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RESEARCH PAPER · Acta chimica slovenica · 2016

The Chemical Capacitance as a Fingerprint of Defect Chemistry in Mixed Conducting Oxides

Jürgen Fleig, Alexander Schmid, Ghislain M. Rupp, Christoph Slouka, Edvinas Navickas, Lukas Andrejs, Herbert Hutter, Lukas Volgger, Andreas Nenning

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The Chemical Capacitance as a Fingerprint of Defect Chemistry in Mixed Conducting OxidesOriginalInfluence of the electrode/electrolyte interface structure on the performance of Pr 0.8 Sr 0.2 Fe 0.7 Ni 0.3 O 3-δ as Solid Oxide Fuel Cell cathode15Characterisation of La0.6Sr0.4Co0.2Fe0.8O3-δ – Ba0.5Sr0.5Co0.8Fe0.2O3-δ composite as cathode for solid oxide fuel cells34Thin-film nano-thermogravimetry applied to praseodymium-cerium oxide films at high temperatures10The Chemical Evolution of the La0.6Sr0.4CoO3−δ Surface Under SOFC Operating Conditions and Its Implications for Electrochemical Oxygen Exchange Activity106Low oxygen partial pressure increases grain boundary ion conductivity in Gd-doped ceria thin films21The Relation of Microstructure, Materials Properties and Impedance of SOFC Electrodes: A Case Study of Ni/GDC Anodes75Hydroxylation and Cation Segregation in (La0.5Sr0.5)FeO3−δ Electrodes30Novel Sample-Stage for Combined Near Ambient Pressure X-ray Photoelectron Spectroscopy, Catalytic Characterization and Electrochemical Impedance Spectroscopy34A mixed ion-electron conducting carbon nanotube ionogel to efficiently harvest heat from both a temperature gradient and temperature fluctuation54Ca2Fe1.95Mg0.05O5: Innovative low cost cathode material for intermediate temperature solid oxide fuel cell13Exploring point defects and trap states in undoped SrTiO3 single crystals26Mass and Charge Transport in Li1−δCoO2 Thin Films─A Complete Set of Properties and Its Defect Chemical Interpretation12Electrode-Supported Protonic Ceramic Electrolysis Cells for Electrochemically Promoted Ammonia Synthesis at Intermediate Temperatures21Identifiability of the mechanisms governing the reaction kinetics of MIEC electrodes in solid oxide cells18Selective photoelectrocatalytic CO2 reduction to ethanol using nanotubular oxides grown on metastable Ti-Cu alloy15Rapid mapping of electrochemical processes in energy-conversion devices69Mechanistic Insights into Oxygen Exchange in Mixed Ionic-Electronic Conductors: A Current–Voltage Study6Reducibility, adsorption energies, surface acidity – fundamental material properties for fast oxygen exchange10Transforming Inert Interfaces into Catalytic Sites: Ceria-based Interlayers for Highly Efficient and Reversible Solid Oxide Cells0Understanding the degradation mechanisms of Ba-based double perovskite electrodes for solid oxide electrochemical cells6In situ NAP-XPS and electrochemical impedance characterisation of La0.31Sr0.58Ti0.97Ni0.03O3-δ thin film model electrodes2When ions are in charge: Generalized ionic impedance spectroscopy for characterizing energy materials and devices2Visualising redox-driven metal–oxide interface dynamics in Ni/GDC electrodes via in situ Auger–Meitner electron microscopy0Quantifying Chemical Capacitance and Diffusion Coefficients in Hydrogenated La 0.6 Sr 0.4 FeO 3– δ via Operando Spectro-Electrochemical Characterizations1

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24 direct citing papers saved.

  1. Influence of the electrode/electrolyte interface structure on the performance of Pr 0.8 Sr 0.2 Fe 0.7 Ni 0.3 O 3-δ as Solid Oxide Fuel Cell cathode

    Electrochimica Acta · 2017-03-27

    Alice Giuliano, Clément Nicollet, Sébastien Fourcade, Fabrice Mauvy, Maria Paola Carpanese, Jean‐Claude Grenier

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  2. Characterisation of La0.6Sr0.4Co0.2Fe0.8O3-δ – Ba0.5Sr0.5Co0.8Fe0.2O3-δ composite as cathode for solid oxide fuel cells

    Electrochimica Acta · 2017-04-19

    Alice Giuliano, Maria Paola Carpanese, Marco Panizza, Giacomo Cerisola, Davide Clematis, Antonio Barbucci

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  3. Thin-film nano-thermogravimetry applied to praseodymium-cerium oxide films at high temperatures

    Applied Physics Letters · 2018-05-21

    Sebastian Schröder, Holger Fritze, Sean R. Bishop, Di Chen, Harry Louis Tuller

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  4. The Chemical Evolution of the La0.6Sr0.4CoO3−δ Surface Under SOFC Operating Conditions and Its Implications for Electrochemical Oxygen Exchange Activity

    Topics in Catalysis · 2018-10-20

    Alexander Karl Opitz, Christoph Rameshan, Markus Kubicek, Ghislain M. Rupp, Andreas Nenning, Thomas Götsch, Raoul Blume, Michael Hävecker, Axel Knop‐Gericke, Günther Rupprechter, Bernhard Klötzer, Jürgen Fleig

    Read original paper ↗ ·

  5. Low oxygen partial pressure increases grain boundary ion conductivity in Gd-doped ceria thin films

    Journal of Physics Energy · 2019-08-30

    Andreas Nenning, Alexander Karl Opitz

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  6. The Relation of Microstructure, Materials Properties and Impedance of SOFC Electrodes: A Case Study of Ni/GDC Anodes

    Energies · 2020-02-22

    Andreas Nenning, Cornelia Bischof, Jürgen Fleig, Martin Bram, Alexander Karl Opitz

    Read original paper ↗ ·

  7. Hydroxylation and Cation Segregation in (La0.5Sr0.5)FeO3−δ Electrodes

    Chemistry of Materials · 2020-03-30

    Dawei Zhang, Michael L. Machala, Di Chen, Zixuan Guan, Hanshi Li, Slavomír Nemšák, Ethan J. Crumlin, Hendrik Bluhm, William C. Chueh

    Read original paper ↗ ·

  8. Novel Sample-Stage for Combined Near Ambient Pressure X-ray Photoelectron Spectroscopy, Catalytic Characterization and Electrochemical Impedance Spectroscopy

    Crystals · 2020-10-17

    Raffael Rameshan, Andreas Nenning, Johannes Raschhofer, Lorenz Lindenthal, Thomas Ruh, Harald Summerer, Alexander Karl Opitz, Tobias Martin Huber, Christoph Rameshan

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  9. A mixed ion-electron conducting carbon nanotube ionogel to efficiently harvest heat from both a temperature gradient and temperature fluctuation

    Journal of Materials Chemistry A · 2021-01-01

    Hanlin Cheng, Shizhong Yue, Qiujian Le, Qi Qian, Jianyong Ouyang

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  10. Ca2Fe1.95Mg0.05O5: Innovative low cost cathode material for intermediate temperature solid oxide fuel cell

    International Journal of Hydrogen Energy · 2021-05-28

    Enrico Squizzato, Giovanni Carollo, Antonella Glisenti

    Read original paper ↗ ·

  11. Exploring point defects and trap states in undoped SrTiO3 single crystals

    Journal of the European Ceramic Society · 2021-10-19

    Matthäus Siebenhofer, Federico Baiutti, Juan de Dios Sirvent, Tobias Martin Huber, Alexander Viernstein, Stefan Smetaczek, Christopher Herzig, Maciej Oskar Liedke, Maik Butterling, Andreas Wagner, Eric Hirschmann, Andreas Limbeck, Albert Tarancón, Jürgen Fleig, Markus Kubicek

    Read original paper ↗ ·

  12. Mass and Charge Transport in Li1−δCoO2 Thin Films─A Complete Set of Properties and Its Defect Chemical Interpretation

    Chemistry of Materials · 2022-11-21

    Andreas Ewald Bumberger, Claudia Steinbach, Joseph Ring, Jürgen Fleig

    Read original paper ↗ ·

  13. Electrode-Supported Protonic Ceramic Electrolysis Cells for Electrochemically Promoted Ammonia Synthesis at Intermediate Temperatures

    ACS Omega · 2023-10-19

    Moe Okazaki, Junichiro Otomo

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  14. Identifiability of the mechanisms governing the reaction kinetics of MIEC electrodes in solid oxide cells

    Electrochimica Acta · 2023-10-28

    Liam Yasin, A. Atkinson, Samuel J. Cooper, Antonio Bertei

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  15. Selective photoelectrocatalytic CO2 reduction to ethanol using nanotubular oxides grown on metastable Ti-Cu alloy

    Chemical Engineering Journal · 2023-11-04

    Juliana de Almeida, Stella Hoffman Câmara, Rodnei Bertazzoli, Krishnan Rajeshwar, R.A.G. Silva, Christiane de Arruda Rodrigues

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  16. Rapid mapping of electrochemical processes in energy-conversion devices

    Joule · 2024-05-24

    Jake D. Huang, Charlie Meisel, Neal P. Sullivan, Andriy Zakutayev, Ryan O’Hayre

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  17. Mechanistic Insights into Oxygen Exchange in Mixed Ionic-Electronic Conductors: A Current–Voltage Study

    Chemistry of Materials · 2024-11-19

    Di Chen, Zixuan Guan, Hongyang Su, Wenle Yan, C.H. Liu, Hanshi Li, Dawei Zhang, William C. Chueh

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  18. Reducibility, adsorption energies, surface acidity – fundamental material properties for fast oxygen exchange

    Journal of Materials Chemistry A · 2025-01-01

    Matthäus Siebenhofer, Filip Grajkowski, Clément Nicollet, Bilge Yildiz, Jürgen Fleig, Markus Kubicek

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  19. Transforming Inert Interfaces into Catalytic Sites: Ceria-based Interlayers for Highly Efficient and Reversible Solid Oxide Cells

    SSRN Electronic Journal · 2025-01-01

    Jingle Wang, HoLam Tang, Yuhao Wang, Kaichuang Yang, Zhe Shen, Mengwei Yuan, Zhengjian Chen

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  20. Understanding the degradation mechanisms of Ba-based double perovskite electrodes for solid oxide electrochemical cells

    Chemical Engineering Journal · 2025-01-18

    Jinsil Lee, Taeyun Kim, Hyeon Jin Lee, Kyung Joong Yoon, Jongho Lee, Jong Hoon Joo

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  21. In situ NAP-XPS and electrochemical impedance characterisation of La0.31Sr0.58Ti0.97Ni0.03O3-δ thin film model electrodes

    Journal of Power Sources · 2025-06-06

    Mait Ainsar, Kuno Kooser, Margus Kodu, Glen Kelp, Aile Tamm, Tanel Käämbre, Priit Möller, Tavo Romann, Michael Hävecker, Thomas Götsch, Gunnar Nurk

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  22. When ions are in charge: Generalized ionic impedance spectroscopy for characterizing energy materials and devices

    Solid State Ionics · 2025-07-25

    Paul Nizet, Francesco Maria Chiabrera, Àlex Morata, Albert Tarancón

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  23. Visualising redox-driven metal–oxide interface dynamics in Ni/GDC electrodes via in situ Auger–Meitner electron microscopy

    Journal of Materials Chemistry A · 2026-01-01

    Christian Melcher, Andreas Nenning, Stanislaus Breitwieser, Kirsten Rath, Luca Balice, Jonathan Rollenitz, Martin Bram, Christoph Rameshan, Alexander Karl Opitz

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  24. Quantifying Chemical Capacitance and Diffusion Coefficients in Hydrogenated La 0.6 Sr 0.4 FeO 3– δ via Operando Spectro-Electrochemical Characterizations

    Nano Letters · 2026-01-26

    Bin Zhao, Luhan Wei, Jieping Zheng, Ying Lu, Haowen Chen, Kaichuang Yang, Qiyang Lu

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