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RESEARCH PAPER · Chemistry of Materials · 2021

Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications

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Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and ApplicationsOriginalEfficient Broadband Near‐Infrared Emission in the GaTaO4:Cr3+ Phosphor191Accessing High-Power Near-Infrared Spectroscopy Using Cr3+-Substituted Metal Phosphate Phosphors114A new broadband near-infrared emitting Mg 2 Al 4 Si 5 O 18 :Cr 3+ phosphor for night-vision imaging29Achievement of high efficiency and thermally stable near-infrared phosphors by designing a chromium crystallographic environment for nondestructive testing and night vision15Deep-red to near-infrared luminescence from Eu 2+ -trapped exciton states in YSiO 2 N9Efficient broadband near-infrared emission induced by Nb 5+ substitution for Ta 5+ in GaTa 1− y Nb y O 4 :Cr 3+ phosphor50Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※8Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Surface modified lanthanide upconversion nanoparticles for drug delivery, cellular uptake mechanism, and current challenges in NIR-driven therapies131Dopant and Compositional Modulation Triggered Broadband and Tunable Near-Infrared Emission in Cs2Ag1–xNaxInCl6:Cr3+ Nanocrystals131NIR emission spectral engineering in NaSc(Si,Ge)2O6: Cr3+ solid-solution phosphors via crystal field regulation24Efficient and broadband near-infrared emission of Cr3+-doped glass-ceramics for near-infrared light sources applications26The blue-green emission color of Ag+, Gd3+ co-activated CdWO4 phosphor via energy transfer for luminescence applications7Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Multiple Strategies to Approach High-Efficiency Luminescence Controllable in Blue/Cyan/Green-Emitting Bi 3+ -Activated Phosphors30Evolutionary Generation of Phosphor Materials and Their Progress in Future Applications for Light-Emitting Diodes563Modulation of Thermally Stable Photoluminescence in Cr 3+ -Based Near-Infrared Phosphors201Blue LED‐Pumped Broadband Short‐Wave Infrared Emitter Based on LiMgPO4:Cr3+,Ni2+ Phosphor97Charge Transfer-Triggered Bi 3+ Near-Infrared Emission in Y 2 Ti 2 O 7 for Dual-Mode Temperature Sensing53Expanded visible-near-infrared temperature sensing properties in view of ultra-broadband tunable luminescence in Mg3Y2Ge3O12:Ce3+, Cr3+ phosphors with advanced applications18Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Deep investigation of phonon induced photoluminescence evolution of YAG:Cr transparent ceramics at a wide temperature range1Environmentally-friendly and low-cost Fe3+-doped broadband NIR light-emitting phosphors54A High-efficiency blue-LED-excitable NIR-II-emitting MgO:Cr3+,Ni2+ phosphor for future broadband light source toward multifunctional NIR spectroscopy applications178Highly distorted Cr3+-doped fluoroantimonate with high absorption efficiency for multifunctional near-infrared spectroscopy applications31Tuning emission color of Eu2+-activated phosphor through phase segregation22Photoluminescent Janus oxazolidine nanoparticles for development of organic light-emitting diodes, anticounterfeiting, information encryption, and optical detection of scratch31Recent Developments of Microscopic Study for Lanthanide and Manganese Doped Luminescent Materials8A novel efficient broadband near-infrared phosphor LiGaGe 2 O 6 :Cr 3+ with EQE enhancement and spectral tuning by Sc 3+ –Ga 3+ substitution for NIR pc-LED application43Site-Selective Occupancy Control of Cr Ions toward Ultrabroad-Band Infrared Luminescence with a Spectral Width up to 419 nm79Site-selective occupation of Cr3+ ions toward ultra-broadband near-infrared emission stannate phosphors23Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Highly efficient and thermally stable broadband NIR phosphors by rationally bridging Cr 3+ –Yb 3+ in LiScGe 2 O 6 for optical bioimaging69Thermally stable and tunable broadband near-infrared emission from NIR-I to NIR-II in Bi-doped germanate glass for smart light sources19An efficient and thermally stable Cr 3+ -activated Y 2 GdSc 2 Al 2 GaO 12 garnet phosphor for NIR spectroscopy applications14Ceramics phosphor powders4Electrochemical and fluorescence sensing performance of four new coordination polymers tuned by different metal ions and dicarboxylic acids13High-power NIR-II LED of Nd 3+ doped glass ceramics towards portable imaging9Machine learning and density functional theory simulation of the electronic structural properties for novel quaternary semiconductors14Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe 3+69Recent Progress in Inorganic Afterglow Materials: Mechanisms, Persistent Luminescent Properties, Modulating Methods, and Bioimaging Applications143Wide‐coverage and Efficient NIR Emission from Single‐component Nanophosphors through Shaping Multiple Metal‐halide Packages63Wide‐coverage and Efficient NIR Emission from Single‐component Nanophosphors through Shaping Multiple Metal‐halide Packages9Tunable-wavelength photoluminescence of a flexible transition metal doped oxide phosphor thin film2Ultra-narrow-band luminescence with spectral width down to 32 nm in bismuth-activated phosphate phosphors with superior thermal stability11AHSS—Construction Material Used in Smart Cities6Stable Polyhedron-Cluster-Based Rigid Fluoride Framework toward Zero-Thermal-Quenching Near-Infrared Emission for Prolonged LED Applications25Dual-targeting lanthanide-ICG-MOF nanoplatform for cancer Theranostics: NIR II luminescence imaging guided sentinel lymph nodes surgical navigation20Multimode Dynamic Photoluminescence of Bi3+-Activated ZnGa2O4 for Optical Information Encryption31In situ synthesis of polychromic up/down-conversion carbon dots/YF3 composites for information encryption and security8First-Principles Analysis of the Effects of Covalency and Ionicity on the 4f–5d Transition Energy of Ce3+ in Garnet-Type Oxides5Synthesis of solid-state multicolor fluorescent calcium carbonate by controlled defect degree of (110)/(104) crystal plane and atomic order1Efficient Ultra‐Broadband Phosphors for High-Power Near-infrared LED and night vision imaging system sources15Advancing Reporting Guidelines for Optimal Characterization of Inorganic Phosphors9Dopants concentration on the properties of various host materials by sol-gel method: Critical review15Structural and luminescence studies of Eu3+ doped K2BaSr(PO4)2 phosphor0Crystallization of Na2SrGe6O14:Cr3+,Yb3+ Glass Ceramics Enabling a Watt‐Level Output Power NIR‐I/NIR‐II Lighting Source56Efficient and ultra-broadband near-infrared emission in perovskite-like Mg4Sb2O9:Cr3+ phosphor5Near‐Infrared Emission of Sm2+ in Oxynitrides14Broadband emitting Fe 3+ ‐doped double perovskite‐type antimonates phosphors for NIR spectroscopy applications28Enhancing the inherent NIR photoluminescence in SrLaLiTeO 6 through Cr 3+ –Yb 3+ co-substitution for high performance pc-LEDs33Chromium Cluster Luminescence: Advancing Near‐Infrared Light‐Emitting Diode Design for Next‐Generation Broadband Compact Light Sources64Multifunctional applications of novel near-infrared emitting Ca2ScNbO6:Cr3+ double-perovskite phosphors35An efficient and thermally stable source with Cr3+ near-infrared luminescence for non-destructive testing applications26Broadband short-wave infrared Mg 4 Nb 2 O 9 :Cr 3+ ,Li + phosphor for nondestructive safety detection and biomedical imaging17Co-doped NaYF 4 :Yb/Er/Tm upconversion luminescent coating to enhance the efficiency of photovoltaic cells9Energy transfer-induced blue light-excited broadband near-infrared luminescence in fluoride Na 3 AlF 6 :Mn 4+ ,Fe 3+4Governing efficiency and thermoresponsivity of luminescence in dirhenium( v ) molecules by a highly tunable emission mechanism6Realizing efficient broadband near-infrared emission and multimode photoluminescence switching via coordination structure modulation in Sb 3+ -doped 0D organic metal chlorides50Site-selective occupancy of Cr 3+ enabling tunable emission from near infrared I to II in fluoride LiInF 4 :Cr 3+18Strategies to fabricate full spectrum responsive photocatalysts0Thermally stable NIR broad emission of Cr 3+ doping phosphor with a high output power14Phase transition and Nd3+/Pr3+ co-doping induced enhancement of NIR emission in ScP3O9: Cr3+ phosphor15Broadband Near-Infrared Luminescence from Mo4+ in Zero-Dimensional Perovskite Cs2Zr(Cl,Br)6 with an Exceptionally High Quantum Efficiency and Thermal Stability49Nanoconfined Synthesis of Lead Sulfide Quantum Dots Embedded in Mesoporous Aluminosilicate Glass with Adjustable Near-Infrared Broadband Luminescence9Thermally Stable NIR Emission from Disordered Ba5La3MgAl3O15:Cr3+ with Peak Wavelength Beyond 900 nm36Emerging Fe 3+ Doped Broad NIR‐Emitting Phosphor Ca 2.5 Hf 2.5 (Ga, Al) 3 O 12 : Fe 3+ for LWUV Pumped NIR LED134A Novel Near‐Infrared Emitting Sr 2 LuSbO 6 :Fe 3+ Phosphor with Persistent Luminescence Performance76Fabrication strategies for chiral self-assembly surface10Broadband near infrared emission in Cr3+,Yb3+, Li+ tri-doped In2TeO614Mini Light‐Emitting Diode Technology with High Quantum Efficient NIR‐II Partially Inverse Spinel MgGa2O4:Cr3+,Ni2+ Nanophosphors28Near‐infrared emitting metal halide materials: Luminescence design and applications78Advances in Fe3+-activated luminescent materials for near-infrared light sources64Simultaneously strong NIR-II and NIR-III luminescence induced by Cr3+-Yb3+-Er3+ energy transfer in KScP2O7 for NIR thermometry, NIR pc-LED and night-vision applications14Molecular Origins of Near-Infrared Luminescence in Molybdenum and Tungsten Oxyhalide Perovskites12A High-Efficiency NIR-II Emitting LiAlSiO4:Cr/Ni Phosphors through Violet Excitation for NIR pc-LED Application12Broadband Near-Infrared Emission from Bi/Cr Co-Doped Aluminosilicate Glasses2Uncovering the presence or absence of photoluminescence from iron ions in crystals10Near-infrared luminescence shift in Ni2+-doped double perovskite phosphors14Solvothermal phase selection of Cr3+-doped (NH4) ScF(3+) compounds (x = 0, 1, 3), structure, and NIR luminescence0Cr3+-Doped LiAlO2 NIR-I Emitting Phosphors with Superior Resistance to Thermal Quenching for Night Vision Monitoring and Bioimaging47Enhanced thermal stability of broadband NIR phosphors Ca3.3Mg0.7ZrGe3O12:Cr3+ for pc-LEDs8Structure–luminescence property relationships of Yb3+-Doped Y2Mg3-xCax(SiO4)3 single crystals for 0.95–1.2 μm broadband emissions6Antithermal-Quenching Near-Infrared Emitting Lu2SrAl4SiO12:Cr3+ Garnet-Type Phosphor for High-Resolution Nonvisual Imaging38Recent progress on bismuth-based materials for full-spectrum-driven photocatalysis14Broadband Near-Infrared Emission of Sm2+ in Highly Stable (Ba,Sr)Al3Si3O4N5 for Encryption and Nondestructive Inspection11Blue light excitable efficient down-conversion photoluminescence of Yb3+ and Er3+ in ultra-wide NIR region via Cr3+-Yb3+-Er3+ energy transfer in KAlP2O7 and multifunctional applications11A high-efficiency blue-LED-excitable broadband Cr 3+ /Ni 2+ co-doped garnet phosphor toward next-generation spectroscopy applications19Synthesis of a novel broadband near-infrared fluoride phosphor with nearly 100% internal quantum efficiency using a cationic substitution strategy13A novel AlF 3 :Cr 3+ NIR phosphor with high thermal quenching stability for advanced pc-LEDs8Application of photoluminescent materials in cultural relics protection0Cr 3+ –Cr 3+ pairing and multi-site engineering in Sr 2 ZnAl 22 O 36 phosphors for broadband near-infrared emissions14Efficient short-wave NIR emission induced by energy transfer from Cr 3+ clusters to Ni 2+ in LiAl 5 O 8 :Cr 3+ ,Ni 2+ phosphor-in-glass for spectroscopy applications11Highly luminescent sodium zinc molybdate: Yb3+/Er3+ upconversion nanoparticles and their temperature sensor and bio-imaging applications14Strategies for broadening the emission spectra of Cr 3+ -doped near-infrared emitting phosphors59Improving the near-infrared luminescence of Ca3MgSnGe3O12:Cr3+ using cation modulation and energy transfer for night-vision and nondestructive testing1Efficient Emission of Lanthanide Ion in Double Perovskite Nanocrystals Enabled by Synergistic Effect of Energy Level Modulation and Crystal‐Field Engineering17Smart Luminescent Materials for Emerging Sensors: Fundamentals and Advances54Tunable emission from solid-solution phosphors Ba3(Sb,Ta)Ga3Si2O14:Bi3+,Eu3+ for diverse optical applications9Near-infrared luminescence and temperature sensing properties of Sc2Mo3O12:Nd3+/Yb3+/Ho3+ phosphor13Highly Efficient and Thermally Stable NIR‐Emitting Phosphor with Largely Tunable Peak Wavelength and Bandwidth Toward NIR Spectroscopy Applications47Controllable morphology and enhanced luminescence in hydrothermally Cr3+-Doped Na3GaF6 phosphors for NIR imaging7Synergistic Therapeutic Effects of Prussian Blue Erbium-Doped Hydroxyapatite Nanoparticles in Photothermal Photodynamic Cancer Therapy13A Nontoxic and Environmentally Friendly NIR‐II Phosphor for Night Vision, Bio‐Imaging, Large‐Scale Detection, and Information Anti‐Counterfeiting with High‐Resolution Imaging29Broadband NIR phosphor with high external quantum yield and application of smoke penetration imaging3Broadband near-infrared long persistent luminescence in Cr3+-Doped CaY2Ga4GeO12 phosphors for advanced light source applications4Ultra-broadband near infrared phosphor with wide spectral range and long peak wavelength achieved by double-site occupation1Near-Infrared Luminescence of Cr3+-Doped Ba2NaNb5O15 Embedded in Transparent Glass-Ceramics as Solid-State Illumination for Night-Vision Imaging18A highly efficient NIR-II-emitting MgGa2O4:Cr3+,Ni2+ phosphor via the Cr3+ ions in tetrahedral sites as the Cr3+-Ni2+ energy transfer bridge10Highly efficient Fe3+-activated hexaaluminate phosphor with multisite luminescence and high thermal stability toward plant lighting8Unlocking Advanced Near‐Infrared Luminescence Activated by Iron Ions for Versatile Applications toward a Treasure Trove of Garnet‐type Structures14Development of Eu 2+ ‐Doped UCr 4 C 4 ‐Type Phosphors Toward Advanced Display Applications22Near-infrared photoluminescence and scintillation properties of Ni2+−doped MgO ceramics3Broadband Near‐Infrared Emitting Lead‐Free Perovskites with High Internal Quantum Efficiency and Small Stokes Shift for Versatile Spectroscopy Applications13Cr3+-doped LiAl5O8 nanocrystals embedded in transparent glass-ceramic with high NIR PLQY and excellent thermal stability7Machine Learning for Organic Fluorescent Materials25KGaGeO4: Cr3+: a novel NIR phosphor with afterglow properties and good thermal stability5Lanthanide cerium(III) complex with deep-red emission beyond 700 nm13Stable near-infrared luminescence from KMgF3:Cr3+ fluoroperovskite phosphor for light-emitting diodes2Density functional theory facilitates heterovalent substitution: The multi-functional application of near-infrared emitting phosphors with excellent thermal stability0Synthesis and spectroscopic analysis of NIR-emitting Na 2 YMg 2 (VO 4 ) 3 :Nd 3+ ,Yb 3+ phosphors for optoelectronic applications3Recent Advances and Emerging Applications of Lanthanide/Transition‐Metal‐Ion‐Doped Short‐Wave Infrared Luminescent Materials10Machine-Learning-Assisted Discovery of Cr3+-Based Near-Infrared Phosphors16High‐Performance Near‐Infrared Ba 3 MgSb 2 O 9 :Fe 3+ , Sn 4+ Phosphors with Elucidated Multifaceted Thermal Quenching Mechanisms14Improved NIR luminescence in Y3-Sc Ga3MgSiO12:Cr3+ phosphor via cation substitution for multifunctional spectroscopic applications4High efficiency near-infrared emission from Fe3+-doped NaAl11O17 phosphors for plant lighting8Preparation and Study of Bright Orange-Yellow Long Persistent Luminescent Ca2LuScGa2Ge2O12:Pr3+ Phosphor0Multi-functional NIR phosphors based on peak position and bandwidth modulation via Cr3+-Cr3+ ion pairs5Efficient and thermal stable broadband near-infrared emitting Gd2CaAl3GaZrO12:Cr3+ garnet phosphor: structure, luminescence, and pc-LED application9Cr3+ sensitized thermal enhanced near-infrared emission in negative thermal expansion Sc2Mo3O12:Cr/Yb/Er phosphor1Fe 3+ ‐Activated Near‐Infrared Mechanoluminescence in Double Perovskite Compound6Color tuning in lanthanide ions doped upconversion nanocrystals2F − substitution-induced high-efficiency broadband near-infrared MgAl 2 O 4 :Fe 3+ phosphors for night-vision and biomedical imaging4Investigation of structure–luminescence relationship in Nd3+-doped Y2(Mg,Ca)3(SiO4)3 single crystals for 1.0-1.15 μm broadband emissions0Using NIR-emitting MgO:Li,Ce,Sm microparticles in the preparation of biophotonic glass – a promising approach to enable optical NIR imaging0Broadband NIR-I/II emitting phosphor Cr3+-Ni2+ Co-doped Mg3Y2Ge3O12 for deep-tissue imaging & night vision2Enhanced broadband near-infrared emission based on cation substitution in Cr3+ ion doped YGdScSbO7 phosphor0Neighboring Cation Co‐Substitution Engineering Strategy for Synergistic Energy Transfer for Efficient Broadband Near‐Infrared Luminescence in Lu 3‐x Ca x Al 5‐x Si x O 12 :Ce 3+ , Cr 3+2Sensitizing effect of lanthanide luminescence by Mo4+/Ag+ in double perovskites: great enhancement of near-infrared emission via wide range of excitation (250–850 nm)12Intraligand Charge Transfer in Zn(II) Complexes for Singlet Oxygen Photocatalysis: A Sustainable Alternative to Precious Metal Systems4

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