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RESEARCH PAPER · Energy & Environmental Science · 2021

Iron-based electrode materials for solid oxide fuel cells and electrolysers

Chengsheng Ni, Jun Hong Zhou, Ziye Zhang, Shuangbin Li, Jiupai Ni, Kai Wu, John T. S. Irvine

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Iron-based electrode materials for solid oxide fuel cells and electrolysersOriginalFuel Cell Technology: The Future Ahead0Phase transition with in situ exsolution nanoparticles in the reduced Pr 0.5 Ba 0.5 Fe 0.8 Ni 0.2 O 3− δ electrode for symmetric solid oxide cells55Transparent conductive oxide type materials as the anode of solid oxide fuel cells at a reduced temperature11Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells7Robust Ruddlesden‐Popper phase Sr 3 Fe 1.3 Mo 0.5 N i0.2 O 7‐δ decorated with in‐situ exsolved Ni nanoparticles as an efficient anode for hydrocarbon fueled solid oxide fuel cells38La0.5Ba0.5CuxFe1−xO3−δ as cathode for high-performance proton-conducting solid oxide fuel cell27Structural Features and Defect Equilibrium in Cubic PrBa1−xSrxFe2O6−δ12Oxidative Strong Metal–Support Interaction Induced by an Amorphous TiOx Seed Layer Boosts the Electrochemical Performance and High-Temperature Durability of Pt Nanocatalysts26Construction of anodic electron transfer chain based on CuCl2/TiOSO4 synergetic mediators for highly efficient conversion of biomass wastes into electricity at low temperature7Coke-resistant ferrite anode decorated with in-situ exsolved ceria for carbonaceous fuel oxidation8Ru-doped lanthanum ferrite as a stable and versatile electrode for reversible symmetric solid oxide cells (r-SSOCs)55Evaluation of electrode-oriented properties of BaFe1−xCexO3−δ9Enhanced oxygen bulk diffusion of La0.6Sr0.4FeO3-δ fuel electrode by high valence transition metal doping for direct CO2 electrolysis in solid oxide electrolysis cells24Defect equilibrium and charge transport in R0.25Sr0.75FeO3−δ (R = La, Nd, Y, Ho): The effect of cation type6Gas sensitization and photochromism of CaTiO3−δ for visible-light photocatalysis16Fluorination Intensifying Oxygen Evolution Reaction for High-Temperature Steam Electrolysis16Perovskite Manganite Materials: Recent Advancements and Challenges as Cathode for Solid Oxide Fuel Cell Applications2Perspective on high-temperature surface oxygen exchange in a porous mixed ionic-electronic conductor for solid oxide cells11Tantalum doped La 0.6 Sr 0.4 FeO 3− δ electrodes for symmetrical proton conducting solid oxide fuel cells18Design of efficient and durable symmetrical protonic ceramic fuel cells at intermediate temperatures via B-site doping of Ni in BaCe0.56Zr0.2Ni0.04Y0.2O3–δ34A stable chromite anode for SOFC with Ce/Ni exsolution for simultaneous electricity generation and CH4 reforming16Chemical design of oxygen electrodes for solid oxide electrochemical cells: A guide66Boosting electrochemical CO2 directly electrolysis by tuning the surface oxygen defect of perovskite40Exsolved materials for CO2 reduction in high-temperature electrolysis cells32Triggering electrode multi-catalytic activity for reversible symmetric solid oxide cells by Pt-doping lanthanum strontium ferrite63Functional properties of La1–xBaxFeO3–δ as symmetrical electrodes for protonic ceramic electrochemical cells7Co nanoparticles decorated with in-situ exsolved oxygen-storage CeO2 for an efficient and stable electrolysis of pure CO28Effect of Zn doping on Sr3Fe2O7-δ Ruddlesden-Popper oxides as active and robust cathodes for protonic ceramic fuel cells19Fluorine-insertion in solid oxide materials for improving their ionic transport and stability. A brief review58Chemistry and electrochemistry of CeO2-based interlayers: Prolonging the lifetime of solid oxide fuel and electrolysis cells41Influence of synthesis temperature on oxygen exchange behavior of electrode material PrBaFe2O6−14Recent progress in electrolyser control technologies for hydrogen energy production: A patent landscape analysis and technology updates38In Situ Generation of Pseudorutile Oxide as the Cathode for Direct Electrolysis of CO21Fluorine doped non-perovskite-type Fe2TiO5 oxide without alkaline earth elements as cathode for efficient CO2 electrolysis10An efficient and durable solid oxide fuel cell integrated with coal gasification system2Physicochemical analysis of infiltrated cathode symmetric cells for intermediate temperature SOFCs9High La/Sr ratio in La0.67Sr0.33Fe0.67Ti0.33O3-δ cathode induced a controlled Fe0 exsolution for CO2 electrolysis10Sr2FeNi0.4Mo0.6O6−δ Evolution for SOFC and SOEC Applications10Smart Dual‐Exsolved Self‐Assembled Anode Enables Efficient and Robust Methane‐Fueled Solid Oxide Fuel Cells34Revealing the Reaction Mechanism of CO2/H2O Coelectrolysis on Perovskite-Based Cathode Materials18Electrochemical performance of iron doped lanthanum strontium chromites as fuel electrodes in high temperature solid oxide cells9Influence of Transition Metal Elements on Ni Migration in Solid Oxide Cell Fuel Electrodes2Strontium doped Fe-based porous carbon for highly efficient electrocatalytic ORR and MOR reactions15Cu doping enhanced the performance of BaFe0.8Zr0.1Y0.1O3-δ cathode for a proton-conducting solid oxide fuel cell at low temperature22On Fe-based perovskite electrodes for symmetrical reversible solid oxide cells – A review34Ba-containing ferrites, Pr1–xBaxFeO3–δ, as symmetrical electrodes and their functional properties in both oxidizing and reducing atmospheres12Electrochemical performance of symmetric solid oxide cells employing a Sc-doped SrFeO3-δ-based electrode42Current and further trajectories in designing functional materials for solid oxide electrochemical cells: A review of other reviews116CO2 Electrolyzers354Bismuth doped La0.5-xBixSr0.5Fe0.9Mo0.1O3-δ perovskite as high active oxygen electrode for solid oxide cells13Syngas Production from CO 2 and H 2 O via Solid-Oxide Electrolyzer Cells: Fundamentals, Materials, Degradation, Operating Conditions, and Applications145Why do BaCo0.4Fe0.4Zr0.1Y0.1O3–δ-derived complex oxides become one of the most promising electrodes for protonic ceramic electrochemical cells? An explanatory review58Improved surface activity of lanthanum ferrite perovskite oxide through controlled Pt-doping for solid oxide cell (SOC) electrodes13Discovering two general characteristic times of transient responses in solid oxide cells20Multifunctional perovskite oxide Sr2Ti1-Ni FeO6– (x=0.1, 0.2, 0.3) as symmetrical electrode for solid oxide cells9Enhancing the CO2 electrolysis performance by Ce doped La0·7Sr0·3Fe0·9Ni0·1O3-δ electrode in symmetric solid oxide electrolysis cell8Activating Ga0.8Ti0.4Nb0.8O4 cathode for direct electrolysis of CO2 via electrochemical switching and infiltration of co-catalyst5Advances in Advanced In Situ Assembled Composite Electrode Materials for Enhanced Solid Oxide Cell Performance33Synthesis and Characterisation of Nanocrystalline CoxFe1−xGDC Powders as a Functional Anode Material for the Solid Oxide Fuel Cell5Boosting the performance of La0.5Sr0.5Fe0.9Mo0.1O3-δ oxygen electrode via surface-decoration with Pr6O11 nano-catalysts7Effect of Continuous Electrolysis on the Power Generation Performance of a Microtubular Oxide Fuel Cell Using Intermediate Ring‐Shaped Collector0Anionic and cationic co-doping to enhance the oxygen transport property of Bi0.5Sr0.5FeO3-δ as a high-performance air electrode for reversible solid oxide cells23Transport properties and phase stability of Ni-doped Pr0.6Ba0.4FeO3–δ as potential symmetrical electrodes for proton-conducting electrochemical cells16Innovative advances and challenges in solid oxide electrolysis cells: Exploring surface segregation dynamics in perovskite electrodes45Incorporating high acidity cations in Co-free BiFeO 3 -based air electrodes for enhancing their electrocatalytic activity and durability in reversible solid oxide cells3Effects of the Ni-Fe support microstructure on the electrochemical performance of the metal-supported solid oxide fuel cell9B-site high valence cation co-doping boosts fast oxygen kinetics in a cobalt-free perovskite air electrode for reversible solid oxide cells10CO2 Electrolysis Using Metal-Supported Solid Oxide Cells with Infiltrated Pr0.5Sr0.4Mn0.2Fe0.8O3−δ Catalyst0Tailoring barium doped cobalt-free nanocomposite cathodes for high-performance solid oxide fuel cells7Unraveling the microstructure and defect chemistry in Fluorine-doped cathode for a Protonic solid oxide fuel cell19Effect of Steam on Ethane Electro-oxidative Dehydrogenation to Ethylene1Electrical properties of high-entropy oxides (La0.2Ba0.2Cu0.2Sn0.2Ni0.2)3O41In situ growth of Cu0-modified oxynitride for optimized photocatalytic nitric oxide oxidation12Rare-Earth-Element-Free Ferrite Cathode for Protonic Solid Oxide Fuel Cells2Thermomechanical behavior of promising mixed ion-electron conductors based on co-doped barium ferrite3Nanostructured fuel electrodes for low-temperature proton- and oxygen-ion-conducting solid oxide cells28Engineering the one-pot synthesized Ba(Ce,Fe)O3-based composites as triple-conducting electrodes for solid oxide electrochemical cell applications15Advances in Nanostructured Electrodes for Solid Oxide Cells by Infiltration or Exsolution9Characterization and testing of strontium titanium ferrite-based solid oxide cells for reversible and co-electrolysis operation6Investigating reduction and oxidation of La0.72Sr0.18Fe0.9Ni0.1O3– δ as a Co-free perovskite electrode for symmetrical solid oxide cells3Advances in high-temperature solid oxide electrolysis technology for clean hydrogen and chemical production: materials, cells, stacks, systems and economics38Recent advances and future prospects in exsolution technology for solid oxide cells20Bio-driven Fe bond restructuring in bio-iron systems enhances electron transfer for chain elongation15Oxygen-ionic transport of (Pr,Ba)FeO3-based perovskite materials: Results from oxygen permeability experiments7Theoretical and experimental design for Experiencing High-end oxygen reduction activity in Al and Mn substituted CoFe2O4 cathode for SOFCs4Doping design strategies of proton-conducting perovskite oxides: A brief compositional map23Dual-engineering of sulfur, oxygen co-doping and defective carbon structure boosts highly efficient hydrogen peroxide electrosynthesis3Design of Cu-containing (Pr,Ba)FeO3-based perovskite electrodes for protonic ceramic electrochemical cells4Ca3Co4O9+δ with an unusual crystal structure as a basis of modernized oxygen electrodes for solid oxide fuel and electrolysis cells7Spin-State Tuning in PrFeO3-δ Perovskite for High-Temperature Oxygen Evolution Reaction21Entropy-Enhancing Strategy Enables Highly Efficient Pt Utilization for High-Temperature H 2 O–CO 2 Coelectrolysis2Potential reduction-induced fast exsolution of hyperfine nanoparticles afford highly active CO2 reduction reaction11Medium entropy design of the cobalt-free perovskite La0.25Ba0.25Sr0.25Ca0.25FeO3-δ as a cathode for IT-SOFCs3Electrochemical and microstructure study of ceramic composite based on BaCo0.4Fe0.4Zr0.2 O 3 − δ : BaZr0.7Ce0.2Y0.1O 3 − δ as a steam electrode interlayer in proton-conducting electrolysis cells3Unraveling the Evolution and Regulation Mechanisms of Reversible Exsolution in Perovskite‐Based Nanoparticles20Advancements and Challenges in Iron Oxide and Ferrites Materials for Solid Oxide Fuel Cells: A Comprehensive Review2Enhanced CO2 electrolysis via H2/CH4 assistance in a symmetric solid oxide electrolysis cell with an alloy-perovskite composite electrode0Cr adsorption and diffusion on LSCF surface: a first-principles study0Oxygen exchange kinetics of BaFeO3– modified with Ce and/or Y: oxygen isotope exchange and pressure relaxation4Recent Development and Modification of Perovskite‐Based CO 2 Electrolysis Solid Oxide Electrolysis Cell Cathode9Hierarchically Oriented Porous Nickel Metal Supported Solid Oxide Fuel Cells Prepared by Phase Inversion Co-Tape Casting Technique5Compatibility of NiO-SDC and NiO-Fe Anodes with Samarium-Doped Ceria Carbonate (SDCC) Electrolyte Intermediate-Temperature Solid Oxide Fuel Cells0Effect of Partial Fe-Substitution by Y and/or Ce in BaFeO3-Based Oxides on Oxygen Diffusion2Enhanced redox stability and electrochemical performance of Ni-modified Sr2FexMo2-xO6-δ electrodes for reversible solid oxide cells2Synergistic engineering and sintering-induced tuning of Al Sn co-doped Zn/Co ferrites for integrated hydroelectric and supercapacitive energy systems14N-Doped-Induced Local Covalency Elevation for Enhancing Cathodic Performance of Solid Oxide Electrolysis Cells5A-site high-entropy engineering enables a cobalt-free perovskite air electrode with exceptional activity and durability for reversible solid oxide cells0Solid oxide fuel cells using iron oxide-based materials0Synergistic anion–cation co-doping in perovskite as a bifunctional cathode for high-performance reversible solid oxide cells0CuxNiy/CeO2 catalyst for CO2 reduction in a creative CO2/H2 solid oxide fuel cell1Synergistic Dual‐Site Modulation Enabling High‐Performance Cobalt‐Free Perovskite Cathodes for Intermediate‐Temperature Solid Oxide Fuel Cells1Cu-induced low-temperature co-exsolution of bimetallic nanoparticles and their performance in high-temperature CO2 electrolysis3In Situ Measurement of Oxygen Vacancy Dynamics and Surface Exchange Reactions in Oxide Electrode under Solid Electrochemical Cell Operating Conditions3Advancing CO2 electrolyzers from laboratory to industrial scale9Controlled exsolution-dissolution in double perovskites enables symmetrical-capable high-performance SOFC electrodes4Modulating Oxygen Activity via Cation Doping for Efficient High-Temperature Carbon Dioxide Electrolysis4In Situ Exsolved Ru and Ni Bimetallic Nanoparticles on Pr 0.7 Sr 0.3 CrO 3 Boost the H 2 Oxidation and Production in the Reversible Solid Oxide Fuel Cell0Dimensionality and Compositional Effects on Sr–Fe-Based Ruddlesden–Popper Oxides for Oxygen Catalysis2Engineering the artificial carbon cycle via tandem strategies and cross-scale integration in electrocatalytic CO2 reduction0Ru‐Doping‐Induced Dual‐Functionality in La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3‐δ : Enhancing Efficient Multi‐Fuels Oxidation and Suppressing Sr Segregation for Robust Symmetric Solid Oxide Cells1Fluorine-enhanced catalytic performance and surface stability in Fe-based double perovskite cathodes for solid oxide fuel cells2Compositional modulation of high-entropy (La, Pr, Ba, Sr, Ca)FeO3-δ cathodes toward enhanced SOFC performance0Modification strategies for fuel electrodes in solid oxide electrolysis cells: Co-electrolysis of CO2/H2O to value-added chemicals0Tailoring triple-conductive properties of cobalt-free BaFe0.9Y0.1O3-δ cathode via Ni doping toward high-performance proton ceramic fuel cells1Boron-functionalized ferrite nanocomposites for water remediation: A mechanism-guided critical review with integrated reliability–practicality scoring0Impedance analysis of rGO-integrated LaFeO3 perovskite materials for efficient energy applications0Rational A‐Site Multi‐Cation Design Enables Durable Fe‐Based Perovskite Air Electrodes for Fast Oxygen Reduction0Sr-doping induces lattice modulation in perovskite for enhanced reversible solid oxide cell performance0Durability-driven advanced energy materials engineering of solid oxide electrolysis cells and stacks0

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  2. Phase transition with in situ exsolution nanoparticles in the reduced Pr 0.5 Ba 0.5 Fe 0.8 Ni 0.2 O 3− δ electrode for symmetric solid oxide cells

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  4. Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells

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  7. Structural Features and Defect Equilibrium in Cubic PrBa1−xSrxFe2O6−δ

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  8. Oxidative Strong Metal–Support Interaction Induced by an Amorphous TiOx Seed Layer Boosts the Electrochemical Performance and High-Temperature Durability of Pt Nanocatalysts

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  9. Construction of anodic electron transfer chain based on CuCl2/TiOSO4 synergetic mediators for highly efficient conversion of biomass wastes into electricity at low temperature

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  10. Coke-resistant ferrite anode decorated with in-situ exsolved ceria for carbonaceous fuel oxidation

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  14. Defect equilibrium and charge transport in R0.25Sr0.75FeO3−δ (R = La, Nd, Y, Ho): The effect of cation type

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  17. Perovskite Manganite Materials: Recent Advancements and Challenges as Cathode for Solid Oxide Fuel Cell Applications

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  19. Tantalum doped La 0.6 Sr 0.4 FeO 3− δ electrodes for symmetrical proton conducting solid oxide fuel cells

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  31. Influence of synthesis temperature on oxygen exchange behavior of electrode material PrBaFe2O6−

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  32. Recent progress in electrolyser control technologies for hydrogen energy production: A patent landscape analysis and technology updates

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  33. In Situ Generation of Pseudorutile Oxide as the Cathode for Direct Electrolysis of CO2

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  34. Fluorine doped non-perovskite-type Fe2TiO5 oxide without alkaline earth elements as cathode for efficient CO2 electrolysis

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  35. An efficient and durable solid oxide fuel cell integrated with coal gasification system

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  36. Physicochemical analysis of infiltrated cathode symmetric cells for intermediate temperature SOFCs

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  37. High La/Sr ratio in La0.67Sr0.33Fe0.67Ti0.33O3-δ cathode induced a controlled Fe0 exsolution for CO2 electrolysis

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  40. Revealing the Reaction Mechanism of CO2/H2O Coelectrolysis on Perovskite-Based Cathode Materials

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  41. Electrochemical performance of iron doped lanthanum strontium chromites as fuel electrodes in high temperature solid oxide cells

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  42. Influence of Transition Metal Elements on Ni Migration in Solid Oxide Cell Fuel Electrodes

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  43. Strontium doped Fe-based porous carbon for highly efficient electrocatalytic ORR and MOR reactions

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  44. Cu doping enhanced the performance of BaFe0.8Zr0.1Y0.1O3-δ cathode for a proton-conducting solid oxide fuel cell at low temperature

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  45. On Fe-based perovskite electrodes for symmetrical reversible solid oxide cells – A review

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