Doped Barium Yttrium Orthogermanate Phosphors5Highly Quantum Efficient and Thermally Stable Near‐Infrared‐Emitting K‐β‐Al 2 O 3 :Cr 3+ Phosphor56Efficient Blue–Violet Phosphor with Small Stokes‐Shift for Full‐Spectrum Lighting39Efficient broadband yellow-emitting Mg2.5Lu1.5Al1.5Si2.5O12:Ce3+ garnet phosphors for blue-light-pumped white light-emitting diodes21Improving the blue emission from Eu2+ by codoping Re3+ ions (Re Y, La, Gd, Lu) in NaMgPO45Tuning Eu 2+ luminescence in Sr 8 CaLu (PO 4 ) 7 via Na + -induced local structure engineering for violet-chip-excitable full-spectrum lighting10Excitation wavelength-dependent long-afterglow Sb, Mn-doped CsCdCl3 perovskite for anti-counterfeiting applications17Structural features and photoluminescence of new transparent MgAl2O4 nanoceramics with chromium impurity4Trap engineering through chemical doping for ultralong X-ray persistent luminescence and anti-thermal quenching in Zn 2 GeO 451A novel borate phosphor Lu 5 Ba 6 B 9 O 27 :Ce 3+ codoped with Sr 2+ /Tb 3+ for NUV-white light emitting diode application10Achieving white emission by site-selective occupation of Eu 2+ in K 2 BaSr(PO 4 ) 2− x (BO 3 ) x :Eu 2+12An efficient blue–violet phosphor: an advanced material designed for high-quality full-spectrum lighting11High thermal stability and quantum efficiency of (Sr,Ba)2Ga2SiO7: Eu2+ phosphors for full-spectrum WLEDs17High-performance green-emitting Ca 2 YScAl 2 Si 2 O 12 :Ce 3+ garnet phosphors and their applications in high-quality blue-chip-pumped white LEDs48Highly efficient and thermally stable broadband green-emitting BaY 2 Sc 2 Al 2 SiO 12 :Ce 3+ phosphors enabling warm-white LEDs with high luminous efficacy and high color rendering index44Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Recent advances in Bi 3+ -activated narrow-band emitting phosphors for backlight display applications10Rgb-Tricolor Multimodal Luminescence of Ce 3 and Mn 2 in Mg 2Al 4Si 5O 18 Via Site Occupancy Engineering for Anticounterfeiting Applications0Stimulated-source-independent persistent luminescence phosphor Sr 2 Ta 2 O 7 :Tb 3+ , Tm 3+ for multi-mode anti-counterfeiting applications41Structure and photoluminescence of Mn 2+/4+ -activated doubly ordered spinel Mg 4 (Ga/Al)SbO 8 : site-selective Al 3+ -to-Ga 3+ substitution enabling Mn 4+ accumulation, excellent anti-thermal quenching of Mn 2+ green emission, and optical thermometry17Thermally Stable Red-Emitting Ca18K3Sc(PO4)14:Mn2+ Phosphor and Enhanced Luminescence by Energy Transfer Between Ce3+-Eu2+-Mn2+22Deep‐Red (Sr,Ba)Lu2O4: Eu2+ Phosphor for Full‐Spectrum Lighting7Mechanism analysis on manipulation of long afterglow luminescence properties of Y3Al5-xGaxO12:Ce3+, Cr3+ phosphors10Ce 3+ -Activated SrLu 2 Al 3 ScSiO 12 Cyan-Green-Emitting Garnet-Structured Inorganic Phosphor Materials toward Application in Blue-Chip-Based Phosphor-Converted Solid-State White Lighting68Effect of the Ratio of Na, K and Li on the PL Performance, Color and Composition of UCr4C4 Phosphor0Heterostructure anion-groups guided design enabling customizable Eu2+ spectrum behavior in borophosphate7Controllable Synthesis of Ba2SiO4:Eu2+ Phosphors with Uniform Size and Shape for Micro-LED Color Conversion5Highly efficient blue-light-excitable ultra-broadband orange-emitting Mg2.5Y1.5Al1.5Si2.5O12:Ce3+ garnet phosphors for solid-state lighting24Efficient Deep-Blue Light-Emitting Diodes from Highly Luminescent Eu2+-Doped Alkali Metal Halide Nanocrystals via Lattice Field Modulation30Efficient Energy Transfer for Near-Perfect Quantum Efficiency and Thermal Stability10Facile synthesis of rare earth ions doped LiSr4(BN2)3 phosphors for white light-emitting diodes10Crystallographic Engineering to Develop Ultra‐Narrow‐Band Cyan‐Emitting UCr 4 C 4 ‐Type Phosphor for Healthy LED Lighting and Display24Effects of Re3+ (Re = Y, La, Gd) Co-doping on Luminescence Properties of MSi2O2N2:Eu2+ (M = Ca, Sr) Phosphors5Color tuning by Si/Ge substitution in Cr4+ doped melilite inorganic pigments1Tailoring traps in Eu2+ activated persistent phosphors for multilevel information storage and encryption23Trap Depth Engineering from Persistent Luminescence Phosphors Mg2-xZnxSnO4 for Dynamic Optical Information Encryption Application9Co-doping Sm3+ transforms Y2Ge2O7:Pr3+ into a novel orange-reddish long afterglow phosphor12Electrical stimulation for brighter persistent luminescence32RGB-tricolor multimodal luminescence of Ce3+ and Mn2+ in Mg2Al4Si5O18 via site occupancy engineering for anticounterfeiting applications8Improvement of thermal damage resistance of SrAl2O4:Eu2+, Dy3+ persistent phosphor by a low temperature pre-annealing and its mechanism2Fluorescent Tetraphenylethylene-Based Cerium Metal–Organic Frameworks for White-Light-Emitting Diodes10Energy transfer and tunable photoluminescence of novel white-emitting Sr8MgY(PO4)7: Ce3+/Eu2+/Sm3+ phosphors7Stability of Phosphors for White LED Excitable by Violet Light3Tailoring of Spectral Behaviors in Ce3+-Activated Ba2Gd8(SiO4)6O2 Cyan-Emitting Phosphors via Site Substitution Engineering for Plant Growth and Full-Spectrum White Light-Emitting Diodes14Luminescent tunable Ba2MgY2(BO3)3:Ce3+,Tb3+ phosphors with significantly improved performance based on energy transfer12Preparation and photoluminescence characterization of novel red emitting Ba4CaB4O10F2:xEu3+ fluorescent materials3High-brightness and high-color-purity red-emitting Ca8MEu(PO4)7 (M = Mg and Zn) phosphate phosphors for near-UV-pumped pc-WLEDs40Exploration of the Structure and Composition of Sn(S₀.₆Te₀.₄) Thin Film as a Potential Absorber in Solar Cell Technology0CaLuGaO 4 :Bi 3+ ,Al 3+ blue phosphor with excellent thermal stability for multiple LED applications10DMF-mediated polycrystalline phase transition of Cd-based perovskites: dual-emission tuning for temperature sensing and single-component white LEDs7Generating cyan emission via ammonia-thermal nitridation: Na 18− x Ca 13+ x Mg 5 (PO 4− y N y ) 18 :Eu 2+1Highly Efficient Wide-Spectrum Green Y 2 Bascal 3 Sio 12:Ce 3+ Phosphor for Advanced White Leds Applications0Highly Efficient Wide-Spectrum Green Y2bascal3sio12:Ce3+ Phosphor for Advanced White Leds Applications0Investigation on the Wavelength Dependency of Eu 3+ by Time‐Resolved Luminescence Spectroscopy2La 2 (CN 2 ) 3 – the missing link of rare-earth carbodiimides, prepared through an efficient synthetic route and its Ce 3+ activated photoluminescence5Near-infrared luminescent materials: a review of their practical applications and prospective advancements47Pressure-triggered polychromatic luminescence in Eu 2+ -activated Ca 8 Zn(SiO 4 ) 4 Cl 2 phosphors for high-sensitivity visual optical manometry29Synthesis and white LEDs applications of single Eu2+-activated garnet phosphors0Two-step model for predicting 4f→5d transition energies of Ce3+ in garnet-type oxides based on first-principles calculations and machine learning8Long Persistent Luminescence in Cu2+-Doped SrGa2Ge2O8 for Information Storage and Encryption21Exploring Oxonitridosilicate Synthesis: From Oxide Zeolites to Nitride Frameworks2Insight into Luminescence Properties of Robust BaSi3Al3O4N5:Ce3+ Blue Persistent Phosphors for Optical Information Storage11Eu2+-doped oxyfluoride glass scintillator for X-ray imaging23Multilevel Trap‐Controlled Bright Mechanoluminescence of Sr/CaGa 2 S 4 : Eu 2+ for Stress Sensing Applications23Luminescence enhancement and color regulation of Sr2LiAlO4-1.5N : Eu2+ phosphor for high color rendering index white LED applications4Compositionally Tuned Self-Activated Alkali Metal Vanadates for High Color Rendering White LEDs and IR Reflective Pigments2Synergetic effect of oxygen vacancy and Cr triggered super-long persistent luminescence in green Ce, Cr: YAGG transparent ceramics11Adjustable emission and energy transfer of BaGdGaO4: Bi3+, Eu3+ phosphors with high quantum efficiency for multifunctional applications9Hydrogen production through visible light-induced water splitting using carbon-based CoCe-MOF as novel photocatalyst15Visible Light Excited Yb3+‐Doped Phosphor Via Eu2+ Bridged Energy Transfer Toward NIR‐II Spectroscopy Application13Ce3+-activated Ca2LuAl3Si2O12: A blue-light-excited broadband cyan-emitting garnet phosphor with an ultra-small Stokes shift for high performance white light-emitting diodes7Symmetry and singular site-occupancy-controlled strong near-narrow-band cyan emission from Ca3Xn2Ge3O12:Bi3 + (Xn = Sc, Y, Lu) phosphors for healthy WLED lighting8Design, classification, and applications of organic, luminescent lanthanide-based photoresponsive materials: A review59A Novel Yellow Phosphor(Ba 3 Sc 2 (BO 3 ) 4 : Eu 2+ ) Suitable for Full‐Spectrum Lighting, Featuring Tunable Photoluminescence and Enhanced Luminous Thermal Stability23Improved Luminescence Performance for W-LED Applications of the Eu3+-Activated Double Molybdate Red Phosphor NaLu(MoO4)29Charge Transfer State: A New Sensitization Route for Blue‐LED‐Excitable Near‐Infrared Phosphors11Cationic Substitution-Enabled Green-Emitting Gd 2– y Y y LuAl 4 GaO 12 : Ce 3+ Garnet Phosphors with High Quantum Efficiency and Superior Thermal Stability for Advanced WLEDs12Mixed‐Phase and Solid‐Solution in Single Particles Yielding Better Phosphors6Divalent Europium-containing colloidal metal halide nanocrystals for light-emitting applications7Highly efficient wide-spectrum green Y2BaScAl3SiO12:Ce3+ phosphor for advanced white LEDs applications5Photoluminescence Modulation of Cation-Induced Gold(I)-Thiolate Aggregates6Progressive chemical pressure-induced trap-controlled multimode luminescence5Efficient broadband reddish-orange emitting Mg2Y2.5Al1.5Si2O12:Ce3+ garnet phosphor opens up new avenues for multifunctional optical applications8Recent progress in Eu2+ activated red phosphors for white LEDs and laser displays: focusing on efficient host screening and innovative structural design20Effect of Tm3+ codoping on Ca2Si5N8:Eu2+, Tm3+ red long-afterglow phosphor0Tuning of the emission wavelength for AlN:Eu2+, Ca2+ phosphors prepared by freeze drying assisted combustion synthesis0Recent Studies of Defects in Persistent Luminescent Materials18Deciphering the Key Factors Governing Mn4+ Zero-Phonon Line Characteristics via Machine Learning Decoding of Host–Mn4+ Interactions3Topological Understanding of Luminescence in Eu 2+ -Doped Borate Phosphors3From Model to Material: Machine Learning Enabled Discovery of LED‐Compatible Phosphors4Smart Semiconductors: An Overview of AZnOS (A= Ca, Sr, Ba) Based Phosphors, Multi‐Stimuli Responsive Luminescence, and Potential Application Prospects12Ce3+-doped garnet phosphor to mitigate cyan spectral gap in full-spectrum white LEDs4Activating Deep‐Red Emission in Borate Phosphors via Low‐Coordination Engineering for Efficient Plant Lighting7A Blue Light–Excited Broadband Chartreuse‐Emitting LuMg 2 Al 3 Si 2 O 12 :Ce 3+ Garnet Phosphor With High Thermal Stability for High‐Performance White LEDs0Photoluminescence and thermoluminescence properties of Ce-doped Ba3Bi2(PO4)4 phosphors0Understanding the charge state of the Eu ion in anti-perovskites: the role of intrinsic defects0Functional Interface Engineering Enables Selective Multicolor Upconversion in NaErF 4 @NaYF 4 Core–Shell Nanocrystals0Bi3+/Te4+ Co-Doped Cs2Sn0.85Zr0.15Cl6 Single-Matrix White Phosphors for UV-Excited WLEDs0Chemical-unit co-substitution enables orthogonally decoupled color tuning in La2SrGa4Ge2O14:Dy3+,Tb3+ germanate phosphors0Unveiling the effect of Eu2+ and Ce3+ activation on the first rare-earth oxonitridolithosilicate LiGd2Si3N5O2: Crystal structure and luminescence properties0Study on Optical and Mechanical Properties of SiOxNy Films0Isolated Mn2+-activated near-infrared phosphors under nephelauxetic effects and strong crystal field0Highly sensitive multimodal visual manometry based on the pressure-activated luminescence of Al2O3:Ce3+0Oxide Glass‐Based Phosphors for White Light Emitting Diodes: Current Status, Challenges, and Future Perspective2A Metastable Polymorph of SrSiO 3 Containing [Si 8 O 24 ] 16– Single Chains: Synthesis, Structure, and Luminescence0Unraveling the Origin of Mn(II) Near‐Infrared Luminescence via Crystal Field Engineering5First-principles study of defect-induced luminescence mechanism in ternary nitride Li3AlN20Ca2LaZr2Ga3O12:Bi3 +: A new non-rare earth doped thermally robust blue phosphor for sustainable and full-spectrum lighting0Exploring the Potential for Yttrium Recovery from Secondary Sources: (Bio)hydrometallurgical and Solvometallurgical Routes0Regulating cyan luminescence in Ca9ZnK(PO4)7: Eu2+ phosphors through Ca/Sr solid solution toward full-spectrum WLEDs0Chemical-unit Co-substitution enables quasi-orthogonally decoupled color tuning in La2SrGa4Ge2O14:Dy3+,Tb3+ germanate phosphors0Hybrid Copper(I) Iodide Scintillators: From Molecular Architecture to X‐Ray Imaging Applications0Robust and Highly Efficient Rare‐Earth‐Based Zero‐Dimensional Hybrid Halides via Cerium Sensitized Terbium Emission0Spectrally stable blue light-emitting diodes based on two-dimensional europium halide perovskite0Synthesis, structural, and optical characterization of Eu3+, Ce3+, and Dy3+ activated Ca0.6Li0.4Al0.6Si1.4N3 phosphors by microwave-assisted solution combustion synthesis for solid-state lighting applications0Recent progress in lanthanide-doped persistent luminescence materials for anti-counterfeiting: From single-mode to multimode0

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