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RESEARCH PAPER · Materials Advances · 2021

Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cells

Andreas Nenning, Manuel Holzmann, Jürgen Fleig, Alexander Karl Opitz

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Excellent kinetics of single-phase Gd-doped ceria fuel electrodes in solid oxide cellsOriginalOperando observation of patterned nickel - gadolinium doped ceria solid oxide fuel cell anode31How the surface state of nickel/gadolinium-doped ceria cathodes influences the electrochemical performance in direct CO2 electrolysis16Effects of mass fraction of La0.9Sr0.1Cr0.5Mn0.5O3-δ and Gd0.1Ce0.9O2-δ composite anodes for nickel free solid oxide fuel cells20Deconvolution of Gas Diffusion Polarization in Ni/Gadolinium-Doped Ceria Fuel Electrodes49Current understanding of ceria surfaces for CO2 reduction in SOECs and future prospects – A review69Combining electrochemical and quantitative elemental analysis to investigate the sulfur poisoning process of ceria thin film fuel electrodes3Doped ceria with exsolved Fe 0 nanoparticles as a Sr-free cathode for CO 2 electrolysis in SOECs at reduced temperatures38Operational Aspects of a Perovskite Chromite-Based Fuel Electrode in Solid Oxide Electrolysis Cells (SOEC)22Highly connected oxygen ion conduction pathways in anode functional layer for high performance solid oxide fuel cells20A single-phase gadolinium-doped ceria cathode for highly efficient CO 2 electrolysis18Exsolved catalyst particles as a plaything of atmosphere and electrochemistry11Standardized microstructure characterization of SOC electrodes as a key element for Digital Materials Design5Unravelling the role of dopants in the electrocatalytic activity of ceria towards CO 2 reduction in solid oxide electrolysis cells8Synthesis and characterisation of a ceria-based cobalt-zinc anode nanocomposite for low-temperature solid oxide fuel cells (LT-SOFCs)21Application of finite Gaussian process distribution of relaxation times on SOFC electrodes30Performance, electrochemical process analysis and degradation of gadolinium doped ceria as fuel electrode material for solid oxide electrolysis cells41Proton-coupled electron transfer at SOFC electrodes8Ni-free CeO2-ZrO2-Sc2O3 nanostructured fuel electrodes for high performance solid oxide cells5Perovskite/Ruddlesden-Popper composite fuel electrode of strontium-praseodymium-manganese oxide for solid oxide cells: An alternative candidate15CeO2-ZrO2-Sm2O3 anodes for intermediate temperature-solid oxide fuel cells2DRT analysis and transmission line modeling of ceria based electrodes for solid oxide cells29Microstructural and electrochemical properties of Ni-impregnated GDC10 and 8YSZ freeze tape cast scaffolds as fuel electrodes for solid oxide cells17Status and progress of metal-supported solid oxide fuel cell: Towards large-scale manufactory and practical applications65[Electrochemical Impedance Analysis of Lsm Air Electrodes in Electrolyte Supported Solid Oxide Cells]0Effective transport properties of porous composites applied to MIEC SOC electrodes4Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles3Investigation of Space Charge Effects on CO2 Electrocatalytic Reduction on Gd-Doped Ceria Via Scanning Kelvin Probe and Model-Based Bayesian Analysis0Fe‐Doped Ceria‐Based Ceramic Cathode for High‐Efficiency CO2 Electrolysis in Solid Oxide Electrolysis Cell12Gadolinium Doped Ceria as Nickel–Free Fuel Electrode in High Temperature CO2‐Electrolysis13Electrochemical Characterization of Nickel/Gadolinia Doped Ceria Fuel Electrodes under H2/H2O/CO/CO2-Atmospheres10Electrocatalysis in Solid Oxide Fuel Cells and Electrolyzers141The CO2 electrolysing mechanism in single-phase mixed-conducting cathode of solid oxide cell0New Insights into the Hydrogen Evolution Mechanism near the Ni/YSZ Triple Phase Boundary during Steam Electrolysis: A Patterned Model Electrode Study2Operando studies on solid oxide ceria electrodes during CO2 electroreduction12Electrochemical performance and durability of high-temperature solid oxide electrolysis cells with SFM and SFM-GDC fuel electrodes for hydrogen and syngas production10The dark side of metal exsolution: a combined in situ surface spectroscopic and electrochemical study on perovskite-type cathodes for high-temperature CO 2 electrolysis13Ni-doping strategy for perovskite anodes towards high-performance ammonia-fueled SOFCs33Online Coupling High‐Temperature Electrolysis with Carbonylation Reactions: A Powerful Method for Continuous Carbon Dioxide Utilization1Online Coupling High‐Temperature Electrolysis with Carbonylation Reactions: A Powerful Method for Continuous Carbon Dioxide Utilization7Pushing the envelope of physical vapor deposited thin-film based solid oxide fuel cells for 500 °C operation: Securing 1 W cm−2 performance, 1000 h stability, scale up to 15 W power, and associated limitations6Electrochemical Impedance Analysis and Modeling of Electrolyte Supported Solid Oxide Fuel Cells with LSM Air Electrodes3A simple compression sealing method for planar single-cell SOFC testing2Constrained flash sintering of gadolinium‐doped ceria thin layers0Ni-free single GDC anode deposited on YSZ porous skeleton via hydrothermal treatment for high humidity SOFC operation8Investigating viability of low temperature co-sintering to produce Ni-YSZ supported solid oxide electrolysis cells with a Ni-GDC active layer11Understanding the Roles of Double- and Triple-Phase Boundaries in High-Temperature CO 2 Electrolysis1Investigating Oxides by Electrochemical Projection of the Oxygen Off‐Stoichiometry Diagram Onto a Single Sample0Bottom-up redox state engineering of Ni/GDC thin-film anodes for carbon tolerant syngas-fueled SOFCs1Exploring the effect of a GDC adhesion layer on performance and durability of Ni-GDC fuel electrode supported solid oxide electrolysis cells0Lattice doping and NiO synergistic decoration for enhanced CO 2 electrolysis in solid oxide electrolysis cells0Visualising redox-driven metal–oxide interface dynamics in Ni/GDC electrodes via in situ Auger–Meitner electron microscopy0Influence of defect interactions on the electrical conductivity of gadolinium-doped ceria0Impact of Ni-GDC fuel electrode microstructure on cell performance in fuel electrode-supported solid oxide cells2Architecture-engineered low-Ni anodes based on dendritic GDC support and Ru nanofiber catalysts for durable SOFCs0Unveiling anodic reaction–diffusion coupling in metal-supported SOFC single cells under direct-ammonia operation via quantitative DRT and CFD analysis0Exploring the effect of a GDC adhesion layer on the performance and durability of Ni-GDC fuel electrode supported solid oxide electrolysis cells1Closing the Carbon Loop: Continuous‐Flow Synthesis of N ‐Aroyl Sulfoximines via Electrochemical CO 2 Reduction0Quantification and deconvolution of gas diffusion and conversion losses in solid oxide single-cell testing0Advances in Ceria‐Based Fuel Electrodes for Solid Oxide Cells: Reaction Mechanisms, Performance, Stability, and Future Directions With Focus on Nickel–Gadolinium‐Doped Ceria1Coupled A-site regulation and multicomponent B-site substitution in SrFeO3−δ-derived perovskites for active and durable oxygen reduction0

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  1. Operando observation of patterned nickel - gadolinium doped ceria solid oxide fuel cell anode

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  2. How the surface state of nickel/gadolinium-doped ceria cathodes influences the electrochemical performance in direct CO2 electrolysis

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    Dingkai Chen, Dimitrios K. Niakolas, Vasiliki Papaefthimiou, Evangelia T. Ioannidou, Stylianos G. Neophytides, Spyridon Zafeiratos

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  3. Effects of mass fraction of La0.9Sr0.1Cr0.5Mn0.5O3-δ and Gd0.1Ce0.9O2-δ composite anodes for nickel free solid oxide fuel cells

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  4. Deconvolution of Gas Diffusion Polarization in Ni/Gadolinium-Doped Ceria Fuel Electrodes

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  5. Current understanding of ceria surfaces for CO2 reduction in SOECs and future prospects – A review

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  6. Combining electrochemical and quantitative elemental analysis to investigate the sulfur poisoning process of ceria thin film fuel electrodes

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  7. Doped ceria with exsolved Fe 0 nanoparticles as a Sr-free cathode for CO 2 electrolysis in SOECs at reduced temperatures

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  8. Operational Aspects of a Perovskite Chromite-Based Fuel Electrode in Solid Oxide Electrolysis Cells (SOEC)

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  9. Highly connected oxygen ion conduction pathways in anode functional layer for high performance solid oxide fuel cells

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  10. A single-phase gadolinium-doped ceria cathode for highly efficient CO 2 electrolysis

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  11. Exsolved catalyst particles as a plaything of atmosphere and electrochemistry

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  12. Standardized microstructure characterization of SOC electrodes as a key element for Digital Materials Design

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  13. Unravelling the role of dopants in the electrocatalytic activity of ceria towards CO 2 reduction in solid oxide electrolysis cells

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  14. Synthesis and characterisation of a ceria-based cobalt-zinc anode nanocomposite for low-temperature solid oxide fuel cells (LT-SOFCs)

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  15. Application of finite Gaussian process distribution of relaxation times on SOFC electrodes

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  16. Performance, electrochemical process analysis and degradation of gadolinium doped ceria as fuel electrode material for solid oxide electrolysis cells

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  17. Proton-coupled electron transfer at SOFC electrodes

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  18. Ni-free CeO2-ZrO2-Sc2O3 nanostructured fuel electrodes for high performance solid oxide cells

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  19. Perovskite/Ruddlesden-Popper composite fuel electrode of strontium-praseodymium-manganese oxide for solid oxide cells: An alternative candidate

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  20. CeO2-ZrO2-Sm2O3 anodes for intermediate temperature-solid oxide fuel cells

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  21. DRT analysis and transmission line modeling of ceria based electrodes for solid oxide cells

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  22. Microstructural and electrochemical properties of Ni-impregnated GDC10 and 8YSZ freeze tape cast scaffolds as fuel electrodes for solid oxide cells

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  23. Status and progress of metal-supported solid oxide fuel cell: Towards large-scale manufactory and practical applications

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  24. [Electrochemical Impedance Analysis of Lsm Air Electrodes in Electrolyte Supported Solid Oxide Cells]

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  25. Effective transport properties of porous composites applied to MIEC SOC electrodes

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  27. Investigation of Space Charge Effects on CO2 Electrocatalytic Reduction on Gd-Doped Ceria Via Scanning Kelvin Probe and Model-Based Bayesian Analysis

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  28. Fe‐Doped Ceria‐Based Ceramic Cathode for High‐Efficiency CO2 Electrolysis in Solid Oxide Electrolysis Cell

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  32. The CO2 electrolysing mechanism in single-phase mixed-conducting cathode of solid oxide cell

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  36. The dark side of metal exsolution: a combined in situ surface spectroscopic and electrochemical study on perovskite-type cathodes for high-temperature CO 2 electrolysis

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