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RESEARCH PAPER · Chemistry of Materials · 2023

Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks

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Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building BlocksOriginalCentrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8A2Pb3[H2N(CH2COO)2]3Cl5 (A = K, Rb): Porous Crystals Constructed on [Pb3Cl5O6] Clusters with Comprehensive Nonlinear Optical Performance3A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage27Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response7K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3Crystal Structures, Phase Transition, and Optical Properties of Two Rare Earth Borate Fluorides: α- and β-BaGdBO3F26Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Cation regulation achieves symmetry breaking: from centrosymmetric M 2 Cs 2 B 10 O 17 (M = Na, K) to noncentrosymmetric Na 3 CsB 10 O 172[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1

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  1. Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

    Inorganic Chemistry · 2023-08-02

    Weiyi Wang, Xinyue Wang, Lu Xiong Xu, Die Zhang, Jiale Xue, Shuyao Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

    Read original paper ↗ ·
  2. Hydroxyl-Driven Enhanced Birefringence in Borophosphates

    Inorganic Chemistry · 2023-11-22

    Yang Xia, Wen-Bin Zhang, Xueting Pan, Xueling Hou, Shujuan Han

    Read original paper ↗ ·
  3. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  4. Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides

    The Journal of Physical Chemistry C · 2024-01-14

    Xueting Pan, Junben Huang, Yineng Huang

    Read original paper ↗ ·
  5. A2Pb3[H2N(CH2COO)2]3Cl5 (A = K, Rb): Porous Crystals Constructed on [Pb3Cl5O6] Clusters with Comprehensive Nonlinear Optical Performance

    Advanced Optical Materials · 2024-03-14

    Ya-Hui Zhu, Zuju Ma, Shuangcheng Li, Zilong Geng, Ruibiao Fu

    Read original paper ↗ ·
  6. A Noncentrosymmetric Metal‐Free Borophosphate: Achieving a Large Birefringence and Excellent Stability by Covalent‐Linkage

    Small · 2024-04-15

    Hui‐Li Zhang, Dong‐Xue Jiao, Xiaofei Li, Chao He, Xi‐Ming Dong, Kai Huang, Jinhua Li, Xing‐Tao An, Qi Wei, Guo‐Ming Wang

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  7. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  8. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·
  9. Ba2ScBSi2O9: A Mixed-Coordination Borosilicate with a Low B/Si Ratio Exhibiting Enhanced Second Harmonic Generation Response

    Inorganic Chemistry · 2024-08-21

    Ming Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·
  10. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  11. Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence

    Inorganic Chemistry · 2025-01-27

    Jiang Wu, Jiahao Jiao, Mayinuer Maimaiti, Ke Li, Jugong Zheng, Min Zhang

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  12. Crystal Structures, Phase Transition, and Optical Properties of Two Rare Earth Borate Fluorides: α- and β-BaGdBO3F2

    Inorganic Chemistry · 2025-03-10

    Yunjie Bai, Cheng Chen, Mingye Han, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·
  13. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  14. Cation regulation achieves symmetry breaking: from centrosymmetric M 2 Cs 2 B 10 O 17 (M = Na, K) to noncentrosymmetric Na 3 CsB 10 O 17

    Journal of Materials Chemistry C · 2025-12-18

    X. Ma, Jiafu Wang, Xiaona Li, Yabo Wu, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  15. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

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