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RESEARCH PAPER · Chemistry of Materials · 2014

Stable, Low Polarization Resistance Solid Oxide Fuel Cell Anodes: La1–xSrxCr1–xFexO3-δ (x = 0.2–0.67)

Daniel E. Fowler, Jacob M. Haag, Claire Boland, David M. Bierschenk, Scott Alexander Barnett, Kenneth Reinhard Poeppelmeier

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Stable, Low Polarization Resistance Solid Oxide Fuel Cell Anodes: La1–xSrxCr1–xFexO3-δ (x = 0.2–0.67)OriginalA-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes208Decreasing the Polarization Resistance of (La,Sr)CrO3−δ Solid Oxide Fuel Cell Anodes by Combined Fe and Ru Substitution58Direct methane oxidation on La1−Sr Cr1FeyO3− perovskite-type oxides as potential anode for intermediate temperature solid oxide fuel cells50Hydrogen Oxidation Mechanisms on Perovskite Solid Oxide Fuel Cell Anodes72Designing Perovskite Oxides for Solid Oxide Fuel Cells21Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO1057In Situ Growth of Nanoparticles in Layered Perovskite La0.8Sr1.2Fe0.9Co0.1O4−δ as an Active and Stable Electrode for Symmetrical Solid Oxide Fuel Cells176Facile Synthesis of Highly Active and Robust Ni–Mo Bimetallic Electrocatalyst for Hydrocarbon Oxidation in Solid Oxide Fuel Cells34Improving oxygen permeation of MIEC membrane reactor by enhancing the electronic conductivity under intermediate-low oxygen partial pressures56The Chemical Capacitance as a Fingerprint of Defect Chemistry in Mixed Conducting Oxides24Catalytic Reactions in MIEC Membrane Reactors1New Insight into Hydrogen Oxidation Reaction on La 0.3 Sr 0.7 Fe 0.7 Cr 0.3 O 3-δ Perovskite as a Solid Oxide Fuel Cell Anode28Fast Response, Highly Sensitive and Selective Mixed-Potential H 2 Sensor Based on (La, Sr)(Cr, Fe)O 3-δ Perovskite Sensing Electrode64Tailoring ceramic membrane structures of solid oxide fuel cells via polymer-assisted electrospray deposition173D‐Printed Electrodes with Improved Mass Transport Properties66Electrical conductivity and oxygen diffusion behaviour of the (La 0.8 Sr 0.2 ) 0.95 Cr x Fe 1−x O 3−δ ( x = 0.3, 0.5 and 0.7) A-site deficient perovskites15The enhanced electrochemical response of Sr(Ti 0.3 Fe 0.7 Ru 0.07 )O 3−δ anodes due to exsolved Ru–Fe nanoparticles59Self-Regenerating Co–Fe Nanoparticles on Perovskite Oxides as a Hydrocarbon Fuel Oxidation Catalyst in Solid Oxide Fuel Cells90A novel anode for solid oxide fuel cells prepared from phase conversion of La0.3Sr0.7Fe0.7Cr0.3O3-δ perovskite under humid hydrogen26Novel carbon and sulfur-tolerant anode material FeNi 3 @PrBa(Fe,Ni) 1.9 Mo 0.1 O 5+δ for intermediate temperature solid oxide fuel cells51Partial oxidation of methane on neodymium and lanthanium chromate based perovskites for hydrogen production27Review of proton- and oxide-ion-conducting perovskite materials for SOFC applications29Highly carbon– and sulfur–tolerant Sr2TiMoO6−δ double perovskite anode for solid oxide fuel cells57Advanced perovskite anodes for solid oxide fuel cells: A review213Bilayer Electrolytes for Low Temperature and Intermediate Temperature Solid Oxide Fuel Cells – A Review13Progress in perovskite anodes for intermediate-temperature solid oxide fuel cells1A-site bismuth doping, a new strategy to improve the electrocatalytic performances of lanthanum chromate anodes for solid oxide fuel cells84Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles2Antimony doping to greatly enhance the electrocatalytic performance of Sr 2 Fe 1.5 Mo 0.5 O 6− δ perovskite as a ceramic anode for solid oxide fuel cells53Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells61Iron-based electrode materials for solid oxide fuel cells and electrolysers130Recent Progress on Mixed Conducting Oxygen Transport Membrane Reactors for Water Splitting Reaction5The effect of Ni doping on the structural, optical and dielectric properties of nanocrystalline YbCrO316A rational design of FeNi alloy nanoparticles and carbonate-decorated perovskite as a highly active and coke-resistant anode for solid oxide fuel cells44The relation between mixed-potential hydrogen response and electrochemical activities for perovskite oxides14Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles56Visible-light excited polar Dion–Jacobson Rb(Bi 1− x Eu x ) 2 Ti 2 NbO 10 perovskites: photoluminescence properties and in vitro bioimaging20Tracking the nanoparticle exsolution/reoxidation processes of Ni-doped SrTi 0.3 Fe 0.7 O 3− δ electrodes for intermediate temperature symmetric solid oxide fuel cells46Deciphering the Interaction of Single-Phase La0.3Sr0.7Fe0.7Cr0.3O3-δ with CO2/CO Environments for Application in Reversible Solid Oxide Cells25Electrochemical Performance Investigation of Sr(Ti 1−x Fe x )O 3− δ Fuel Electrodes with Different Fe Contents for Solid Oxide Electrochemical Cells3LaCrO3–CeO2-Based Nanocomposite Electrodes for Efficient Symmetrical Solid Oxide Fuel Cells31Reduction of operation temperature in SOFCs utilizing perovskites: Review6Simulation of dynamic response of mixed-potential hydrogen sensors4Nanostructured La0.75Sr0.25Cr0.5Mn0.5O3–Ce0.8Sm0.2O2 Heterointerfaces as All-Ceramic Functional Layers for Solid Oxide Fuel Cell Applications24Synergistically Promoting Coking Resistance of a La0.4Sr0.4Ti0.85Ni0.15O3−δ Anode by Ru-Doping-Induced Active Twin Defects and Highly Dispersed Ni Nanoparticles18Anode material for solid oxide fuel cell: a review43Electrochemical performance of iron doped lanthanum strontium chromites as fuel electrodes in high temperature solid oxide cells9Enhanced stability of electrocatalytic properties against cathodic current polarization for chromium ferrite perovskite-based composite cathodes2Catalytic effect of aluminum on the structural, optical, and electrical properties of LaSrCrO3-δ anode6Enhancing layered perovskite ferrites with ultra-high-density nanoparticles via cobalt doping for ceramic fuel cell anode13Dry reforming of methane over Ni5 nanocluster supported on double perovskite surface − A DFT study5Different enhancement of Ni doping on La0.3Sr0.7Fe0.9Ti0.1O3-δ electrodes in symmetrical solid oxide cell1Recent Progress on the Materials of Oxygen Ion-Conducting Solid Oxide Fuel Cells and Experimental Analysis of Biogas-Assisted Electrolysis over a LSC Anode11Effects of praseodymium oxide infiltration on the surface segregation behavior and electrocatalytic properties of La0.3Ca0.7Fe0.7Cr0.3O3-δ cathode2Perovskite Type ABO 3 Oxides in Photocatalysis, Electrocatalysis, and Solid Oxide Fuel Cells: State of the Art and Future Prospects354A new look into the surface segregation problem of Fe–Cr based perovskite cathodes enabled by bond valence modeling: A viable solution strategy and the underlying mechanisms1

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  1. A-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes

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  2. Decreasing the Polarization Resistance of (La,Sr)CrO3−δ Solid Oxide Fuel Cell Anodes by Combined Fe and Ru Substitution

    Chemistry of Materials · 2015-04-30

    Daniel E. Fowler, Andreas Messner, Elizabeth C. Miller, Benjamin W. Slone, Scott Alexander Barnett, Kenneth Reinhard Poeppelmeier

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  3. Direct methane oxidation on La1−Sr Cr1FeyO3− perovskite-type oxides as potential anode for intermediate temperature solid oxide fuel cells

    Applied Catalysis B: Environmental · 2015-06-17

    C. F. Aliotta, Leonarda Francesca Liotta, Francesca Deganello, Valeria La Parola, Antonino Martorana

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  4. Hydrogen Oxidation Mechanisms on Perovskite Solid Oxide Fuel Cell Anodes

    Journal of The Electrochemical Society · 2016-01-01

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  5. Designing Perovskite Oxides for Solid Oxide Fuel Cells

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  6. Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO10

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  7. In Situ Growth of Nanoparticles in Layered Perovskite La0.8Sr1.2Fe0.9Co0.1O4−δ as an Active and Stable Electrode for Symmetrical Solid Oxide Fuel Cells

    Chemistry of Materials · 2016-04-11

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  8. Facile Synthesis of Highly Active and Robust Ni–Mo Bimetallic Electrocatalyst for Hydrocarbon Oxidation in Solid Oxide Fuel Cells

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  9. Improving oxygen permeation of MIEC membrane reactor by enhancing the electronic conductivity under intermediate-low oxygen partial pressures

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  10. The Chemical Capacitance as a Fingerprint of Defect Chemistry in Mixed Conducting Oxides

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  11. Catalytic Reactions in MIEC Membrane Reactors

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  12. New Insight into Hydrogen Oxidation Reaction on La 0.3 Sr 0.7 Fe 0.7 Cr 0.3 O 3-δ Perovskite as a Solid Oxide Fuel Cell Anode

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  13. Fast Response, Highly Sensitive and Selective Mixed-Potential H 2 Sensor Based on (La, Sr)(Cr, Fe)O 3-δ Perovskite Sensing Electrode

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  14. Tailoring ceramic membrane structures of solid oxide fuel cells via polymer-assisted electrospray deposition

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  15. 3D‐Printed Electrodes with Improved Mass Transport Properties

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  16. Electrical conductivity and oxygen diffusion behaviour of the (La 0.8 Sr 0.2 ) 0.95 Cr x Fe 1−x O 3−δ ( x = 0.3, 0.5 and 0.7) A-site deficient perovskites

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  17. The enhanced electrochemical response of Sr(Ti 0.3 Fe 0.7 Ru 0.07 )O 3−δ anodes due to exsolved Ru–Fe nanoparticles

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  18. Self-Regenerating Co–Fe Nanoparticles on Perovskite Oxides as a Hydrocarbon Fuel Oxidation Catalyst in Solid Oxide Fuel Cells

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  19. A novel anode for solid oxide fuel cells prepared from phase conversion of La0.3Sr0.7Fe0.7Cr0.3O3-δ perovskite under humid hydrogen

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  20. Novel carbon and sulfur-tolerant anode material FeNi 3 @PrBa(Fe,Ni) 1.9 Mo 0.1 O 5+δ for intermediate temperature solid oxide fuel cells

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  21. Partial oxidation of methane on neodymium and lanthanium chromate based perovskites for hydrogen production

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  22. Review of proton- and oxide-ion-conducting perovskite materials for SOFC applications

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  23. Highly carbon– and sulfur–tolerant Sr2TiMoO6−δ double perovskite anode for solid oxide fuel cells

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  24. Advanced perovskite anodes for solid oxide fuel cells: A review

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  25. Bilayer Electrolytes for Low Temperature and Intermediate Temperature Solid Oxide Fuel Cells – A Review

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  27. A-site bismuth doping, a new strategy to improve the electrocatalytic performances of lanthanum chromate anodes for solid oxide fuel cells

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  28. Sr(Ti,Fe)O 3− δ Based Intermediate Temperature Solid Oxide Fuel Cell Anode with Self-precipitated (Ni,Fe) and Gd 0.1 Ce 0.9 O 2− δ Nano Particles

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  29. Antimony doping to greatly enhance the electrocatalytic performance of Sr 2 Fe 1.5 Mo 0.5 O 6− δ perovskite as a ceramic anode for solid oxide fuel cells

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  30. Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells

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  34. A rational design of FeNi alloy nanoparticles and carbonate-decorated perovskite as a highly active and coke-resistant anode for solid oxide fuel cells

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  35. The relation between mixed-potential hydrogen response and electrochemical activities for perovskite oxides

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  36. Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles

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  41. LaCrO3–CeO2-Based Nanocomposite Electrodes for Efficient Symmetrical Solid Oxide Fuel Cells

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  42. Reduction of operation temperature in SOFCs utilizing perovskites: Review

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  45. Synergistically Promoting Coking Resistance of a La0.4Sr0.4Ti0.85Ni0.15O3−δ Anode by Ru-Doping-Induced Active Twin Defects and Highly Dispersed Ni Nanoparticles

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  49. Catalytic effect of aluminum on the structural, optical, and electrical properties of LaSrCrO3-δ anode

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