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RESEARCH PAPER · Coordination Chemistry Reviews · 2025

Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

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Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic boratesOriginalTuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups3Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation1CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties0Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications1The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4氢键组装的新型紫外非线性光学晶体(R/S‑DACH)Mal·H2O的设计及性能研究(特邀)0Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals2Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1Breakthrough in High Quality LaBGeO 5 Crystal for Deep Ultraviolet Quasi-Phase Matching Application0K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals0Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect0Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0

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  1. Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures

    Dalton Transactions · 2025-12-04

    Shenghong Zeng, Mayinuer Maimaiti, Jinche Wu, Tingwen Han, Hui Chai, Fangfang Zhang, Min Zhang

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  2. Achieving Ultra‐High Optical Anisotropy via Structural Regulation and Coplanar Engineering of Extended π‐Conjugated [H 2–x C 3 N 3 S 3 ] (x = 1, 2) Groups

    Advanced Functional Materials · 2025-12-12

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  3. Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    S AN, Yaqi Jin, Wenhu Wang, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  4. CsB(OH) 4 (H 2 O) 2 and Na(NH 4 ) 2 B 10 O 16 OH(H 2 O): a hydroxylation modification strategy regulates the borate structures and optical properties

    Dalton Transactions · 2026-01-01

    Kelibinuer Wulamu, Ziting Yan, Dongdong Chu, Juanjuan Lu, Yanhui Zhang, Hong Du

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  5. Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications

    Chemical Communications · 2026-01-01

    Muhammad Mujahid Iqbal, Hussin Elkik, Changyou Liu, Aqsa Munawar, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  6. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  7. 氢键组装的新型紫外非线性光学晶体(R/S‑DACH)Mal·H2O的设计及性能研究(特邀)

    Chinese Journal of Lasers · 2026-01-01

    阚子钧 Kan Zijun, 李雷鸣 Li Leiming, 吴红萍 Wu Hongping, 张玉杰 ZHANG Yujie, 俞洪伟 Yu Hongwei, 吴以成 Wu Yicheng

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  8. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  9. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

    Advanced Optical Materials · 2026-04-25

    Juhui Cui, Feng Yu, Minqiang Gai

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  10. Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals

    Advanced Science · 2026-05-11

    Lingli Wu, Chensheng Lin, Bo Li, Huixin Fan, Lingfei Lv, Shunda Yang, Tao Yan, Min Luo

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  11. Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals

    Advanced Functional Materials · 2026-06-01

    Hangwei Jia, Yaqi Jin, Muhammad Arif, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  12. Breakthrough in High Quality LaBGeO 5 Crystal for Deep Ultraviolet Quasi-Phase Matching Application

    ACS Applied Materials & Interfaces · 2026-06-29

    Jiahao Wang, Lingfei Lv, Rongbing Su, Z G Zhu, Hongjiang Wu, Hongyuan Sha, Zujian Wang, Bin Su, Chao He

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  13. K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-07-02

    Jingjing Xu, Huili Zhang, Xuemei Shi, Xin Wen, Jingyao Lu, Jindong Chen, Chensheng Lin, Ning Ye, Guang Peng

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  14. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  15. Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals

    Science China Chemistry · 2026-07-13

    Juhui Cui, Minqiang Gai, Ke Li, Z L Yang, Xueling Hou, Shilie Pan, Miriding Mutailipu

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  16. Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs

    Chinese Journal of Chemistry · 2026-08-03

    Linsen Wang, Qianzhen Zhang, Ran An, Zhihua Yang, Yun Yang, Xueyan Wu

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  17. Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect

    Angewandte Chemie International Edition · 2026-08-11

    Hongyuan Sha, Dongling Yang, Lilin Yang, Fan Xiao, Xiaoming Yang, Lingfei Lv, Chao He, Zhihua Yang, Fangfang Zhang, Zujian Wang, Xifa Long

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  18. Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect

    Angewandte Chemie · 2026-08-11

    Hongyuan Sha, Dongling Yang, Lilin Yang, Fan Xiao, Xiaoming Yang, Lingfei Lv, Chao He, Zhihua Yang, Fangfang Zhang, Zujian Wang, Xifa Long

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  19. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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  20. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

    Bailin Chen, Yaqi Jin, Hucai Yang, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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