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RESEARCH PAPER · Crystal Growth & Design · 2015

Large Birefringent Materials, Na6Te4W6O29 and Na2TeW2O9: Synthesis, Structure, Crystal Growth, and Characterization

Hongwei Yu, Weiguo Zhang, P. Shiv Halasyamani

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Large Birefringent Materials, Na6Te4W6O29 and Na2TeW2O9: Synthesis, Structure, Crystal Growth, and CharacterizationOriginalTop-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO442Copper polytellurite-chlorides with A2+ cations (ACd, Pb) obtained by CVT reactions5Positive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis36M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238Hydrothermal Synthesis of the Oxofluoride FeSbO2F2—An Anti-ferromagnetic Spin S = 5/2 Compound16The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density14Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties26Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals13LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20Controlled Growth of Layered Acentric CdTeMoO6 Single Crystals with Linear and Nonlinear Optical Properties50Co‐Crystals of 2‐Amino‐5‐Nitropyridine Barbital with Extreme Birefringence and Large Second Harmonic Generation Effect32NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence18BaB8O12F2: a promising deep-UV birefringent material60CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups16Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35Crystal Structure of the Disordered Non-Centrosymmetric Compound Fe0.43Mo2.56SbO9.53Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene284Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals12Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence28BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence37Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33Synthesis and Magnetic Properties of the Ternary Oxofluoride Fe3Sb4O6F69Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra2Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence92Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence13Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se828LaTeBO 5 : a new borotellurite with a large birefringence activated by the highly distorted [Te (iv) O 4 ] group16Different mechanism of stereochemical activity and birefringence in post-transition metal halides: A first-principles investigation1Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure24Tunable Circularly Polarized Luminescence from Single Crystal and Powder of the Simplest Tetraphenylethylene Helicate87Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS218[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40Rational design of a promising oxychalcogenide infrared nonlinear optical crystal60Recent advances in tellurite molybdate/tungstate crystals15Potential optical functional crystals with large birefringence: Recent advances and future prospects322Novel Polarized Crystal BaTeW2O9: Crystal Growth, Characterization, and Wide-Band Polarized Prism15Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains185Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap9Achieving effective balance between bandgap and birefringence by confining π-conjugation in an optically anisotropic crystal39Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)5Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction4AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence9Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds9Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence6Combining rigid and deformable groups to construct a robust birefringent crystal for compact polarization components25Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizations34Syntheses and crystal structures of four new d0 transition metal tellurites1Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate4Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5(C9H7BrN)BF4 and (C9H7BrN)2SiF6: Two Birefringent Crystals with Distinct Optical Anisotropy Regulated by Anions7Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Giant Birefringence and Strong Third-Order Nonlinear Optical Response in a Hybrid Crystal Templated by a Push–Pull π-Conjugated System6CaYIIIS 4 (III = Ga, In): Two Olivine-Type Compounds Exhibiting Exceptional Birefringence Properties1LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion3中红外氧化物非线性光学晶体研究进展（特邀）0Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals0Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit6First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg 3 P 2 S 80From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates0

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  1. Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO4

    Crystal Growth & Design · 2016-05-23

    Hongwei Yu, Jacqueline Cantwell, Hongping Wu, Weiguo Zhang, Kenneth Reinhard Poeppelmeier, P. Shiv Halasyamani

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  2. Copper polytellurite-chlorides with A2+ cations (ACd, Pb) obtained by CVT reactions

    Inorganic Chemistry Communications · 2016-07-12

    Diana O. Zinyakhina, Oleg I. Siidra, Dmitri O. Charkin, Еvgeny V. Nazarchuk, Р. С. Бубнова

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  3. Positive and negative contribution to birefringence in a family of carbonates: A Born effective charges analysis

    Journal of Solid State Chemistry · 2016-09-09

    Qun Jing, Guang Yang, Juan Hou, Maozhu Sun, Haibin Cao

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  4. M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

    Chemistry of Materials · 2017-01-30

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

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  5. Hydrothermal Synthesis of the Oxofluoride FeSbO2F2—An Anti-ferromagnetic Spin S = 5/2 Compound

    Inorganic Chemistry · 2017-03-24

    S. Ali, Reinhard Karl Kremer, Mats Johnsson

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  6. The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density

    Journal of Alloys and Compounds · 2017-05-11

    Lili Liu, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  7. Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2017-08-25

    S. Ali, Weiguo Zhang, P. Shiv Halasyamani, Mats Johnsson

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  8. Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups

    Journal of Materials Science · 2017-11-13

    Zhaohui Chen, Zhizhong Zhang, Ronglan Wu, Xiaoyu Dong, Yunjing Shi, Qun Jing

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  9. Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals

    CrystEngComm · 2018-01-01

    Ning Jia, Xixi Xiong, Shanpeng Wang, Tongtong Yu, Bing Q. Han, Jie Qiao, Chenning Li, Xutang Tao

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  10. LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge

    Inorganic Chemistry · 2018-02-14

    Yun Mo Yang, Qingrong Kong, Zhihua Yang, Shilie Pan

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  11. Controlled Growth of Layered Acentric CdTeMoO6 Single Crystals with Linear and Nonlinear Optical Properties

    Crystal Growth & Design · 2018-05-02

    Conggang Li, Xiangxin Tian, Zeliang Gao, Qian Wu, Peng Zhao, Youxuan Sun, Chengqian Zhang, Shao-Jun Zhang, Deliang Cui, Xutang Tao

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  12. Co‐Crystals of 2‐Amino‐5‐Nitropyridine Barbital with Extreme Birefringence and Large Second Harmonic Generation Effect

    Chemistry - A European Journal · 2018-05-07

    Marlena Gryl, Tomasz Seidler, Joanna Wojnarska, Katarzyna Marta Stadnicka, Irena Matulková, Ivan Němec, Petr Němec

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  13. NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence

    Journal of Solid State Chemistry · 2018-09-12

    Zhiqing Xie, Shichao Cheng, Shuwei Li, Hanqin Ding

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  14. BaB8O12F2: a promising deep-UV birefringent material

    Inorganic Chemistry Frontiers · 2018-12-25

    Zhizhong Zhang, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan

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  15. CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups

    CrystEngComm · 2019-01-01

    Wang Ya, Jian Wei Han, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  16. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

    Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  17. Crystal Structure of the Disordered Non-Centrosymmetric Compound Fe0.43Mo2.56SbO9.5

    Crystals · 2019-01-15

    S. Ali, Sven Lidin, Mats Johnsson

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  18. Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5 Functional Gene

    Journal of the American Chemical Society · 2019-01-18

    Min Zhang, Donghai An, Cong Hu, Xinglong Chen, Zhihua Yang, Shilie Pan

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  19. Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals

    Inorganic Chemistry · 2019-04-19

    Weiqun Lu, Zeliang Gao, Xiaoli Du, Xiangxin Tian, Qian Wu, Conggang Li, Youxuan Sun, Yang Liu, Xutang Tao

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  20. Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides

    Science China Materials · 2019-10-24

    Junben Huang, Siru Guo, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  21. Rb3Na(H2C3N3O3)4·3H2O with Large Birefringence

    ACS Omega · 2019-12-13

    Mukeremu Aibibula, Li Wang, Shuzhao Huang

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  22. BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains

    Dalton Transactions · 2020-01-01

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  23. PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence

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  24. Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer

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  25. Synthesis and Magnetic Properties of the Ternary Oxofluoride Fe3Sb4O6F6

    European Journal of Inorganic Chemistry · 2020-07-27

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  26. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

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  27. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

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  28. KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra

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  29. Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence

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  30. Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence

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  31. Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se8

    Inorganic Chemistry · 2020-12-23

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  32. LaTeBO 5 : a new borotellurite with a large birefringence activated by the highly distorted [Te (iv) O 4 ] group

    Dalton Transactions · 2021-01-01

    Jiankang Wang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  33. Different mechanism of stereochemical activity and birefringence in post-transition metal halides: A first-principles investigation

    Journal of Solid State Chemistry · 2021-02-06

    Kui Wang, Qun Jing, Zhenzhen Wan, Ming‐Hsien Lee, Haiming Duan, Haibin Cao, Jun Zhang

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  34. Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure

    Inorganic Chemistry · 2021-06-16

    Tian Tian, Zefen Li, Naizheng Wang, Sangen Zhao, Jiayue Xu, Zheshuai Lin, Dajiang Mei

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  35. Tunable Circularly Polarized Luminescence from Single Crystal and Powder of the Simplest Tetraphenylethylene Helicate

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  36. Na+/Ag+ substitution induced birefringence enhancement from AgGaS2 to NaGaS2

    Journal of Alloys and Compounds · 2021-12-04

    Yihan Yun, Wenlong Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  37. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

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  38. Rational design of a promising oxychalcogenide infrared nonlinear optical crystal

    Chemical Science · 2022-01-01

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  39. Recent advances in tellurite molybdate/tungstate crystals

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  40. Potential optical functional crystals with large birefringence: Recent advances and future prospects

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  41. Novel Polarized Crystal BaTeW2O9: Crystal Growth, Characterization, and Wide-Band Polarized Prism

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  42. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

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  43. Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species

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  44. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains

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  45. Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap

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  46. Achieving effective balance between bandgap and birefringence by confining π-conjugation in an optically anisotropic crystal

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  47. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

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  48. Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)

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  49. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

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  50. Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction

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