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RESEARCH PAPER · Chemical Reviews · 2018

Down-Conversion Nitride Materials for Solid State Lighting: Recent Advances and Perspectives

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Down-Conversion Nitride Materials for Solid State Lighting: Recent Advances and PerspectivesOriginalA highly efficient and thermally stable green phosphor (Lu 2 SrAl 4 SiO 12 :Ce 3+ ) for full-spectrum white LEDs96Controllable optical tuning and improvement in Li + ,Eu 3+ -codoped BaSc 2 O 4 :Bi 3+ based on energy transfer and charge compensation96Controllable two-dimensional luminescence tuning in Eu 2+ ,Mn 2+ doped (Ca,Sr) 9 Sc(PO 4 ) 7 based on crystal field regulation and energy transfer61Mechanisms of catalytic reduction of CO 2 with heme and nonheme metal complexes133Photoluminescence tuning in a novel Bi 3+ /Mn 4+ co-doped La 2 ATiO 6 :(A = Mg, Zn) double perovskite structure: phase transition and energy transfer78Tunable dual emission of Ca 3 Al 4 ZnO 10 :Bi 3+ ,Mn 4+ via energy transfer for indoor plant growth lighting154Supramolecular Organization in Confined Nanospaces77A Review on Halide Perovskites as Color Conversion Layers in White Light Emitting Diode Applications92Development of near-ultraviolet-excitable single-phase white-light-emitting phosphor KBaY(BO3)2:Ce3+,Dy3+ for phosphor-converted white light-emitting-diodes48Site Occupation of Eu2+ in Ba2–xSrxSiO4 (x = 0–1.9) and Origin of Improved Luminescence Thermal Stability in the Intermediate Composition54Eu 2+ Site Preferences in the Mixed Cation K 2 BaCa(PO 4 ) 2 and Thermally Stable Luminescence577Alkali Lithosilicates: Renaissance of a Reputable Substance Class with Surprising Luminescence Properties78Integrated Surface Modification to Enhance the Luminescence Properties of K2TiF6:Mn4+ Phosphor and Its Application in White-Light-Emitting Diodes102Structural Confinement toward Giant Enhancement of Red Emission in Mn2+‐Based Phosphors165Control of Narrow-Band Emission in Phosphor Materials for Application in Light-Emitting Diodes160Persistent luminescence instead of phosphorescence: History, mechanism, and perspective680Color Conversion Materials for High‐Brightness Laser‐Driven Solid‐State Lighting404Mn4+-Doped Heterodialkaline Fluorogermanate Red Phosphor with High Quantum Yield and Spectral Luminous Efficacy for Warm-White-Light-Emitting Device Application56An overview on enhancing the stability of lead halide perovskite quantum dots and their applications in phosphor-converted LEDs1206A Thermally Robust La3Si6N11:Ce‐in‐Glass Film for High‐Brightness Blue‐Laser‐Driven Solid State Lighting133Moisture‐Resistant Mn4+‐Doped Core–Shell‐Structured Fluoride Red Phosphor Exhibiting High Luminous Efficacy for Warm White Light‐Emitting Diodes176Understanding the blue-emitting orthoborate phosphor NaBaBO 3 :Ce 3+ through experiment and computation49A narrow-band blue emitting phosphor Ca 8 Mg 7 Si 9 N 22 :Eu 2+ for pc-LEDs49A thermally stable narrow-band green-emitting phosphor MgAl 2 O 4 :Mn 2+ for wide color gamut backlight display application168Epitaxial growth via anti-solvent-induced deposition towards a highly efficient and stable Mn 4+ doped fluoride red phosphor for application in warm WLEDs73Fluorescence–phosphorescence dual emissive carbon nitride quantum dots show 25% white emission efficiency enabling single-component WLEDs164High-performance and moisture-resistant red-emitting Cs 2 SiF 6 :Mn 4+ for high-brightness LED backlighting86Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs107Multichannel photoluminescence tuning in Eu-doped apatite phosphors via coexisting cation substitution, energy transfer and valence mixing54Structure, luminescence and energy transfer in Ce 3+ and Mn 2+ codoped γ-AlON phosphors83On the luminance saturation of phosphor-in-glass (PiG) films for blue-laser-driven white lighting: Effects of the phosphor content and the film thickness98An advanced laser headlight module employing highly reliable glass phosphor55New strategy for designing orangish-red-emitting phosphor via oxygen-vacancy-induced electronic localization348Synthesis, spectroscopic properties and applications of divalent lanthanides apart from Eu2+108Realizing Visible Light Excitation of Tb3+ via Highly Efficient Energy Transfer from Ce3+ for LED‐Based Applications63Self-Trapped Excitons in All-Inorganic Halide Perovskites: Fundamentals, Status, and Potential Applications976Investigation of laser-induced luminescence saturation in a single-crystal YAG:Ce phosphor: Towards unique architecture, high saturation threshold, and high-brightness laser-driven white lighting119Sr[Li2Al2O2N2]:Eu2+—A high performance red phosphor to brighten the future340Application of thermally coupled energy levels in Er3+ doped CdMoO4 phosphors: Enhanced solid-state lighting and non-contact thermometry48Sr2LiScB4O10:Ce3+/Tb3+: A Green-Emitting Phosphor with High Energy Transfer Efficiency and Stability for LEDs and FEDs107Transparent Ceramics Enabling High Luminous Flux and Efficacy for the Next-Generation High-Power LED Light64Enhancing quantum efficiency and tuning photoluminescence properties in far-red-emitting phosphor Ca14Ga10Zn6O35:Mn4+ based on chemical unit engineering142Full visible spectra emission introduced by crystal-site engineering in β-Ca3(PO4)2-type solid solution phosphors for high quality white light emitting diodes application63Novel cyan‐emitting KBaScSi 2 O 7 :Eu 2+ phosphors with ultrahigh quantum efficiency and excellent thermal stability for WLEDs57Effects of cationic substitution on the luminescence behavior of Dy3+ doped orthophosphate phosphor87Data-Driven Discovery of Full-Visible-Spectrum Phosphor133New scheme of LiDAR-embedded smart laser headlight for autonomous vehicles48Self‐Trapped Exciton to Dopant Energy Transfer in Rare Earth Doped Lead‐Free Double Perovskite158Photoluminescence Control of UCr 4 C 4 -Type Phosphors with Superior Luminous Efficiency and High Color Purity via Controlling Site Selection of Eu 2+ Activators112Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes660Designing High‐Performance LED Phosphors by Controlling the Phase Stability via a Heterovalent Substitution Strategy76Ultra-broadband cyan-to-orange emitting Ba 1+x Sr 1−x Ga 4 O 8 :Bi 3+ phosphors: luminescence control and optical temperature sensing95A novel germanate based red-emitting phosphor with high efficiency, high color purity and thermal stability for white light-emitting diodes and field emission displays67Discovery of a novel rare-earth free narrow-band blue-emitting phosphor Y 3 Al 2 Ga 3 O 12 :Bi 3+ with strong NUV excitation for LCD LED backlights62Dual-site occupancy induced broadband cyan emission in Ba 2 CaB 2 Si 4 O 14 :Ce 3+79Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Upconversion-mediated Boltzmann thermometry in double-layered Bi 2 SiO 5 :Yb 3+ ,Tm 3+ @SiO 2 hollow nanoparticles74Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs99Recent progress on discovery of novel phosphors for solid state lighting88Lanthanide-Doped Bi 2 SiO 5 @SiO 2 Core–Shell Upconverting Nanoparticles for Stable Ratiometric Optical Thermometry73Color tuning of β-Ca3(PO4)2-type phosphor with enhanced quantum efficiency via self-charge compensation for healthy and warm solid state lighting application55Effect of Sm3+ doping on optical properties of Mg2P2O7 and Mg3P2O8 phosphors70Tunable Photoluminescence and Energy Transfer Efficiency in β-Ca3(PO4)2-Ca9La(PO4)7:Eu2+, Mn2+ Solid Solution Phosphors Introduced by Emptying Site and Structural Confinement Effect for Solid-State Lighting Application47Strategies for Designing Antithermal‐Quenching Red Phosphors216Novel efficient deep-red-emitting Ca2LuTaO6:Mn4+ double-perovskite phosphors for plant growth LEDs57Yellow/Orange-Emitting ABZn 2 Ga 2 O 7 :Bi 3+ (A = Ca, Sr; B = Ba, Sr) Phosphors: Optical Temperature Sensing and White Light-Emitting Diode Applications256Recent processes on light-emitting lead-free metal halide perovskites99Interstitial Site Engineering for Creating Unusual Red Emission in La3Si6N11:Ce3+57Comparative study of Al2O3-YAG:Ce composite ceramic and single crystal YAG:Ce phosphors for high-power laser lighting56Enhanced Upconversion Luminescence-Guided Synergistic Antitumor Therapy Based on Photodynamic Therapy and Immune Checkpoint Blockade70A facile in situ surface-coating passivation strategy for improving the moisture resistance of Mn4+-activated fluoride red phosphor49Design of a CaAlSiN3:Eu/glass composite film: Facile synthesis, high saturation-threshold and application in high-power laser lighting53Facile low-temperature solid-state synthesis of efficient blue-emitting Cs3Cu2I5 powder phosphors for solid-state lighting105Inkjet-Printed Quantum Dot Color Conversion Films for High-Resolution and Full-Color Micro Light-Emitting Diode Displays141Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor115Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Industry-friendly synthesis and high saturation threshold of a LuAG:Ce/glass composite film realizing high-brightness laser lighting58A novel narrow-band blue-emitting phosphor of Bi3+-activated Sr3Lu2Ge3O12 based on a highly symmetrical crystal structure used for WLEDs and FEDs183Narrow-band emitters in LED backlights for liquid-crystal displays217Ternary solid solution phosphors Ca1--Li Al1--Si1++N3-O :Ce3+ with enhanced thermal stability for high-power laser lighting67Abnormal Bi3+-Activated NIR Emission in Highly Symmetric XAl12O19 (X = Ba, Sr, Ca) by Selective Sites Occupation106Ultra-high color rendering warm-white light-emitting diodes based on an efficient green-emitting garnet phosphor for solid-state lighting276Enhanced Cyan Emission and Optical Tuning of Ca 3 Ga 4 O 9 :Bi 3+ for High‐Quality Full‐Spectrum White Light‐Emitting Diodes139A promising blue-emitting phosphor CaYGaO 4 :Bi 3+ for near-ultraviolet (NUV) pumped white LED application and the emission improvement by Li + ions89Anti‐Thermal‐Quenching Bi 3+ Luminescence in a Cyan‐Emitting Ba 2 ZnGe 2 O 7 :Bi Phosphor Based on Zinc Vacancy162Single‐Crystal Red Phosphors and Their Core–Shell Structure for Improved Water‐Resistance for Laser Diodes Applications87Effect of M3+ (M = Bi, Al) co-doping on the luminescence enhancement of Ca2ZnSi2O7:Sm3+ orange-red−emitting phosphors64Design of a Bismuth-Activated Narrow-Band Cyan Phosphor for Use in White Light Emitting Diodes and Field Emission Displays100CaAlSiN 3 :Eu 2+ /Lu 3 Al 5 O 12 :Ce 3+ phosphor-in-glass film with high luminous efficiency and CRI for laser diode lighting84Recent progress of zero-dimensional luminescent metal halides873Structure and photoluminescence of Eu 3+ doped Sr 2 InTaO 6 red phosphor with high color purity90Thermal stability of nitride phosphors for light-emitting diodes66Designed glass frames full color in white light-emitting diodes and laser diodes lighting79High Efficiency Green‐Emitting LuAG:Ce Ceramic Phosphors for Laser Diode Lighting90CaAlSiN3:Eu/glass composite film in reflective configuration: A thermally robust and efficient red-emitting color converter with high saturation threshold for high-power high color rendering laser lighting50Unveiling Mn4+ substitution in oxyfluoride phosphor Rb2MoO2F4:Mn4+ applied to wide-gamut fast-response backlight displays94Superior thermally-stable narrow-band green emitter from Mn2+-doped zero thermal expansion (ZTE) material78Unraveling the Luminescence Quenching of Phosphors under High-Power-Density Excitation92Large-scale room-temperature synthesis of high-efficiency lead-free perovskite derivative (NH4)2SnCl6:Te phosphor for warm wLEDs66Recent prospects on phosphor-converted LEDs for lighting, displays, phototherapy, and indoor farming164Efficient Dual-Band White-Light Emission with High Color Rendering from Zero-Dimensional Organic Copper Iodide131Utilizing energy transfer strategy to produce efficient green luminescence in Ca2LuHf2Al3O12:Ce3+,Tb3+ garnet phosphors for high-quality near-UV-pumped warm-white LEDs52Near‐Unity and Zero‐Thermal‐Quenching Far‐Red‐Emitting Composite Ceramics via Pressureless Glass Crystallization70Composition and structure design of three-layered composite phosphors for high color rendering chip-on-board light-emitting diode devices82Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Highly efficient and zero-thermal-quenching blue-emitting Eu2+-activated K-beta-alumina phosphors72Highly Efficient Green‐Emitting Phosphor BaZnAl 10 O 17 :Mn 2+ with Ultra‐Narrow Band and Extremely Low Thermal Quenching for Wide Color Gamut LCD Backlights59Novel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+ (R = Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting51Narrow Bandwidth Luminescence in Sr2Li(Al,Ga)O4:Eu2+ by Selective Site Occupancy Engineering for High Definition Displays52Emitting area limitation via scattering control in phosphor film realizing high-luminance laser lighting53Preparation and luminescence characterization of Eu(III)-activated Forsterite for optoelectronic applications56Structure and luminescence investigation of Gd3+-sensitized perovskite CaLa4Ti4O15:Eu3+: A novel red-emitting phosphor for high-performance white light-emitting diodes and plants lighting72Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68Oligo-β-diketones as versatile ligands for use in metallo-supramolecular chemistry: Recent progress and perspectives51An efficient blue phosphor with high thermal stability for lighting and optical pressure sensor applications69Energy-saving chromium-activated garnet-structured phosphor-converted near-infrared light-emitting diodes73How to Obtain Anti‐Thermal‐Quenching Inorganic Luminescent Materials for Light‐Emitting Diode Applications252Pure White Emission with 91.9% Photoluminescence Quantum Yield of [(C3H7)4N]2Cu2I4 out of Polaronic States and Ultra-High Color Rendering Index112Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50White light emission from AIE‐active luminescent organic materials65Metal To Metal Charge Transfer Induced Efficient Yellow/Far‐Red Luminescence in Na2Ca3(Nb, Ta)2O9:Bi3+ toward the Applications of White‐LEDs and Plant Growth Light48Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index69Efficient near-infrared phosphors discovered by parametrizing the Eu(II) 5d-to-4f energy gap92Molecular imaging nanoprobes for theranostic applications95Challenges and Strategies to Design Phosphors for Future White Light Emitting Diodes104Evolutionary Generation of Phosphor Materials and Their Progress in Future Applications for Light-Emitting Diodes563Superhigh-Luminance Ce:YAG Phosphor in Glass and Phosphor-in-Glass Film for Laser Lighting103Solar spectral management for natural photosynthesis: from photonics designs to potential applications53Lanthanide-doped luminescent perovskites: A review of synthesis, properties, and applications52Powder synthesis and luminescence of a novel yellow-emitting Ba5Si11Al7N25: Eu2+ phosphor discovered by a single-particle-diagnosis approach for warm w-LEDs50A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs69Variable halide perovskites: diversification of anti-counterfeiting applications49Preparation, characterization, and application of a red phosphor Ca2InTaO6:Eu3+ in w-LEDs and latent fingerprint detection56Regulating Eu 2+ Multisite Occupation through Structural Disorder toward Broadband Near-Infrared Emission91Facile Synthesis of Highly Efficient and Thermally Stable BaAl 4 Sb 2 O 12 :Eu 2+ Phosphor in Air72Efficient red-emitting SrZrO3:Eu3+ phosphor superstructures for display device applications51Broadband Emission Origin in Metal Halide Perovskites: Are Self‐Trapped Excitons or Ions?198Cr3+-Doped NIR Phosphor with Well-Defined Stokes/Anti-Stokes Phonon Sidebands for a Ratiometric Thermometer and Thermally Stable NIR LEDs53Intriguing Room Temperature Phosphorescence in Crystalline Porous Organic Frameworks84Enhanced Thermal Stability of Red‐Emitting Sr2Si5N8:Eu2+ Phosphors from Triggered Applicable Trap Level via Rare Earth Ions Co‐Doping59Patterned phosphor-in-glass films with efficient thermal management for high-power laser projection displays80A brief review of characteristic luminescence properties of Eu 3+ in mixed-anion compounds53An efficient and thermally stable red emitting Eu2+ doped oxide for rechargeable portable flashlight62A Robust Anti-Thermal-Quenching Phosphor Based on Zero-Dimensional Metal Halide Rb3InCl6:xSb3+80Full-color, time-valve controllable and Janus-type long-persistent luminescence from all-inorganic halide perovskites107Looking into the future of hybrid glasses58Color-conversion displays: current status and future outlook102Interactions between H2O and lead halide perovskites: Recent progress and applications54Rare‐Metal‐Free Ultrabroadband Near‐Infrared Phosphors72

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