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RESEARCH PAPER · Crystals · 2017

Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

Yi Jin Yang, Xingxing Jiang, Zheshuai Lin, Yicheng Wu

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Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical CrystalsOriginalLithium borate Li 3 B 5 O 8 (OH) 2 with large second harmonic generation and a high damage threshold in the deep-ultraviolet spectral range16Novel borate CsZn2B3O7 single crystal with large efficient second harmonic generation in deep-ultraviolet spectral range43Polar phase transitions in heteroepitaxial stabilized La 0.5 Y 0.5 AlO 3 thin films0CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units184CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units895Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15Thermal properties and CW laser performances of pure and Nd doped Bi 2 ZnB 2 O 7 single crystals6Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials191Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials714A novel photocatalytic water splitting solar-to-hydrogen energy conversion: Non-centro-symmetric borate CsZn2B3O7 photocatalyst21High-Power, Solid-State, Deep Ultraviolet Laser Generation64A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration16Combination of d 10 -cations and fluorine anion as active participants to design novel borate/carbonate nonlinear optical materials24Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses25A Novel Reddish Orange Luminescent Material Sr3B2O6:Sm3+6Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27Bismuth-Based Oxyborate Piezoelectric Crystals: Growth and Electro-Elastic Properties12Modification in structural, functional, thermal, dielectric, impedance and nonlinear optical properties of ammonium pentaborate crystal by addition of di-sodium sulphide nanoparticles7Structural, spectral, thermal and nonlinear optical analysis of potassium tartrate hemihydrate crystal1Crystal Growth of Multifunctional Borates and Related Materials0Synthesis and Photoluminescence Characterization of NaSr4(BO3)3 Activated with Dy3+ Ion*5Solution Phase Mass Synthesis of 2D Atomic Layer with Hexagonal Boron Network22Nonlinear Optical Crystals for Second Harmonic Generation19Synthesis & structural characterization of Yttrium calcium borate, compound, by one step solid- state reaction method0Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties11Spectrally uncorrelated biphotons generated from “the family of BBO crystal”15Widely Tunable Angular Non-Critical Phase-Matching Wavelengths from 0.72 to 1.42 μm Based on RE1xRE21−xCOB Mixed Crystals3Polymorphism in SmSc3(BO3)4: Crystal structure, luminescent and SHG properties19Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)24Na1.7Li0.3BaZn7(TeO6)3: The first mixed alkali metal and alkaline earth metal zinc tellurate0Effect of L-Serine Doping on Growth and Properties of Ammonium Pentaborate Single Crystal4A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**175A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**27Crystal growth of Sr3BeB6O13 and its thermal and optical properties1Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation58Inorganic nonlinear optical materials7Neutron detection properties of thermoluminescent Sr2B2O5:Eu ceramics12Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals5Electronic, optical and spectroscopic properties of N-dialkyl-imidazolium hexafluorophosphate (CNMIM.PF6) ionic liquid crystal molecules investigated by computational methods14From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups13Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Pioneering Exploration in the Na–Lu–B–O System: Na3LuB8O15 with Polyborate Structure and Short UV Cutoff Edge1Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy24Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction4Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction11K3Y3(BO3)4: A Potential UV Nonlinear-Optical Crystal Designed by a Chemical Substitution Strategy14Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Influence of an alkali metal dopant Rb on the structural, mechanical and optical properties of an UV-transparent ammonium pentaborate crystal0Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence0Effects of alkali metal (K+) cation substitution on the mechanical and nonlinear optical properties of ammonium pentaborate crystal0

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  1. Lithium borate Li 3 B 5 O 8 (OH) 2 with large second harmonic generation and a high damage threshold in the deep-ultraviolet spectral range

    Physical Chemistry Chemical Physics · 2017-01-01

    A.H. Reshak

    Read original paper ↗ ·

  2. Novel borate CsZn2B3O7 single crystal with large efficient second harmonic generation in deep-ultraviolet spectral range

    Journal of Alloys and Compounds · 2017-06-12

    A.H. Reshak

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  3. Polar phase transitions in heteroepitaxial stabilized La 0.5 Y 0.5 AlO 3 thin films

    Journal of Physics Condensed Matter · 2017-07-25

    Shenghua Liu, Chunfeng Zhang, Mengya Zhu, Qian He, Jak Chakhalian, Xiaoran Liu, Albina Y. Borisevich, Xiaoyong Wang, Min Xiao

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  4. CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie · 2017-09-12

    Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  5. CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie International Edition · 2017-09-12

    Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  6. Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations

    Inorganic Chemistry Frontiers · 2018-01-01

    Yanna Chen, Min Zhang, Cong Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  7. Thermal properties and CW laser performances of pure and Nd doped Bi 2 ZnB 2 O 7 single crystals

    CrystEngComm · 2018-01-01

    Feifei Chen, Xinle Wang, Lei Wei, Fapeng Yu, Shiwei Tian, Chao Jiang, Yanlu Li, Xiufeng Cheng, Zhengping Wang, Xian Zhao

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  8. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie · 2018-01-10

    Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2018-01-10

    Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  10. A novel photocatalytic water splitting solar-to-hydrogen energy conversion: Non-centro-symmetric borate CsZn2B3O7 photocatalyst

    Journal of Alloys and Compounds · 2018-01-31

    A.H. Reshak

    Read original paper ↗ ·

  11. High-Power, Solid-State, Deep Ultraviolet Laser Generation

    Applied Sciences · 2018-02-03

    Hongwen Xuan, Hironori Igarashi, Shinji Ito, Chen Qu, Zhigang Zhao, Yohei Kobayashi

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  12. A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

    Chemistry of Materials · 2018-03-08

    Zhiqing Xie, Miriding Mutailipu, Guijie He, Guopeng Han, Ying Wang, Zhihua Yang, Min Zhang, Shilie Pan

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  13. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

    Chao Wu, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  14. Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration

    Chinese Science Bulletin (Chinese Version) · 2018-03-22

    Minqiang Gai, Ying Wang, Shilie Pan

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  15. Combination of d 10 -cations and fluorine anion as active participants to design novel borate/carbonate nonlinear optical materials

    Journal of Alloys and Compounds · 2018-05-18

    Beenish Bashir, Bingbing Zhang, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  16. Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses

    Inorganic Chemistry · 2018-11-14

    Fengjiao Guo, Jian Wei Han, Jianian Cheng, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  17. A Novel Reddish Orange Luminescent Material Sr3B2O6:Sm3+

    Journal of Applied Spectroscopy · 2019-01-01

    İlhan Pekgözlü

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  18. Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F2

    Acta Physica Sinica · 2019-01-01

    Minqiang Gai, Ying Wang, Shilie Pan

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  19. Bismuth-Based Oxyborate Piezoelectric Crystals: Growth and Electro-Elastic Properties

    Crystals · 2019-01-06

    Feifei Chen, Xiufeng Cheng, Fapeng Yu, Chunlei Wang, Xian Zhao

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  20. Modification in structural, functional, thermal, dielectric, impedance and nonlinear optical properties of ammonium pentaborate crystal by addition of di-sodium sulphide nanoparticles

    Modern Physics Letters B · 2019-02-25

    A. P. Kochuparampil, J. H. Joshi, H. O. Jethva, M. J. Joshi

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  21. Structural, spectral, thermal and nonlinear optical analysis of potassium tartrate hemihydrate crystal

    Journal of Materials Science Materials in Electronics · 2019-03-16

    N. Kalaimani, R. Aarthi, Chidambaram Ramachandra Raja

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  22. Crystal Growth of Multifunctional Borates and Related Materials

    MDPI eBooks · 2019-05-03

    Leonyuk, Nikolay I

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  23. Synthesis and Photoluminescence Characterization of NaSr4(BO3)3 Activated with Dy3+ Ion*

    Journal of Applied Spectroscopy · 2019-07-01

    İlhan Pekgözlü

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  24. Solution Phase Mass Synthesis of 2D Atomic Layer with Hexagonal Boron Network

    Journal of the American Chemical Society · 2019-08-02

    Tetsuya Kambe, Reina Hosono, Shotaro Imaoka, Akiyoshi Kuzume, Kimihisa Yamamoto

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  25. Nonlinear Optical Crystals for Second Harmonic Generation

    Crystallography Reports · 2019-12-01

    Somayeh Solgi, Majid Jafar Tafreshi, Morteza Sasani Ghamsari

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  26. Synthesis & structural characterization of Yttrium calcium borate, compound, by one step solid- state reaction method

    مجله بلورشناسی و کانی شناسی ایران · 2019-12-01

    Majid Jafar Tafreshi, Somayeh Solgi, Morteza Sasani Ghamsari

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  27. Emergent Deep‐Ultraviolet Nonlinear Optical Candidates

    Angewandte Chemie International Edition · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  28. Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich

    Angewandte Chemie · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  29. Nd3+ and Pr3+ doped anti-zeolite matrix-LiBa12(BO3)7F4: Crystal structures, luminescence properties

    Materials Chemistry and Physics · 2020-01-01

    Ekaterina A. Simonova, Artem B. Kuznetsov, В. А. Светличный, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Elena N. Nigmatulina, Maria V. Kolesnichenko, К. А. Кох, Sergey V. Rashchenko, Alexander E. Kokh

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  30. Spectrally uncorrelated biphotons generated from “the family of BBO crystal”

    Quantum Engineering · 2020-05-16

    Rui‐Bo Jin, Wu‐Hao Cai, Chunling Ding, Feng Mei, Guang‐Wei Deng, Ryosuke Shimizu, Qiang Zhou

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  31. Widely Tunable Angular Non-Critical Phase-Matching Wavelengths from 0.72 to 1.42 μm Based on RE1xRE21−xCOB Mixed Crystals

    Crystals · 2020-08-24

    Ranran Li, Hongwei Qi, Yanqing Liu, Fapeng Yu, Pingzhang Yu, Zhengping Wang, Xinguang Xu, Xian Zhao

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  32. Polymorphism in SmSc3(BO3)4: Crystal structure, luminescent and SHG properties

    Journal of Alloys and Compounds · 2020-08-27

    Artem B. Kuznetsov, К. А. Кох, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Sergey V. Rashchenko, Dmitry M. Ezhov, Ammar Y. Jamous, Asset Bolatov, Bolat Uralbekov, В. А. Светличный, Aleksander E. Kokh

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  33. Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa2Sm2(BO3)(PO4)2

    Acta Crystallographica Section C Structural Chemistry · 2020-11-13

    Dan Zhao, Lin-Ying Shi, Rui-Juan Zhang, Ya-Li Xue

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  34. Na1.7Li0.3BaZn7(TeO6)3: The first mixed alkali metal and alkaline earth metal zinc tellurate

    Inorganic Chemistry Communications · 2020-12-01

    Ting Zhang, Jingjing Zheng, Shichao Cheng, Junwei Feng, Chunyan Bai

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  35. Effect of L-Serine Doping on Growth and Properties of Ammonium Pentaborate Single Crystal

    Journal of Electronic Materials · 2021-03-18

    K. R. Rathod, J. H. Joshi, A. P. Kochuparampil, M. J. Joshi, Ketan Parikh

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  36. A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**

    Angewandte Chemie International Edition · 2021-09-16

    Lin Xiong, Li‐Ming Wu, Ling Chen

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  37. A General Principle for DUV NLO Materials: π‐Conjugated Confinement Enlarges Band Gap**

    Angewandte Chemie · 2021-09-17

    Lin Xiong, Li‐Ming Wu, Ling Chen

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  38. Crystal growth of Sr3BeB6O13 and its thermal and optical properties

    Journal of Crystal Growth · 2021-10-21

    Ruixin Guo, Weilong Zhu, Lei Bai, Qian Wu, Lijuan Liu, Xiaoyang Wang

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  39. Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation

    Inorganic Chemistry · 2021-11-19

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  40. Inorganic nonlinear optical materials

    Elsevier eBooks · 2022-02-25

    Chunmei Huang, Fangfang Zhang, Shilie Pan

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  41. Neutron detection properties of thermoluminescent Sr2B2O5:Eu ceramics

    Optical Materials · 2022-11-10

    Hajime Komiya, Hiroki Kawamoto, Yutaka Fujimoto, Masanori Koshimizu, Go Okada, Yusuke Koba, Genichiro Wakabayashi, Keisuke Asai

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  42. Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals

    Advanced Theory and Simulations · 2023-01-29

    Zhen Hong Fan, Zhixin Sun, Ai Wang, Yaohui Yin, Hui Li, Guangyong Jin, Chao Xin

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  43. Electronic, optical and spectroscopic properties of N-dialkyl-imidazolium hexafluorophosphate (CNMIM.PF6) ionic liquid crystal molecules investigated by computational methods

    Journal of Molecular Modeling · 2023-08-07

    Varsha Gautam, Mirtunjai Mishra, Khem Bahadur Thapa, Jitendra Kumar, Devendra Singh, Devesh Kumar

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  44. From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Cheng Chen, Danyang Dou, Yunjie Bai, Bingbing Zhang, Ying Wang

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  45. Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]

    Coordination Chemistry Reviews · 2024-02-02

    W. Zhang, Xueling Hou, Shujuan Han, Shilie Pan

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  46. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

    Journal of Physics and Chemistry of Solids · 2024-02-22

    Sergey M. Aksenov, Nikita V. Chukanov, Viktor P. Tarasov, Daria A. Banaru, Stephanie A. Mackley, A. M. Banaru, Sergey V. Krivovichev, Peter Carman Burns

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  47. Pioneering Exploration in the Na–Lu–B–O System: Na3LuB8O15 with Polyborate Structure and Short UV Cutoff Edge

    Crystal Growth & Design · 2024-03-08

    Juhe Liu, Yuwei Chen, Mengran Sun, Wenhao Liu, Xianghe Meng, Jiyong Yao

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  48. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  49. C6N7(NH2)3·H3PO4: Strong Second Harmonic Generation and Giant Birefringence Benefiting from Amino Substitution Strategy

    Advanced Optical Materials · 2024-08-22

    Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  50. Cu(I)‐Induced ‘Click Reaction’ Involving Coordination and Covalent Assembly of Hybrid Borates for the Electrocatalytic CO 2 Reduction

    Angewandte Chemie · 2024-09-12

    Jianbing Chen, Yinghua Yu, Hai‐Xia Zhang, Jian Zhang

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