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RESEARCH PAPER · ChemistrySelect · 2021

An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals

Sekar Anand, M. Usha Rani, S. Kalainathan

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An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical CrystalsOriginalAnalysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4- N , N -dimethylamino-4- N -methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications22A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O4Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation5Investigation on the growth, structural, absorption and emission, mechanical, thermal and nonlinear behaviour of the schiff base 2-methoxy-N-[4-(dimethyl amino) benzylidene] aniline (2MDA) single crystal4Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity6Computationally-driven discovery of second harmonic generation in EuBa 3 (B 3 O 6 ) 3 through inversion symmetry breaking4Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Efficient second harmonic generation from nonlinear one-dimensional meta-grating metasurface under vertically incident pump laser excitation2Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications61Material synthesis, crystal structure, Hirshfeld surface and physicochemical characteristics Novel Stilbazolium crystal of 4-(2-(3-ethoxy-4-hydroxy-phenyl)-vinyl)-1-methyl pyridinium iodide (MEMPI) single crystal for NLO activity1Wide‐Bandgap RBa3(B3O6)3 (R = Nd, Sm, Tb, Dy, and Er) Single Crystals for Ultraviolet Nonlinear Optics6Thermal and mechanical properties of deep-ultraviolet light sources candidate materials BeGeN 2 by machine-learning molecular dynamics simulations8A Review of Extreme Ultraviolet Lithography and Its Future Development Trends1Exploring physicochemical traits of a novel DSDA single crystal grown via the fusion of new diphenylamine anion for optical limiting applications0Identifying Superior Alternatives for Deep-Ultraviolet LEDs under High Pressure0Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components2One-dimensional wide-bandgap semiconductor β-Ga 2 O 3 nanorods for high-performance solar-blind ultraviolet photodetectors1Sum-frequency generation of more than 50 W of deep-ultraviolet light at 266 nm in LBO crystals based on a spherical-aberration-compensated high-energy picosecond Nd:YVO 4 laser3NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence2Cation electronic structure governs Deep-UV nonlinear optical response in MB4O7 (M = Sn, Pb, Yb) Tetraborates: Lone pairs versus 4f electrons0Charge and structural flexibility of tartrate groups enable high-performance ultraviolet nonlinear optical crystals0

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  1. Analysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4- N , N -dimethylamino-4- N -methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications

    RSC Advances · 2022-01-01

    Anand Sekar, M. Usha Rani, S. Kalainathan, Ravi Shanker Babu

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  2. A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O

    Zeitschrift für anorganische und allgemeine Chemie · 2022-04-01

    Xinrui Yang, Xin Liu, Ling Chen, Li‐Ming Wu

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  3. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  4. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

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  5. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

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  6. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  7. SbI3·3S8: A Novel Promising Inorganic Adducts Crystal for Second Harmonic Generation

    Materials · 2023-01-27

    Tushar Kanti Das, Marcin Jesionek, Mirosława Kępińska, M. Nowak, Michalina Kotyczka-Morańska, Maciej Zubko, Jarosław Młyńczak, Krzysztof Kopczyński

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  8. Investigation on the growth, structural, absorption and emission, mechanical, thermal and nonlinear behaviour of the schiff base 2-methoxy-N-[4-(dimethyl amino) benzylidene] aniline (2MDA) single crystal

    Journal of Materials Science Materials in Electronics · 2023-03-01

    Balachandar Rajagopal Krishnamoorthy, S. Kalainathan, Anand Sekar, Senthil Kannan

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  9. Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

    ChemPhotoChem · 2023-07-25

    Anand Sekar, M. Usha Rani

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  10. Computationally-driven discovery of second harmonic generation in EuBa 3 (B 3 O 6 ) 3 through inversion symmetry breaking

    Optical Materials Express · 2023-10-23

    Jingyang He, Louis Alaerts, Yu Wang, Victor Trinquet, Suguru Yoshida, Hemant P. Yennawar, Victor Sanni, Romain Claes, Rowan R. Katzbaer, Evan Krysko, Saugata Sarker, Raymond E. Schaak, Gian‐Marco Rignanese, Geoffroy Hautier, Zhiqiang Q. Mao, Venkatraman Gopalan

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  11. Hydroxyl-Driven Enhanced Birefringence in Borophosphates

    Inorganic Chemistry · 2023-11-22

    Yang Xia, Wen-Bin Zhang, Xueting Pan, Xueling Hou, Shujuan Han

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  12. Efficient second harmonic generation from nonlinear one-dimensional meta-grating metasurface under vertically incident pump laser excitation

    Infrared Physics & Technology · 2023-11-23

    Dexian Yan, Cuicui Zhao, Yu Qiu, Xiangjun Li, Le Zhang, Jining Li

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  13. Advances in Solid-State Nonlinear Optical Materials: From Fundamentals to Applications

    ACS Applied Optical Materials · 2023-12-12

    Hafiz Zohaib Aslam, Joseph T. Doane, Michael T. Yeung, Georgiy Akopov

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  14. Material synthesis, crystal structure, Hirshfeld surface and physicochemical characteristics Novel Stilbazolium crystal of 4-(2-(3-ethoxy-4-hydroxy-phenyl)-vinyl)-1-methyl pyridinium iodide (MEMPI) single crystal for NLO activity

    Journal of Molecular Structure · 2024-08-17

    Nandhini Krishnan, S. Kalainathan

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  15. Wide‐Bandgap RBa3(B3O6)3 (R = Nd, Sm, Tb, Dy, and Er) Single Crystals for Ultraviolet Nonlinear Optics

    Advanced Optical Materials · 2024-08-31

    Saugata Sarker, Yu Wang, Caeli Benyacko, Yingdong Guan, Suguru Yoshida, Hemant P. Yennawar, Jingyang He, Zhiqiang Q. Mao, Venkatraman Gopalan

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  16. Thermal and mechanical properties of deep-ultraviolet light sources candidate materials BeGeN 2 by machine-learning molecular dynamics simulations

    Physical Review Materials · 2025-03-24

    Zhendong Li, Longwei Han, Tao Ouyang, Juexian Cao, Yongshen Yao, Xiaolin Wei

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  17. A Review of Extreme Ultraviolet Lithography and Its Future Development Trends

    Advances in Engineering Technology Research · 2025-07-28

    Jinhui Lai

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  18. Exploring physicochemical traits of a novel DSDA single crystal grown via the fusion of new diphenylamine anion for optical limiting applications

    Journal of Molecular Structure · 2025-08-18

    Anand Sekar, M. Usha Rani, Ravi Shanker Babu, Sashmitha Kumar, Vijaya Baskaran, Raji Vinayagamoorthy, Santhosh Nallakumar, Manohar Darla

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  19. Identifying Superior Alternatives for Deep-Ultraviolet LEDs under High Pressure

    The Journal of Physical Chemistry C · 2025-12-09

    Kapil Mandal, Subhas Ghosal, Sandeep K. Reddy, Balaram Dey, Kalipada Das

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  20. Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components

    Chemical Communications · 2026-01-01

    马祖驹, Zehui Fang, Zhenlong Xie, Jia-Xiang Zhang, Hua Lin

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  21. One-dimensional wide-bandgap semiconductor β-Ga 2 O 3 nanorods for high-performance solar-blind ultraviolet photodetectors

    Nanoscale · 2026-01-01

    Jiateng Zhang, Zixuan Cheng, Yong Wang, Dingyi Yang, Biao Wu, Cheng Zhang, Ming Li, Zhao Lu, Xuetao Gan, Yan Liu, Yue Hao, Genquan Han

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  22. Sum-frequency generation of more than 50 W of deep-ultraviolet light at 266 nm in LBO crystals based on a spherical-aberration-compensated high-energy picosecond Nd:YVO 4 laser

    Optics Express · 2026-02-04

    Yang Janet Liu, Jianglin Guan, Xiaoyan Qiu, Bin Liu, Yuhong Shen, Junyang Dong, Yiwen Jin, Yichao Peng, S J Wang, Chong Liu

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  23. NH 4 B 3 PO 6 (OH) 3 : A Hydroxyborophosphate with Short DUV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-27

    Bailin Chen, Yansheng Jiang, Hangwei Jia, Shuai An, Xueling Hou, Shilie Pan

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  24. Cation electronic structure governs Deep-UV nonlinear optical response in MB4O7 (M = Sn, Pb, Yb) Tetraborates: Lone pairs versus 4f electrons

    Computational Condensed Matter · 2026-06-16

    M. Naveed-Ul-Haq

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  25. Charge and structural flexibility of tartrate groups enable high-performance ultraviolet nonlinear optical crystals

    Chinese Journal of Structural Chemistry · 2026-09-01

    Hongbo Huang, Yinsong Zhao, Yining Wang, Jiaxing Wang, Hanyu Chen, Daqing Yang, Ying Wang, Bingbing Zhang

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