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RESEARCH PAPER · Inorganic Chemistry · 2020

Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

Zenghui Yue, Xiaofeng Guo, Mei‐Ling Feng, Yue‐Jian Lin, Yu Ju, Xiao Lin, Zhi‐Hui Zhang, Xiao-Jing Guo, Jian Hung Lin, Yuying Huang, Jian‐Qiang Wang

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Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular ComplexesOriginalSupramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations51Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV11Structural Complexity and Magnetic Orderings in a Large Family of 3d–4f Heterobimetallic Sulfates10Bridging the Transuranics with Uranium(IV) Sulfate Aqueous Species and Solid Phases13Decisive Role of 5f-Orbital Covalence in the Structure and Stability of Pentavalent Transuranic Oxo [M6O8] Clusters11Tuning of the Network Dimensionality and Photoluminescent Properties in Homo- and Heteroleptic Lanthanide Coordination Polymers21Impact of Noncovalent Interactions on the Structural Chemistry of Thorium(IV)-Aquo-Chloro Complexes10Effect of Background Electrolyte Composition on the Interfacial Formation of Th(IV) Nanoparticles on the Muscovite (001) Basal Plane8Recent advances in uranium-containing polyoxometalates59Th(IV) Bromide Complexes: A Homoleptic Aqua Ion and a Novel Th(H2O)4Br4 Structural Unit2Solvent Extraction and Conformation Rigidity: Actinide(IV) and Actinide(VI) Come Together11Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers8Alkali Counterion-Dependent Crystallization of Uranium(IV)–Chloro Structural Units6Synthesis and Crystal Structure of New Uranium(IV) Sulfate K(Al(H2O)6)3[U2(SO4)9]0Mild Hydrothermal Synthesis, Crystal Structure, and Spectroscopic Analysis of a Highly Luminescent Uranyl Sulfate, K(UO 2 )SO 4 F1

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  1. Supramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations

    Journal of the American Chemical Society · 2020-04-22

    Ian Colliard, Gregory W. Morrison, Hans‐Conrad zur Loye, May Nyman

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  2. Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV

    Chemistry - A European Journal · 2020-07-01

    Ian Colliard, May Nyman

    Read original paper ↗ ·

  3. Structural Complexity and Magnetic Orderings in a Large Family of 3d–4f Heterobimetallic Sulfates

    Inorganic Chemistry · 2020-07-29

    Huangjie Lu, Kariem Diefenbach, Zi‐Jian Li, Hongliang Bao, Xiaofeng Guo, Jian‐Qiang Wang, Thomas E. Albrecht‐Schmitt, Jian Hung Lin

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  4. Bridging the Transuranics with Uranium(IV) Sulfate Aqueous Species and Solid Phases

    Inorganic Chemistry · 2020-11-19

    Ian Colliard, Clément Falaise, May Nyman

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  5. Decisive Role of 5f-Orbital Covalence in the Structure and Stability of Pentavalent Transuranic Oxo [M6O8] Clusters

    Inorganic Chemistry · 2020-12-08

    Shu‐Xian Hu, Peng Zhang, Erli Lu, Ping Zhang

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  6. Tuning of the Network Dimensionality and Photoluminescent Properties in Homo- and Heteroleptic Lanthanide Coordination Polymers

    Inorganic Chemistry · 2020-12-15

    Zhaofa Zheng, Huangjie Lu, Yumin Wang, Hongliang Bao, Zi‐Jian Li, Guoping Xiao, Jian Hung Lin, Yuan Qian, Jian‐Qiang Wang

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  7. Impact of Noncovalent Interactions on the Structural Chemistry of Thorium(IV)-Aquo-Chloro Complexes

    Inorganic Chemistry · 2021-04-22

    Jennifer N. Wacker, Aaron D. Nicholas, Monica Vasiliu, Alexander C. Marwitz, Jeffery A. Bertke, David A. Dixon, Karah E. Knope

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  8. Effect of Background Electrolyte Composition on the Interfacial Formation of Th(IV) Nanoparticles on the Muscovite (001) Basal Plane

    The Journal of Physical Chemistry C · 2021-07-07

    Julia Neumann, Canrong Qiu, Peter J. Eng, S. Skanthakumar, L. Soderholm, Thorsten Stumpf, Moritz Schmidt

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  9. Recent advances in uranium-containing polyoxometalates

    Inorganic Chemistry Frontiers · 2022-01-01

    Guo‐Ping Yang, Ke Li, Changwen Hu

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  10. Th(IV) Bromide Complexes: A Homoleptic Aqua Ion and a Novel Th(H2O)4Br4 Structural Unit

    Crystal Growth & Design · 2022-06-06

    Anamar Blanes Díaz, Orlando Stewart, Monica Vasiliu, Aaron D. Nicholas, Aphra V. Murray, Madeline C. Shore, David A. Dixon, Karah E. Knope

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  11. Solvent Extraction and Conformation Rigidity: Actinide(IV) and Actinide(VI) Come Together

    Inorganic Chemistry · 2022-12-14

    Nataliya E. Borisova, Alexandre M. Fedoseev, Галина Валерьевна Костикова, Petr Igorevich Matveev, Leonid Yu. Starostin, Marina Sokolova, Mariia V. Evsiunina

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  12. Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers

    CrystEngComm · 2024-12-13

    Thomas L. McCusker, Nicole A. Vanagas, Jennifer E. S. Szymanowski, Robert G. Surbella, Jeffery A. Bertke, Ana Arteaga, Karah E. Knope

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  13. Alkali Counterion-Dependent Crystallization of Uranium(IV)–Chloro Structural Units

    Inorganic Chemistry · 2025-06-12

    Madeline C. Shore, Jennifer N. Wacker, Pere Miró, Jeffery A. Bertke, Karah E. Knope

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  14. Synthesis and Crystal Structure of New Uranium(IV) Sulfate K(Al(H2O)6)3[U2(SO4)9]

    Journal of Structural Chemistry · 2026-01-01

    Yu. S. Pozgalova, Vasili Yu Grishaev, Kompanchenko A.A., D. O. Charkin, I.G. Tananaev, Sergey M. Aksenov

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  15. Mild Hydrothermal Synthesis, Crystal Structure, and Spectroscopic Analysis of a Highly Luminescent Uranyl Sulfate, K(UO 2 )SO 4 F

    Crystal Growth & Design · 2026-02-06

    Gopabandhu Panigrahi, Lakshani W. Masachchi, Mark D. Smith, Hans‐Conrad zur Loye

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