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RESEARCH PAPER · Journal of Rare Earths · 2021

Recent advances in nonlinear optical rare earth structures

Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

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Recent advances in nonlinear optical rare earth structuresOriginalApplying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21Complex coordinated functional groups: A great genes for nonlinear optical materials64Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups8Impedance spectroscopy and DFT/TD-DFT studies of diyttrium trioxide for optoelectronic fields19Crystal Growth, Characterization, and Thermal Annealing of Nonlinear Optical Crystals AgGaGenSe2(n+1) (n = 1.5, 1.75, 2, 3, 4, 5, and 9) for Mid-infrared Applications12Research progress of rare earth separation methods and technologies183Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold143Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold7AgGaGeSe4: An Infrared Nonlinear Quaternary Selenide with Good Performance6A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114Investigation of Intensity Dependent Nonlinear Absorption in Cerium Phosphate Nanorods6Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28A review of structures and physical properties of rare earth chalcophosphates77Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template95LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Rare earth inorganic-organic hybrid compounds based on Keggin-type polyoxometalate {SiW12} with fast-responsive photochromism and switchable luminescence properties31Sustainability applications of rare earths from metallurgy, magnetism, catalysis, luminescence to future electrochemical pseudocapacitance energy storage72Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16Co-substitution design: a new glaserite-type rare-earth phosphate K 2 RbSc(PO 4 ) 2 with high structural tolerance6Multi-scale Crystallization Materials: Advances in in-situ Characterization Techniques and Computational Simulations2Expanding gaudefroyite family to Sr2MBi(REEO)3(BO3)4 (M = Ca, Sr, Ba; REE = Y, Eu) borates with large second harmonic generation responses8Role of Sm in tuning the third-order nonlinear optical properties of spray coated Sn1-xSmxO2 films4Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Light‐Emitting Device Based on Amplified Spontaneous Emission29Optimal Design of Mid-Infrared Nonlinear-Optical Crystals: From SrZnSnSe 4 to SrZnSiSe 422Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance56ZnS NPs enhanced Eu3+ photoluminescence in the sol-gel silica matrix1Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27A Modified Method for Determining the Optical Indicatrix in Monoclinic Crystals Based on Optical Prisms2Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70How much length of boron-nitride incorporated benzene like structures can produce efficient harmonic generation at their low-lying excited states?2Rare Earths—The Answer to Everything40Mixed Anionic M(S/X)6 Polyhedra as Symmetry-Breaking Motifs to Enhance the Infrared Nonlinear Optical Response in Y–M–S–X (M = Ga, Ge; X = Cl, Br)5A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence12Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Experimental and Mechanistic Analysis of Bastnaesite Pelletization in the Context of Carbochlorination1Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups5Advanced Ceramics for Photonic Applications: A Rich Landscape0Molecular properties of a triazole–Ce(III) complex with antioxidant activity: structure, spectroscopy, and relationships with related derivatives. Influence of the ligands in the complex2Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10Novel green-emitting BaBi2B2O7:Tb3+ solid solutions: The luminescence, crystal structure and compositional deformations5Rare‐Earth Substitution Induced Symmetry Breaking for The First Sc‐Based Nonlinear Optical Chalcogenide with High‐Performance30Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions4Unravelling the impact of octahedral distortion and non-covalent interactions on the hyperpolarizabilities of Co(II) and Ni(II) coordination complexes with uridine nucleotide11Sign Reversal of Optical Nonlinearity by Pauli Blocking in Blue Light-Emitting Samarium-Doped ZnO Nanostructures2Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1A Theoretical Investigation of the Linear and Nonlinear Optical Responses of Scandium- and Yttrium-Doped (sub-nm) Ag and Au Clusters0Crystal and band energy structure of Nd1.5Y(Tb)1.5Ga1.67S7 sulfide2Spin-Resolved Second-Harmonic Generation from Europium 4f/5d States in a Weakly Stabilized Metastable Polymorph of Eu 2 P 2 S 60Nonlinear Optical Properties of Nanoclusters and Applications of Nanotechnology0Modification of optical, thermal, and second harmonic generation characteristics of zinc tris (thiourea) sulphate crystals through Nd3+ and K+ co-doping0Recent progress of rare earth element electrocatalysts: The critical role of electronic configuration regulation0Synthesis, structure, optical properties, and magnetic behavior of layered heavy rare-earth thiogermanates CsDyGeS4 and CsErGeS40

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  1. Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)

    Inorganic Chemistry Frontiers · 2021-01-01

    Gary Cicirello, Kui Wu, Bingbing Zhang, Jian Wang

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  2. Complex coordinated functional groups: A great genes for nonlinear optical materials

    Chinese Chemical Letters · 2021-12-03

    Weikang Wang, Dajiang Mei, Shaoguo Wen, Jian Wang, Yuandong Wu

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  3. Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Jin Chen, Qianqian Chen, Fei‐Fei Mao, Zhen Liu, Bingxuan Li, Xiaohui Wu, Ke‐Zhao Du

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  4. Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups

    Inorganic Chemistry Frontiers · 2022-01-01

    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  5. Impedance spectroscopy and DFT/TD-DFT studies of diyttrium trioxide for optoelectronic fields

    Journal of Rare Earths · 2022-03-17

    Ali A. Alkathiri, Ahmed A. Atta, Moamen Salah El-Deen Refat, Sonam Shakya, Ali M. Hassanien, Saud A. Algarni, Emad M. Ahmed, Sultan E. Alomariy, Mohammed Alsawat, Norah Algethami

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  6. Crystal Growth, Characterization, and Thermal Annealing of Nonlinear Optical Crystals AgGaGenSe2(n+1) (n = 1.5, 1.75, 2, 3, 4, 5, and 9) for Mid-infrared Applications

    Inorganic Chemistry · 2022-04-15

    Xinyao Liu, Jing Peng, Xiao Xiao, Zhengbin Xiong, Gaohai Huang, Baojun Chen, Z. Y. He, Wei Huang

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  7. Research progress of rare earth separation methods and technologies

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    Mory Traore, Aijun Gong, Yiwen Wang, Lina Qiu, Yuzhen Bai, Weiyu Zhao, Yang Liu, Yi g Chen, Ying Liu, Huilin Wu, Shuli Li, Yueyi You

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  8. Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

    Angewandte Chemie International Edition · 2022-06-08

    Xiao Fen Huang, Sihan Yang, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  9. Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

    Angewandte Chemie · 2022-06-08

    Xiao Fen Huang, Sihan Yang, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  10. AgGaGeSe4: An Infrared Nonlinear Quaternary Selenide with Good Performance

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    Junhui Dang, Naizheng Wang, Jiyong Yao, Yuandong Wu, Zheshuai Lin, Dajiang Mei

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  11. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  12. Investigation of Intensity Dependent Nonlinear Absorption in Cerium Phosphate Nanorods

    Journal of Physics Conference Series · 2022-10-01

    Anita Mary Peter, Manikandan Ramya, Madanan Kailasnath

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  13. Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials

    European Journal of Inorganic Chemistry · 2022-10-05

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  14. A review of structures and physical properties of rare earth chalcophosphates

    Coordination Chemistry Reviews · 2022-10-11

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  15. Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template

    ACS Central Science · 2022-11-11

    Zi‐Jian Li, Wenqi Jin, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  16. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

    Advanced Optical Materials · 2022-12-03

    Xiaojing Li, Zilong Chen, Fuming Li, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  17. Rare earth inorganic-organic hybrid compounds based on Keggin-type polyoxometalate {SiW12} with fast-responsive photochromism and switchable luminescence properties

    Journal of Rare Earths · 2022-12-15

    Hong Cui, Yanli Yang, Xue Bai, Han Xu, Wensha Zhang, Ying Lü, Shuxia Liu

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  18. Sustainability applications of rare earths from metallurgy, magnetism, catalysis, luminescence to future electrochemical pseudocapacitance energy storage

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  19. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  20. Co-substitution design: a new glaserite-type rare-earth phosphate K 2 RbSc(PO 4 ) 2 with high structural tolerance

    Dalton Transactions · 2023-01-01

    Jingfang Zhou, Pifu Gong, Mingjun Xia, Qian Wu

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  21. Multi-scale Crystallization Materials: Advances in in-situ Characterization Techniques and Computational Simulations

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  22. Expanding gaudefroyite family to Sr2MBi(REEO)3(BO3)4 (M = Ca, Sr, Ba; REE = Y, Eu) borates with large second harmonic generation responses

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    Р. С. Бубнова, A.P. Shablinskii, Sergey Yu. Stefanovich, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, Bogdan I. Lazoryak, В. Л. Уголков, С. К. Филатов

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  23. Role of Sm in tuning the third-order nonlinear optical properties of spray coated Sn1-xSmxO2 films

    Optical Materials · 2023-01-30

    P. Asha Hind, P. S. Patil, Neelamma Basayya Gummagol, U. K. Goutam, Bharathipura Venkataramana Rajendra

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  24. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

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  25. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

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  26. Light‐Emitting Device Based on Amplified Spontaneous Emission

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  27. Optimal Design of Mid-Infrared Nonlinear-Optical Crystals: From SrZnSnSe 4 to SrZnSiSe 4

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  28. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

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  29. ZnS NPs enhanced Eu3+ photoluminescence in the sol-gel silica matrix

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  30. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

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  31. A Modified Method for Determining the Optical Indicatrix in Monoclinic Crystals Based on Optical Prisms

    Crystal Growth & Design · 2023-11-28

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  32. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

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  33. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  34. How much length of boron-nitride incorporated benzene like structures can produce efficient harmonic generation at their low-lying excited states?

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  35. Rare Earths—The Answer to Everything

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  36. Mixed Anionic M(S/X)6 Polyhedra as Symmetry-Breaking Motifs to Enhance the Infrared Nonlinear Optical Response in Y–M–S–X (M = Ga, Ge; X = Cl, Br)

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  37. A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence

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  38. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

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  39. Experimental and Mechanistic Analysis of Bastnaesite Pelletization in the Context of Carbochlorination

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  40. Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy

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  41. LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups

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  42. Advanced Ceramics for Photonic Applications: A Rich Landscape

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  43. Molecular properties of a triazole–Ce(III) complex with antioxidant activity: structure, spectroscopy, and relationships with related derivatives. Influence of the ligands in the complex

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  44. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

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  45. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

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  46. Novel green-emitting BaBi2B2O7:Tb3+ solid solutions: The luminescence, crystal structure and compositional deformations

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  47. Rare‐Earth Substitution Induced Symmetry Breaking for The First Sc‐Based Nonlinear Optical Chalcogenide with High‐Performance

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  48. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

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  49. Strong Second‐Harmonic Generation Responses in Salt‐Inclusion Oxychalcogenides Enabled by the Highly Distorted Polyhedra with Mixed‐Anions

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  50. Unravelling the impact of octahedral distortion and non-covalent interactions on the hyperpolarizabilities of Co(II) and Ni(II) coordination complexes with uridine nucleotide

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