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RESEARCH PAPER · Chemical Science · 2018

Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction

Nicolas P. Martin, Christophe Volkringer, Natacha Henry, Xavier Trivelli, Grégory Stoclet, Atsushi Ikeda‐Ohno, Thierry Loiseau

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Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reactionOriginal{Np 38 } clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides40Bottom-up synthesis of functionalized {Ce 4 (SiW 9 O 34 ) 2 ( l ) 2 } polyoxometalates6Etude de la précipitation quantitative de l’uranium(VI) et du plutonium(IV) en milieu acide nitrique par de nouveaux ligands organiques0Uranyl Cation Incorporation in the [P8W48O184]40– Macrocycle Phosphopolytungstate23Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl439Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl46Extension of the Plutonium Oxide Nanocluster Family to Include {Pu16} and {Pu22}43Crystal Chemistry and SAXS Studies of an Octahedral Polyoxoarsenotungstate Nanocluster Encapsulating Four Unprecedented Thorium Arsenate Fragments ({Th3As2On} – n = 25 or 26)10Synthèses, caractérisations et cristallochimie de polyoxométallates incorporant des actinides et des lanthanides comme simulants d’actinides0Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34Influence of pH on Ce IV -[As III W 9 O 33 ] 9− association for the formation of hexanuclear cerium( iv ) oxo-hydroxo-clusters stabilized by trivacant polyanions10Polyoxometalate-based complexes as ligands for the study of actinide chemistry34Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation23Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes15Supramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations51Cu(II)-Hydrazide Coordination Compound Supported on Silica Gel as an Efficient and Recyclable Heterogeneous Catalyst for Green Click Synthesis of β-Hydroxy-1,2,3-triazoles in Water45Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV11Metal–Organic Frameworks Based on Group 3 and 4 Metals140Bridging the Transuranics with Uranium(IV) Sulfate Aqueous Species and Solid Phases13Insight into the structure–property relationship of UO 2 nanoparticles29Snapshots of Ce 70 Toroid Assembly from Solids and Solution39Structure of the {U13} polyoxo cluster U13O8Cl x (MeO)38–x (x = 2.3, MeO = methoxide)3High energy resolution X-ray spectroscopy of f-electron systems0Size and structure of hexanuclear plutonium oxo-hydroxo clusters in aqueous solution from synchrotron analysis11Reactivity of a Chloride Decorated, Mixed Valent Ce III/IV 38 –Oxo Cluster16First observation of [Pu 6 (OH) 4 O 4 ] 12+ cluster during the hydrolytic formation of PuO 2 nanoparticles using H/D kinetic isotope effect13Recent advances in uranium-containing polyoxometalates59Unveiling the new function of uranyl molecular clusters as fluorometric sensors for UV and X-ray dosimetry8A New Concept of Radiation Detection Based on a Fluorochromic and Piezochromic Nanocluster70Metal–Oxo Cluster Formation Using Ammonium and Sulfate to Differentiate M IV (Th, U, Ce) Chemistries16Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands8Platonic and Archimedean solids in discrete metal-containing clusters138Ferrocene‐Based Actinide Clusters: Synthesis, Crystal Structures, and Characterization3Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications11A New Molybdenum Blue Structure Type: How Uranium Expands this Family of Polyoxometalates6Globular pattern formation of hierarchical ceria nanoarchitectures4Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers8Uranyl Clusters Based on 1,10-Phenanthroline Derivative Ligands: Synthesis, Crystal Structures, and Iodine Capture1Pertechnetate/Perrhenate-Linked Frameworks of UIV, UIV6-Hexamer and Uranyl (VI) Building Units3A Photoluminescent Uranyl Complex for Dual-Platform X-ray Dose Detection3SGMCC : A New Software for Searching the Global‐Minimum Structure of Coordinated Complex7Ultrasound-assisted synthesis of inorganic tin chemical products: Insights and advances1Coordination Chemistry of Thorium Supported by a Single Polyoxoalkoxide Ligand0

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  1. {Np 38 } clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

    Chemical Communications · 2018-01-01

    Nicolas P. Martin, Christophe Volkringer, Pascal Roussel, Juliane März, Christoph Hennig, Thierry Loiseau, Atsushi Ikeda‐Ohno

    Read original paper ↗ ·

  2. Bottom-up synthesis of functionalized {Ce 4 (SiW 9 O 34 ) 2 ( l ) 2 } polyoxometalates

    CrystEngComm · 2018-01-01

    Maxime Dufaye, Sylvain Duval, Kelvinraj Nursiah, Grégory Stoclet, Xavier Trivelli, Thierry Loiseau

    Read original paper ↗ ·

  3. Etude de la précipitation quantitative de l’uranium(VI) et du plutonium(IV) en milieu acide nitrique par de nouveaux ligands organiques

    Unknown journal · 2018-11-16

    Gaël Loubert

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  4. Uranyl Cation Incorporation in the [P8W48O184]40– Macrocycle Phosphopolytungstate

    Inorganic Chemistry · 2018-12-28

    Maxime Dufaye, Sylvain Duval, Grégory Stoclet, Xavier Trivelli, Marielle Huvé, Alain Moissette, Thierry Loiseau

    Read original paper ↗ ·

  5. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )

    RSC Advances · 2019-01-01

    Maxime Dufaye, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda‐Ohno, Thierry Loiseau

    Read original paper ↗ ·

  6. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

    Angewandte Chemie International Edition · 2019-01-02

    Lucile Chatelain, Radmila Faizova, Farzaneh Fadaei‐Tirani, Jacques Pécaut, Marinella Mazzanti

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  7. Structural Snapshots of Cluster Growth from {U6} to {U38} During the Hydrolysis of UCl4

    Angewandte Chemie · 2019-01-02

    Lucile Chatelain, Radmila Faizova, Farzaneh Fadaei‐Tirani, Jacques Pécaut, Marinella Mazzanti

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  8. Extension of the Plutonium Oxide Nanocluster Family to Include {Pu16} and {Pu22}

    Chemistry - A European Journal · 2019-01-03

    Ginger E. Sigmon, Amy E. Hixon

    Read original paper ↗ ·

  9. Crystal Chemistry and SAXS Studies of an Octahedral Polyoxoarsenotungstate Nanocluster Encapsulating Four Unprecedented Thorium Arsenate Fragments ({Th3As2On} – n = 25 or 26)

    European Journal of Inorganic Chemistry · 2019-08-28

    Maxime Dufaye, Sylvain Duval, Grégory Stoclet, Thierry Loiseau

    Read original paper ↗ ·

  10. Synthèses, caractérisations et cristallochimie de polyoxométallates incorporant des actinides et des lanthanides comme simulants d’actinides

    Unknown journal · 2019-10-03

    Maxime Dufaye

    Read original paper ↗ ·

  11. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

    Inorganic Chemistry Frontiers · 2019-10-29

    Zi‐Jian Li, Shangyao Guo, Huangjie Lu, Yongjia Xu, Zenghui Yue, Linhong Weng, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

    Read original paper ↗ ·

  12. Influence of pH on Ce IV -[As III W 9 O 33 ] 9− association for the formation of hexanuclear cerium( iv ) oxo-hydroxo-clusters stabilized by trivacant polyanions

    CrystEngComm · 2019-11-28

    Maxime Dufaye, Sylvain Duval, Grégory Stoclet, Thierry Loiseau

    Read original paper ↗ ·

  13. Polyoxometalate-based complexes as ligands for the study of actinide chemistry

    Dalton Transactions · 2020-01-01

    Thomas Auvray, Ellen M. Matson

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  14. Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation

    Chemistry - A European Journal · 2020-01-30

    Nicole A. Vanagas, Robert F. Higgins, Jennifer N. Wacker, Dane Romar C. Asuigui, Evan Warzecha, Stosh A. Kozimor, Sarah L. Stoll, Eric J. Schelter, Jeffery A. Bertke, Karah E. Knope

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  15. Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

    Inorganic Chemistry · 2020-02-04

    Zenghui Yue, Xiaofeng Guo, Mei‐Ling Feng, Yue‐Jian Lin, Yu Ju, Xiao Lin, Zhi‐Hui Zhang, Xiao-Jing Guo, Jian Hung Lin, Yuying Huang, Jian‐Qiang Wang

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  16. Supramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations

    Journal of the American Chemical Society · 2020-04-22

    Ian Colliard, Gregory W. Morrison, Hans‐Conrad zur Loye, May Nyman

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  17. Cu(II)-Hydrazide Coordination Compound Supported on Silica Gel as an Efficient and Recyclable Heterogeneous Catalyst for Green Click Synthesis of β-Hydroxy-1,2,3-triazoles in Water

    ACS Omega · 2020-05-26

    Marzieh Emami, Rahman Bikas, Nader Noshiranzadeh, Anna Kozakiewicz, Tadeusz Lis

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  18. Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV

    Chemistry - A European Journal · 2020-07-01

    Ian Colliard, May Nyman

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  19. Metal–Organic Frameworks Based on Group 3 and 4 Metals

    Advanced Materials · 2020-09-09

    Liang Feng, Jiandong Pang, Ping She, Jia‐Luo Li, Jun‐Sheng Qin, Dong‐Ying Du, Hong-Cai “Joe” Zhou

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  20. Bridging the Transuranics with Uranium(IV) Sulfate Aqueous Species and Solid Phases

    Inorganic Chemistry · 2020-11-19

    Ian Colliard, Clément Falaise, May Nyman

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  21. Insight into the structure–property relationship of UO 2 nanoparticles

    Inorganic Chemistry Frontiers · 2020-12-15

    Evgeny Gerber, Anna Yu. Romanchuk, Stephan Weiß, Stephen Bauters, Bianca Schacherl, Tonya Vitova, René Hübner, Salim Shams Aldin Azzam, Dirk Detollenaere, Dipanjan Banerjee, Sergei M. Butorin, Stepan Nikolaevich Kalmykov, Kristina O. Kvashnina

    Read original paper ↗ ·

  22. Snapshots of Ce 70 Toroid Assembly from Solids and Solution

    Journal of the American Chemical Society · 2021-06-17

    Ian Colliard, Jessica C. Brown, Dylan B. Fast, A. Kirstin Sockwell, Amy E. Hixon, May Nyman

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  23. Structure of the {U13} polyoxo cluster U13O8Cl x (MeO)38–x (x = 2.3, MeO = methoxide)

    Acta Crystallographica Section E Crystallographic Communications · 2021-07-30

    Sebastian Fichter, Thomas Radoske, Atsushi Ikeda‐Ohno

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  24. High energy resolution X-ray spectroscopy of f-electron systems

    Unknown journal · 2021-09-10

    Evgeny Gerber

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  25. Size and structure of hexanuclear plutonium oxo-hydroxo clusters in aqueous solution from synchrotron analysis

    Journal of Synchrotron Radiation · 2021-12-15

    Thomas Dumas, Matthieu Virot, Denis Menut, Christelle Tamain, Cyril Micheau, Sandrine Dourdain, Olivier Diat

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  26. Reactivity of a Chloride Decorated, Mixed Valent Ce III/IV 38 –Oxo Cluster

    Inorganic Chemistry · 2021-12-16

    Jennifer N. Wacker, Alexander S. Ditter, Samantha K. Cary, Aphra V. Murray, Jeffery A. Bertke, Gerald T. Seidler, Stosh A. Kozimor, Karah E. Knope

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  27. First observation of [Pu 6 (OH) 4 O 4 ] 12+ cluster during the hydrolytic formation of PuO 2 nanoparticles using H/D kinetic isotope effect

    Chemical Communications · 2022-01-01

    Manon Cot-Auriol, Matthieu Virot, Thomas Dumas, Olivier Diat, Denis Menut, Philippe Moisy, Sergey I. Nikitenko

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  28. Recent advances in uranium-containing polyoxometalates

    Inorganic Chemistry Frontiers · 2022-01-01

    Guo‐Ping Yang, Ke Li, Changwen Hu

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  29. Unveiling the new function of uranyl molecular clusters as fluorometric sensors for UV and X-ray dosimetry

    Dalton Transactions · 2022-01-01

    Huangjie Lu, Zhaofa Zheng, Jie Qiu, Yuan Qian, Jian‐Qiang Wang, Jian Hung Lin

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  30. A New Concept of Radiation Detection Based on a Fluorochromic and Piezochromic Nanocluster

    Journal of the American Chemical Society · 2022-01-20

    Huangjie Lu, Huiliang Hou, Yu-Chang Hou, Zhaofa Zheng, Yingying Ma, Zhengyang Zhou, Xiaofeng Guo, Qing‐Jiang Pan, Yonggang Wang, Yuan Qian, Jian‐Qiang Wang, Jian Hung Lin

    Read original paper ↗ ·

  31. Metal–Oxo Cluster Formation Using Ammonium and Sulfate to Differentiate M IV (Th, U, Ce) Chemistries

    Inorganic Chemistry · 2022-07-04

    Ian Colliard, Jessica C. Brown, May Nyman

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  32. Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands

    Inorganic Chemistry · 2022-09-01

    Rameswar Bhattacharjee, Pere Miró

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  33. Platonic and Archimedean solids in discrete metal-containing clusters

    Chemical Society Reviews · 2022-12-19

    Xi‐Ming Luo, Ya‐Ke Li, Xi‐Yan Dong, Shuang‐Quan Zang

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  34. Ferrocene‐Based Actinide Clusters: Synthesis, Crystal Structures, and Characterization

    European Journal of Inorganic Chemistry · 2023-03-18

    Jin‐Dong Wang, Kong‐Qiu Hu, Zhi‐wei Huang, Lei Mei, Jipan Yu, Zhifang Chai, Xin‐Peng Wang, Wei‐Qun Shi

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  35. Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

    Chemical Science · 2024-01-01

    Naoki Ogiwara, Wei Zhou, Sayaka Uchida

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  36. A New Molybdenum Blue Structure Type: How Uranium Expands this Family of Polyoxometalates

    Chemistry - A European Journal · 2024-02-27

    Daniel E. Felton, Kyson R. Smith, Nicholas A. Poole, Karl Cronberger, Peter Carman Burns

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  37. Globular pattern formation of hierarchical ceria nanoarchitectures

    Communications Chemistry · 2024-06-12

    Noboru Aoyagi, Ryuhei Motokawa, Masahiko Okumura, Yuki Ueda, Takumi Saito, Shotaro Nishitsuji, Tomitsugu Taguchi, Takumi Yomogida, Gen Sazaki, Atsushi Ikeda‐Ohno

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  38. Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers

    CrystEngComm · 2024-12-13

    Thomas L. McCusker, Nicole A. Vanagas, Jennifer E. S. Szymanowski, Robert G. Surbella, Jeffery A. Bertke, Ana Arteaga, Karah E. Knope

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  39. Uranyl Clusters Based on 1,10-Phenanthroline Derivative Ligands: Synthesis, Crystal Structures, and Iodine Capture

    Inorganic Chemistry · 2025-05-22

    Xiao-Feng Men, Xiang‐he Kong, Zhi‐wei Huang, Xuan Fu, Lei Mei, Na Niu, Kong‐Qiu Hu, Wei‐Qun Shi

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  40. Pertechnetate/Perrhenate-Linked Frameworks of UIV, UIV6-Hexamer and Uranyl (VI) Building Units

    Inorganic Chemistry · 2025-07-15

    Mohammad Shohel, Ian Colliard, May Nyman

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  41. A Photoluminescent Uranyl Complex for Dual-Platform X-ray Dose Detection

    Inorganic Chemistry · 2025-07-24

    Cong Li, Jian Xie, Baowei Hu, Heyao Zhang, Huangjie Lu

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  42. SGMCC : A New Software for Searching the Global‐Minimum Structure of Coordinated Complex

    Journal of Computational Chemistry · 2025-11-02

    Yangyang Zhang

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  43. Ultrasound-assisted synthesis of inorganic tin chemical products: Insights and advances

    Chemical Engineering and Processing - Process Intensification · 2026-03-20

    Qian Zhang, Qian Zhang, Tian Wang, Tao Xu, Hongying Xia, Hongying Xia, Thiquynhxuan Le, Libo Zhang

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  44. Coordination Chemistry of Thorium Supported by a Single Polyoxoalkoxide Ligand

    Inorganic Chemistry · 2026-09-12

    Dominic Shiels, Adriana C Berlfein, William W. Brennessel, Ellen M. Matson

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