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RESEARCH PAPER · Chemistry of Materials · 2018

Self-Regenerating Co–Fe Nanoparticles on Perovskite Oxides as a Hydrocarbon Fuel Oxidation Catalyst in Solid Oxide Fuel Cells

Ke‐Yu Lai, Arumugam Manthiram

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Self-Regenerating Co–Fe Nanoparticles on Perovskite Oxides as a Hydrocarbon Fuel Oxidation Catalyst in Solid Oxide Fuel CellsOriginalUsing Data Mining To Search for Perovskite Materials with Higher Specific Surface Area44PEROVSKITE-LIKE (La0.75Ca0.25)0.95Cr1-xFexO3-δ AS POTENTIAL ELECTRODE MATERIALS FOR SYMMETRIC SOLID OXIDE FUEL CELLS0Sulfur Poisoning Recovery on a Solid Oxide Fuel Cell Anode Material through Reversible Segregation of Nickel50A-Site Ordered Double Perovskite with in Situ Exsolved Core–Shell Nanoparticles as Anode for Solid Oxide Fuel Cells97Nickel enriched Ruddlesden-Popper type lanthanum strontium manganite as electrode for symmetrical solid oxide fuel cell54Enhancing coking resistance of Ni/YSZ electrodes: In situ characterization, mechanism research, and surface engineering107Insight into the Electrochemical Processes of the Titanate Electrode with in Situ Ni Exsolution for Solid Oxide Cells28Co-electrolysis of H2O and CO2 on exsolved Ni nanoparticles for efficient syngas generation at controllable H2/CO ratios94In situ exsolution of PdO nanoparticles from non-stoichiometric LaFePd0.05O3+δ electrode for impedancemetric NO2 sensor33Enhancing NH3 sensing performance of mixed potential type sensors by chemical exsolution of Ag nanoparticle on AgNbO3 sensing electrode43Interface and grain boundary degradation in LSM-YSZ composite Solid Oxide Fuel Cell cathodes operated in humidified air22Heterointerface engineering for enhancing the electrochemical performance of solid oxide cells319Robust redox-reversible perovskite type steam electrolyser electrode decorated with in situ exsolved metallic nanoparticles67Advanced perovskite anodes for solid oxide fuel cells: A review212Wrinkled Perovskite La0.9Mn0.6Ni0.4O3−δ Nanofibers as Highly Efficient Electrocatalyst for Rechargeable Li−O2 Batteries11In Situ Investigation of Reversible Exsolution/Dissolution of CoFe Alloy Nanoparticles in a Co‐Doped Sr 2 Fe 1.5 Mo 0.5 O 6− δ Cathode for CO 2 Electrolysis340Progress in perovskite anodes for intermediate-temperature solid oxide fuel cells1Direct-methane solid oxide fuel cells with an in situ formed Ni–Fe alloy composite catalyst layer over Ni–YSZ anodes56Review of anodic reactions in hydrocarbon fueled solid oxide fuel cells and strategies to improve anode performance and stability57Au Quantum Dot/Nickel Tetraminophthalocyanaine–Graphene Oxide-Based Photoelectrochemical Microsensor for Ultrasensitive Epinephrine Detection28In-situ exsolution of nanoparticles from Ni substituted Sr2Fe1.5Mo0.5O6 perovskite oxides with different Ni doping contents111Active technological control of synthesis of high-active catalysts on the surface of solid electrolytes of fuel elements880 Hours operation of a tubular solid oxide fuel cell using propane/air23In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts163Structure and electrochemical properties of titanate perovskite with in situ exsolution as a ceramic electrode material9Exsolved Alloy Nanoparticles Decorated Ruddlesden–Popper Perovskite as Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells55In-situ exsolved NiFe alloy nanoparticles on Pr0.8Sr1.2(NiFe)O4-δ for direct hydrocarbon fuel solid oxide fuel cells35A highly active and carbon-tolerant anode decorated with in situ grown cobalt nano-catalyst for intermediate-temperature solid oxide fuel cells88Efficient bifunctional electrocatalysts for solid oxide cells based on the structural evolution of perovskites with abundant defects and exsolved CoFe nanoparticles72Dopant‐Driven Positive Reinforcement in Ex‐Solution Process: New Strategy to Develop Highly Capable and Durable Catalytic Materials51Dopant-Induced Tailoring of Isothermal Redox Properties of CaMnO3 Perovskites4Modeling Exsolution of Pt from ATiO3 Perovskites (A = Ca/Sr/Ba) Using First-Principles Methods21Designing perovskite catalysts for controlled active-site exsolution in the microwave dry reforming of methane62Metal Exsolution to Enhance the Catalytic Activity of Electrodes in Solid Oxide Fuel Cells55Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives181NdBaFe2–xCoxO5+δ Double Perovskites with Exsolved Co–Fe Alloy Nanoparticles as Highly Efficient and Stable Anodes for Direct Hydrocarbon Solid Oxide Fuel Cells11Trends and Prospects of Bimetallic Exsolution67Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules120Nanoparticle exsolution in perovskite oxide and its sustainable electrochemical energy systems43The first observation of Ni nanoparticle exsolution from YSZ and its application for dry reforming of methane22Emergence and Future of Exsolved Materials214Clean and stable conversion of oxygen-bearing low-concentration coal mine gas by solid oxide fuel cells with an additional reforming layer36Perovskite Oxides in Catalytic Combustion of Volatile Organic Compounds: Recent Advances and Future Prospects137Unraveling the evolution of exsolved Fe–Ni alloy nanoparticles in Ni-doped La 0.3 Ca 0.7 Fe 0.7 Cr 0.3 O 3− δ and their role in enhancing CO 2 –CO electrocatalysis35Plasma Driven Exsolution for Nanoscale Functionalization of Perovskite Oxides50Impact of syngas from biomass gasification on solid oxide fuel cells: A review study for the energy transition56Study on anode material of CoδFe1-δOx-Sm0.2Ce0.8O1.9 for solid oxide fuel cell0A critical review of the nano-structured electrodes of solid oxide cells40The two-step electrosynthesis of nanocomposites of Ag, Au, and Pd nanoparticles with iron( ii ) oxide-hydroxide13A comprehensive review of solid oxide fuel cells operating on various promising alternative fuels382Propane-fuelled microtubular solid oxide fuel cell stack electrically connected by an anodic rectangular window11Methane reforming in solid oxide fuel cells: Challenges and strategies87Advances on methane reforming in solid oxide fuel cells71Exsolution: A promising strategy for constructing advanced composite solids16Chemical Looping Partial Oxidation of Methane: Reducing Carbon Deposition through Alloying17Cyclobis(paraquat-p-phenylene) – mediated electrosynthesis of new-type nanocomposite of palladium nanoparticles with designated macrocyclic organic compound7Coke-resistant ferrite anode decorated with in-situ exsolved ceria for carbonaceous fuel oxidation8Liquid biofuels for solid oxide fuel cells: A review32Recent Developments on Solid Oxide Fuel Cells Using Methane and other Related Hydrocarbons0Reduced thermal expansion by surface-mounted nanoparticles in a pillared-layered metal-organic framework4Bifunctional electrocatalysts Pr 0.5 Sr 0.5 Cr 0.1 Fe 0.9− x Ni x O 3− δ ( x = 0.1, 0.2) for the HOR and ORR of a symmetric solid oxide fuel cell50Boosting the performance of reversible solid oxide electrochemical cells with a novel hybrid oxygen electrode, Pr 1.39 Ba 0.14 Sr 0.53 Co 1.48 Fe 0.76 O 6− δ -Ba 0.66 Sr 0.34 CoO 3− δ16Synthesis and characterisation of a ceria-based cobalt-zinc anode nanocomposite for low-temperature solid oxide fuel cells (LT-SOFCs)21Emerging Exsolution Materials for Diverse Energy Applications: Design, Mechanism, and Future Prospects45Exsolution of Co–Fe Alloy Nanoparticles on the PrBaFeCoO5+δ Layered Perovskite Monitored by Neutron Powder Diffraction and Catalytic Effect on Dry Reforming of Methane13Ni-doped Ba0.9Zr0.8Y0.2O3-δ as a methane dry reforming catalyst for direct CH4–CO2 solid oxide fuel cells16NiCoP/Co9S8 nanoflowers as advanced electrode material for asymmetric supercapacitors13Quantifying Electrochemical Driving Force for Exsolution in Perovskite Oxides by Designing Graded Oxygen Chemical Potential29Achieving High-Efficiency CO2 Electrolysis for SrFeO3-δ-Based Symmetric Electrodes13Promoting catalysis activity with optimizable self-generated Co-Fe alloy nanoparticles for efficient CO2 electrolysis performance upgrade33A doped cobaltite for enhanced SOFCs fed with dry biogas8Improving the Oxygen Evolution Reaction: Exsolved Cobalt Nanoparticles on Titanate Perovskite Catalyst18Perovskite-Type Oxides as Exsolution Catalysts in CO2 Utilization5Nanoparticle Exsolution on Perovskite Oxides: Insights into Mechanism, Characteristics and Novel Strategies102Review on Fe-based double perovskite cathode materials for solid oxide fuel cells69Realizing efficient operations of Ni-cermet-based fuel cells on hydrocarbons via an in situ self-assembled metal/oxide nano-heterostructured catalyst8La-based perovskites for autothermal reforming: In-situ electrical conductivity measurements and catalytic study2Application of metallic oxide coated carbon nanoparticles in adsorption of heavy metals and reusability for latent fingerprint detection: A review9In situ ex-solution of CoFeRu solid solution nanoparticles from non-stoichiometric (La0.8Sr0.2)0.9Co0.1Fe0.8Ru0.1O3−δ perovskite for hydrogen gas sensor3Co-Ru bimetallic nanoparticles/oxygen deficient perovskite oxides as a highly efficient anode catalyst layer for direct-methane solid oxide fuel cells10Optimizing Reversible Exsolution and Phase Transformation in Double Perovskite Sr2Fe1.5‐xCoxMo0.5O6‐δ Electrodes for High‐Performance Symmetric Solid Oxide Cells4Hierarchical exsolution in vertically aligned heterostructures8In Situ Probing Dynamic Exsolution of Fe0 from Perovskite under Graded Potentials7Surface reconstruction of versatile perovskites via in situ nanoparticle engineering for solid oxide cells4In situ exsolved Fe-Ni nanoparticles on Pr0.8La0.2Fe Ni1-O3- perovskite as high-performance anode for solid oxide fuel cells3Electrode surface engineering for proton-conducting ceramic cells: Advances and perspectives1Impact of Phase-Separated Janus-Type Formation on the Reversibility of Multicomponent Exsolved Nanoparticles from Complex Perovskites0Fe2O3-modified anodes enable efficient deposited-carbon utilization in direct propane fuel cells0Investigation on microwave-driven chemical looping steam reforming (CLSR) of toluene over LaNiO3-σ perovskite oxygen carriers0

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  5. Nickel enriched Ruddlesden-Popper type lanthanum strontium manganite as electrode for symmetrical solid oxide fuel cell

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  16. In Situ Investigation of Reversible Exsolution/Dissolution of CoFe Alloy Nanoparticles in a Co‐Doped Sr 2 Fe 1.5 Mo 0.5 O 6− δ Cathode for CO 2 Electrolysis

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  18. Direct-methane solid oxide fuel cells with an in situ formed Ni–Fe alloy composite catalyst layer over Ni–YSZ anodes

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