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RESEARCH PAPER · Angewandte Chemie · 2018

Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation

Yanlong Wang, Wei Liu, Zhuanling Bai, Tao Zheng, Mark A. Silver, Yuxiang Li, Yaxing Wang, Xia Wang, Juan Diwu, Zhifang Chai, Shuao Wang

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Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and SeparationOriginalHigh Uptake of ReO 4 − and CO 2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th 48 Ni 6 ] Nanocage‐Based Metal–Organic Framework148High Uptake of ReO4− and CO2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th48Ni6] Nanocage‐Based Metal–Organic Framework21Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework44Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton245A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane289A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane33Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving137Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving59Zinc and Cadmium Complexes of Pyridinemethanol Carboxylates: Metal Carboxylate Zwitterions and Metal–Organic Frameworks11From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution118Docking of Cu I and Ag I in Metal–Organic Frameworks for Adsorption and Separation of Xenon195Docking of CuI and AgI in Metal–Organic Frameworks for Adsorption and Separation of Xenon15Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10A Robust Calcium–Organic Framework for Effective Separation of Xenon and Krypton11High‐Silica CHA Zeolite Membrane with Ultra‐High Selectivity and Irradiation Stability for Krypton/Xenon Separation70High‐Silica CHA Zeolite Membrane with Ultra‐High Selectivity and Irradiation Stability for Krypton/Xenon Separation12Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage19An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Unveiling the Unique Roles of Metal Coordination and Modulator in the Polymorphism Control of Metal‐Organic Frameworks20MOFs with 12-Coordinate 5f-Block Metal Centers41Creating Optimal Pockets in a Clathrochelate-Based Metal–Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies168Metal-organic frameworks in separations: A review91Boosting xenon adsorption with record capacity in microporous carbon molecular sieves23Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation98Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers2Metal-organic frameworks for xenon and krypton separation32Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework12Anion‐Shielded Porous Organic Cages for High‐Performance Xenon/Krypton Separation3An Ultrastable Hydrogen‐Bonded Organic Framework With Two‐Dimensional Pores for Rapid Adsorption Kinetics and Efficient Xe/Kr Separation0

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  1. High Uptake of ReO 4 − and CO 2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th 48 Ni 6 ] Nanocage‐Based Metal–Organic Framework

    Angewandte Chemie International Edition · 2019-02-21

    Hang Xu, Chun‐Shuai Cao, Han‐Shi Hu, Shibin Wang, Jincheng Liu, Peng Cheng, Nikolas Kaltsoyannis, Jun Li, Bin Zhao

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  2. High Uptake of ReO4− and CO2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th48Ni6] Nanocage‐Based Metal–Organic Framework

    Angewandte Chemie · 2019-02-22

    Hang Xu, Chun‐Shuai Cao, Han‐Shi Hu, Shibin Wang, Jincheng Liu, Peng Cheng, Nikolas Kaltsoyannis, Jun Li, Bin Zhao

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  3. Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework

    Inorganic Chemistry · 2019-02-25

    Peng Li, Subhadip Goswami, Ken‐ichi Otake, Xingjie Wang, Zhijie Chen, Sylvia L. Hanna, Omar K. Farha

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  4. Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials

    ACS Applied Nano Materials · 2019-03-15

    Peng Li, Xingjie Wang, Ken‐ichi Otake, Jiafei Lyu, Sylvia L. Hanna, Timur İslamoğlu, Omar K. Farha

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  5. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

    Chemistry - A European Journal · 2019-04-10

    Korey Prescott Carter, J. August Ridenour, Mark Kalaj, Christopher L. Cahill

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  6. A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton

    Journal of the American Chemical Society · 2019-05-15

    Liangying Li, Lidong Guo, Zhiguo Zhang, Qiwei Yang, Yiwen Yang, Zongbi Bao, Qilong Ren, Jing Li

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  7. A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane

    Angewandte Chemie International Edition · 2019-05-22

    Zheng Niu, Xili Cui, Tony Pham, Pui Ching Lan, Huabin Xing, Katherine A. Forrest, Łukasz Wojtas, Brian Space, Shengqian Ma

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  8. A Metal–Organic Framework Based Methane Nano‐trap for the Capture of Coal‐Mine Methane

    Angewandte Chemie · 2019-05-22

    Zheng Niu, Xili Cui, Tony Pham, Pui Ching Lan, Huabin Xing, Katherine A. Forrest, Łukasz Wojtas, Brian Space, Shengqian Ma

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  9. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie International Edition · 2019-11-20

    Qingju Wang, Tian Ke, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

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  10. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie · 2019-11-20

    Qingju Wang, Ke Tian, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

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  11. Zinc and Cadmium Complexes of Pyridinemethanol Carboxylates: Metal Carboxylate Zwitterions and Metal–Organic Frameworks

    ChemPlusChem · 2020-04-24

    Yan Liu, Shi‐Xin Lin, Ru‐Jie Niu, Quan Liu, Wen‐Hua Zhang, David James Young

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  12. From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates

    European Journal of Inorganic Chemistry · 2020-06-19

    Aphra V. Murray, Nicole A. Vanagas, Jennifer N. Wacker, Jeffery A. Bertke, Karah E. Knope

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  13. Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution

    Chemistry - A European Journal · 2020-09-22

    Zi‐Jian Li, Yu Ju, Huangjie Lu, Xiaoling Wu, Xinle Yu, Yongxin Li, Xiaowei Wu, Zhi‐Hui Zhang, Jian Hung Lin, Yuan Qian, Mingyang He, Jian‐Qiang Wang

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  14. Docking of Cu I and Ag I in Metal–Organic Frameworks for Adsorption and Separation of Xenon

    Angewandte Chemie International Edition · 2020-11-28

    Haoze Wang, Zhaolin Shi, Jingjing Yang, Tu Sun, Bunyarat Rungtaweevoranit, Hao Lyu, Yue‐Biao Zhang, Omar M. Yaghi

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  15. Docking of CuI and AgI in Metal–Organic Frameworks for Adsorption and Separation of Xenon

    Angewandte Chemie · 2020-11-28

    Haoze Wang, Zhaolin Shi, Jingjing Yang, Tu Sun, Bunyarat Rungtaweevoranit, Hao Lyu, Yue‐Biao Zhang, Omar M. Yaghi

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  16. Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

    RSC Advances · 2021-01-01

    Ting Yu, Zhenghua Qian, Lin Li, Xiaoling Wu, Hui He, Yanbo Qiao, Ye Guoan

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  17. A Robust Calcium–Organic Framework for Effective Separation of Xenon and Krypton

    Crystal Growth & Design · 2021-01-05

    Li Wang, Wenping Liu, Jie Ding, Hualian Zhang, Yudie Zhu, Feng Luo

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  18. High‐Silica CHA Zeolite Membrane with Ultra‐High Selectivity and Irradiation Stability for Krypton/Xenon Separation

    Angewandte Chemie International Edition · 2021-02-05

    Xuerui Wang, Tao Zhou, Ping Zhang, Wenfu Yan, Yongguo Li, Li Peng, Dylan Veerman, Mengyang Shi, Xuehong Gu, Freek Kapteijn

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  19. High‐Silica CHA Zeolite Membrane with Ultra‐High Selectivity and Irradiation Stability for Krypton/Xenon Separation

    Angewandte Chemie · 2021-02-05

    Xuerui Wang, Tao Zhou, Ping Zhang, Wenfu Yan, Yongguo Li, Li Peng, Dylan Veerman, Mengyang Shi, Xuehong Gu, Freek Kapteijn

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  20. Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage

    Inorganic Chemistry · 2021-04-12

    Yuan-Bo Wu, Cheng Xiong, Qing‐Yan Liu, Jianguo Ma, Feng Luo, Yu‐Ling Wang

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  21. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  22. Unveiling the Unique Roles of Metal Coordination and Modulator in the Polymorphism Control of Metal‐Organic Frameworks

    Chemistry - A European Journal · 2021-11-03

    Zi‐Jian Li, Yu Ju, Zeya Zhang, Huangjie Lu, Yongxin Li, Ningjin Zhang, Xian‐Long Du, Xiaofeng Guo, Zhi‐Hui Zhang, Yuan Qian, Mingyang He, Jian‐Qiang Wang, Jian Hung Lin

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  23. MOFs with 12-Coordinate 5f-Block Metal Centers

    Journal of the American Chemical Society · 2022-02-10

    Kai Lv, Christian Urbank, Michael Patzschke, Juliane März, Peter Kaden, Stephan Weiß, Moritz Schmidt

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  24. Creating Optimal Pockets in a Clathrochelate-Based Metal–Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies

    Journal of the American Chemical Society · 2022-02-18

    Wei Gong, Yi Xie, Thang Duc Pham, Suchetha Shetty, Florencia A. Son, Karam B. Idrees, Zhijie Chen, Haomiao Xie, Yan Liu, Randall Q. Snurr, Banglin Chen, Bassam Alameddine, Yong Cui, Omar K. Farha

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  25. Metal-organic frameworks in separations: A review

    Analytica Chimica Acta · 2022-08-05

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  26. Boosting xenon adsorption with record capacity in microporous carbon molecular sieves

    Science China Chemistry · 2022-12-27

    Fuqiang Chen, Xinlei Huang, Yang Liu, Zhiguo Zhang, Qiwei Yang, Yiwei Yang, Dan Zhao, Qilong Ren, Zongbi Bao

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  27. Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation

    Journal of the American Chemical Society · 2023-01-18

    Wei Gong, Yi Xie, Xingjie Wang, Kent O. Kirlikovali, Karam B. Idrees, Fanrui Sha, Haomiao Xie, Yan Liu, Banglin Chen, Yong Cui, Omar K. Farha

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  28. Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers

    Inorganic Chemistry Communications · 2023-08-18

    Xue-Ru Liu, Xue-Ru Liu, Zhuang Hui, Wen-Lei Mu, Chao Liu

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  29. Metal-organic frameworks for xenon and krypton separation

    Cell Reports Physical Science · 2023-11-20

    Yuting Yang, Chang‐Zheng Tu, Licheng Guo, Li Wang, Feixing Cheng, Feng Luo

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  30. Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework

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  31. Anion‐Shielded Porous Organic Cages for High‐Performance Xenon/Krypton Separation

    Angewandte Chemie · 2025-11-24

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  32. An Ultrastable Hydrogen‐Bonded Organic Framework With Two‐Dimensional Pores for Rapid Adsorption Kinetics and Efficient Xe/Kr Separation

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