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RESEARCH PAPER · Chemistry of Materials · 2017

Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction Systems

Yunxia Song, Min Luo, Chensheng Lin, Ning Ye

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Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction SystemsOriginalCollaborative enhancement from Pb 2+ and F − in Pb 2 (NO 3 ) 2 (H 2 O)F 2 generates the largest second harmonic generation effect among nitrates91Experimental and ab initio studies of Cd 5 (BO 3 ) 3 Cl: the first cadmium borate chlorine NLO material with isolated BO 3 groups21Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges17Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238Controlled Hydrothermal Crystallization of Anhydrous Ln2(OH)4SO4 (Ln=Eu–Lu, Y) as a New Family of Layered Rare Earth Metal Hydroxides41Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges10Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response112Perfect balance harmony in Ba 2 NO 3 (OH) 3 : a beryllium-free nitrate as a UV nonlinear optical material184Synthesis, crystal structure and optical properties of a new fluorocarbonate with an interesting sandwich-like structure7A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge27Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials356Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Beryllium-Free Nonlinear-Optical Crystals A 3 Ba 3 Li 2 Ga 4 B 6 O 20 F (A = K and Rb): Members of the Sr 2 Be 2 (BO 3 ) 2 O Family with a Strong Covalent Connection between the ∞ 2 [Li 2 Ga 4 B 6 O 20 F] 9– Double Layers27Rb 3 VO(O 2 ) 2 CO 3 : A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response207Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response42Second-order nonlinear optical crystals with mixed anions250Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23BaB8O12F2: a promising deep-UV birefringent material60Changes of optical transition models caused by crystal structural changes in CaSe2O50A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials98Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework61Module-Analysis-Assisted Design of Deep Ultraviolet Fluorooxoborates with Extremely Large Gap and High Structural Stability109Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials37Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive14Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O545Be2CO3F2 Monolayer: A Flexible Ultraviolet Nonlinear Optical Material via Rational Design6KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Nitrate nonlinear optical crystals: A survey on structure-performance relationships146RbNa(HC 3 N 3 O 3 )·2H 2 O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material69Layered rare-earth hydroxides: a new family of anion-exchangeable layered inorganic materials57(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design302Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect42Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles146Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate8K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence61Rational Design of the Metal‐Free KBe 2 BO 3 F 2 ⋅(KBBF) Family Member C(NH 2 ) 3 SO 3 F with Ultraviolet Optical Nonlinearity201Rational Design of the Metal‐Free KBe2BO3F2⋅(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity31Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy47Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62The synthesis, characterization, and theoretical analysis of (NH 4 ) 3 PbCl 52Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219[C(NH2)3]3PO4·2H2O: A new metal-free ultraviolet nonlinear optical phosphate with large birefringence and second-harmonic generation response70π‑Conjugated Trigonal Planar [C(NH2)3]+ Cationic Group: A Superior Functional Unit for Ultraviolet Nonlinear Optical Materials52Te(CS(NH2)2)4SO4·2H2O: A Three-in-One Semiorganic Nonlinear Optical Crystal with an Unusual Quadrilateral (TeS4)6– Chromophore14Recent advances in nonlinear optical rare earth structures63Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials28A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation63A Photochromic Zinc–Viologen Framework with a High-Contrast Nonlinear Optical Switchable Behavior24Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)216An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals25A New Nonlinear Optical Material with N(CN)2− Anion2NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency15A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency96Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response5Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)6Large optical anisotropy differentiation induced by the anion-directed regulation of structures29PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group3Potential optical functional crystals with large birefringence: Recent advances and future prospects322Nonlinear optical and detonation properties of semiorganic nitrate crystal C6H14N2(NO3)3·H3O8[C4H4O4]⋅[C6H13N] as a nonlinear optical co-crystal with spike-like dielectric anomalies0Directional Construction of New Nonlinear Optical Bifunctional Units through Molecular Engineering Design Inspired by the B 3 O 7 -Typed Configuration23Remarkable Infrared Nonlinear Optical, Dielectric, and Strong Diamagnetic Characteristics of Semiconducting K3[BiS3]5Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response44RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates15Phosphites: A Nonlinear Optical Materials System with a Wide Band Gap and Moderate Second-Harmonic Generation Effect27KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs39An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Structural characteristics and effective two photon absorption induced optical limiting behavior of Co2+ doped monoclinic LaPO4 nanostructures26Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Two Mixed-Alkali-Metal Selenates as Short-Wave Ultraviolet Nonlinear-Optical Materials10Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence59Quadruple‐Bidentate Nitrate‐Ligated A 2 Hg(NO 3 ) 4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence2Designing a Dimension Reduced Hybrid Perovskite with Robust Large Birefringence by Expanding Cationic π‐Delocation40Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25Enlargement of Bandgap and Birefringence in Nonlinear Optical Alkali‐Metal Sulfate Crystals by the Substitution of Asymmetrical Non‐π‐Conjugated Cation8New Functional Groups Design toward High Performance Ultraviolet Nonlinear Optical Materials95Mg(C 3 O 4 H 2 )(H 2 O) 2 : A New Ultraviolet Nonlinear Optical Material Derived from KBe 2 BO 3 F 2 with High Performance and Excellent Water‐Resistance7Mg(C3O4H2)(H2O)2: A New Ultraviolet Nonlinear Optical Material Derived from KBe2BO3F2 with High Performance and Excellent Water‐Resistance43A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains13Mild-hydrothermal synthesis of RE(OH)SO4 layered compounds (RE = La–Tb), crystal structure, thermolysis, and photoluminescence5(C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups33External electric field driven conformation transition between lithium salts and electride-like molecules: intriguing NLO switches in Li@corannulene3Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43[Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption5A critical review of the solution chemistry, solubility, and thermodynamics of europium: Recent advances on the Eu(III) hydrolysis24Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction11Enhanced UV Nonlinear Optical Properties in Layered Germanous Phosphites through Functional Group Sequential Construction116Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66A3Sc(SO4)3 (A = K, Rb, Cs): Three Deep‐Ultraviolet Transparent Alkali‐Scandium Sulfates with Strong Second‐Harmonic Generation Response and High Thermal Stability14NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5Functional Modules Map of Unexplored Chemical Space: Guiding the Discovery of Giant Birefringent Materials76Constructing Ultraviolet Nonlinear Optical Crystals with Superior Thermal Stability Based on Organic π-Conjugated [HCOO] Groups6π-Lone pair synergy in (C7H4NO4)(IO3): Optimal balance among SHG, birefringence, and bandgap performance29Toward Strong UV–Vis–NIR Second-Harmonic Generation by Dimensionality Engineering of Zinc Thiocyanates32Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)4Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109Rational design of a series of non-centrosymmetric antiperovskite and double antiperovskite borate fluorides13“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A potential UV nonlinear-optical crystal with a strong second-harmonic response: RbNa 2 Eu 2 (BO 3 ) 35Cation tuning in anionic framework hydroborates: tailored deep-ultraviolet optical crystals with large birefringence1The impact of anionic group arrangement on the optical properties of the arsenate series0Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit16Exploring the Crystallization of Lanthanum(III) and Neodymium(III) Hydroxides from Solution4Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal9[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5Gd(OH)₂NO₃ rare earth ions functionalized reduced graphene oxide: A promising material for supercapacitor electrode applications3REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects0BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0Isoniazid nitrate: synergistic dual π-conjugation triggering prominent second-harmonic generation0K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit2Synthesis and characterization of hydrated alkali metal calcium nitrates ACa(NO 3 ) 3 ·2H 2 O (A = NH 4 , Rb, Cs) as short ultraviolet birefringent materials0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence0(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV nonlinear optical material due to π-conjugated cation and hydrogen bonding intervention1Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1Hydrogen‐Bond‐Directed Assembly of Urea Derivatives: Exceptional Birefringence Achieved by π ‐Conjugated Unit Alignment3Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals2Redox‐Driven Strategy Enabling Leapfrog Enhancement of Birefringence in Layered Tin‐Based Optical Crystals1

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  1. Collaborative enhancement from Pb 2+ and F − in Pb 2 (NO 3 ) 2 (H 2 O)F 2 generates the largest second harmonic generation effect among nitrates

    Chemical Communications · 2017-01-01

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  2. Experimental and ab initio studies of Cd 5 (BO 3 ) 3 Cl: the first cadmium borate chlorine NLO material with isolated BO 3 groups

    Dalton Transactions · 2017-01-01

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  3. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

    Dalton Transactions · 2017-01-01

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  4. ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

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  5. Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties

    Inorganic Chemistry Frontiers · 2017-01-01

    Chao Wu, Longhua Li, Jun‐Ling Song, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  6. M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

    Chemistry of Materials · 2017-01-30

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  7. Controlled Hydrothermal Crystallization of Anhydrous Ln2(OH)4SO4 (Ln=Eu–Lu, Y) as a New Family of Layered Rare Earth Metal Hydroxides

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  8. Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups

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  9. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials

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  10. LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges

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  11. Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response

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  12. Perfect balance harmony in Ba 2 NO 3 (OH) 3 : a beryllium-free nitrate as a UV nonlinear optical material

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  13. Synthesis, crystal structure and optical properties of a new fluorocarbonate with an interesting sandwich-like structure

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  14. A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge

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  15. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

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  16. M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials

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  17. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

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  18. Beryllium-Free Nonlinear-Optical Crystals A 3 Ba 3 Li 2 Ga 4 B 6 O 20 F (A = K and Rb): Members of the Sr 2 Be 2 (BO 3 ) 2 O Family with a Strong Covalent Connection between the ∞ 2 [Li 2 Ga 4 B 6 O 20 F] 9– Double Layers

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  19. Rb 3 VO(O 2 ) 2 CO 3 : A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

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  20. Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

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  21. Second-order nonlinear optical crystals with mixed anions

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  22. Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)2

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  23. BaB8O12F2: a promising deep-UV birefringent material

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  24. Changes of optical transition models caused by crystal structural changes in CaSe2O5

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  25. A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials

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  26. Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

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  27. Module-Analysis-Assisted Design of Deep Ultraviolet Fluorooxoborates with Extremely Large Gap and High Structural Stability

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  28. Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials

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  29. Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive

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  30. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O

    Crystal Growth & Design · 2019-04-03

    Yutong Shi, Min Luo, Chensheng Lin, Guang Peng, Ning Ye

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  31. Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O5

    Inorganic Chemistry · 2019-04-09

    Qian Wang, Fei Yang, Xing Wang, Jing Wen Zhou, Jia Ju, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  32. Be2CO3F2 Monolayer: A Flexible Ultraviolet Nonlinear Optical Material via Rational Design

    Inorganic Chemistry · 2019-05-23

    Yilimiranmu Rouzhahong, Bingbing Zhang, Ailijiang Abudurusuli, Shilie Pan, Zhihua Yang

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  33. KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active

    Crystal Growth & Design · 2019-06-06

    Zeng-Hao Yue, Zhen‐Tao Lu, Huaiguo Xue, Sheng‐Ping Guo

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  34. Nitrate nonlinear optical crystals: A survey on structure-performance relationships

    Coordination Chemistry Reviews · 2019-09-10

    Xiaomeng Liu, Pifu Gong, Yi Jin Yang, Gaomin Song, Zheshuai Lin

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  35. RbNa(HC 3 N 3 O 3 )·2H 2 O exhibiting a strong second harmonic generation response and large birefringence as a new potential UV nonlinear optical material

    Inorganic Chemistry Frontiers · 2019-10-14

    Yunxia Song, Donghong Lin, Min Luo, Chensheng Lin, Qiaoling Chen, Ning Ye

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  36. Layered rare-earth hydroxides: a new family of anion-exchangeable layered inorganic materials

    Russian Chemical Reviews · 2019-11-29

    Alexey D. Yapryntsev, Alexander E. Baranchikov, Vladimir K. Ivanov

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  37. (NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization

    Chemical Communications · 2020-01-01

    Yalan Deng, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  38. From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides

    Chemical Communications · 2020-01-01

    Liling Cao, Min Luo, Chensheng Lin, Yuqiao Zhou, Dan Zhao, Tao Yan, Ning Ye

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  39. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  40. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

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  41. Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design

    Chemical Science · 2020-01-01

    Guohong Zou, Kang Min Ok

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  42. Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect

    Inorganic Chemistry Frontiers · 2020-01-01

    Xianghe Meng, Kaijin Kang, Fei Liang, Jian Tang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  43. Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles

    Coordination Chemistry Reviews · 2020-01-10

    Youchao Liu, Yaoguo Shen, Sangen Zhao, Junhua Luo

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  44. Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate

    Inorganic Chemistry Communications · 2020-03-20

    Yaoguo Shen, Xiaoling Xue, Renwen Yan, Hong Lin

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  45. K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence

    Journal of Alloys and Compounds · 2020-04-15

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  46. Rational Design of the Metal‐Free KBe 2 BO 3 F 2 ⋅(KBBF) Family Member C(NH 2 ) 3 SO 3 F with Ultraviolet Optical Nonlinearity

    Angewandte Chemie International Edition · 2020-06-14

    Min Luo, Chensheng Lin, Donghong Lin, Ning Ye

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  47. Rational Design of the Metal‐Free KBe2BO3F2⋅(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity

    Angewandte Chemie · 2020-06-15

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  48. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2020-06-19

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  49. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie · 2020-06-19

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  50. A(H3C3N3O3)(NO3) (A = K, Rb): Alkali-Metal Nitrate Isocyanurates with Strong Optical Anisotropy

    Inorganic Chemistry · 2020-06-28

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