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RESEARCH PAPER · Chemical Science · 2022

Rational design of a promising oxychalcogenide infrared nonlinear optical crystal

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Rational design of a promising oxychalcogenide infrared nonlinear optical crystalOriginal[Ba2F2][Ge2O3S2]: An Unprecedented Heteroanionic Infrared Nonlinear Optical Material Containing Three Typical Anions47Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance56Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances29The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps68Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups35A unique [Sb 6 O 2 S 13 ] 12− finite chain in oxychalcogenide Ba 6 Sb 6 O 2 S 13 leading to ultra-low thermal conductivity and giant birefringence12Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution30Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Recent progress of newly developed functional building units and corresponding nonlinear optical materials14[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds36Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11Synthesis of Non-centrosymmetric, Metastable Rare-Earth Oxysulfides by Anionic Redox Topochemistry8NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps28Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors21Chiral and Polar Duality Design of Heteroanionic Compounds: Sr18Ge9O5S31 Based on [Sr3OGeS3]2+ and [Sr3SGeS3]2+ Groups20Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks13Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals9Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units7Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework8Synthesis and Investigation of Electrochemical Studies on Thulium Tellurite (TmTeO3) for Supercapacitor Electrode Application9The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution28Sr2HgGe2OS6: A Hg-Based Oxychalcogenide Infrared Nonlinear Optical Material Exhibiting Favorable Balance between a Large Band Gap and Strong Second Harmonic Generation Response10Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Ae3[TO3][SnOQ3] (Ae = Sr, Ba; T = Si, Ge; Q = S, Se) and Ba3[CO3][MQ4] (M = Ge, Sn; Q = S, Se): Design and Syntheses of a Series of Heteroanionic Antiperovskite-Type Oxychalcogenides30Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22Probing structural, surface morphological, optical, low temperature magnetic studies and electrochemical studies on gadolinium tellurite (GdTeO3)6La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances18Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy4La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio15Two-in-one: assembling hybrid supertetrahedra chromophores and achieving high-performance “hexagonal warriors” in nonlinear optical crystals6A new synthetic tellurium oxychloride (ZrTe2O6Cl): structural evaluation, spectroscopic (FT–IR, Raman, UV–vis) properties and thermal (TGA/DSC) behavior2Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate12Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering4Recent progress in structural design strategies of high-birefringence optical crystals55From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide5Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2LnEuGa3OS6 (Ln = La, Pr, Nd): three dual rare earth metal-based oxychalcogenides with good IR nonlinear optical performances1Ba 3 S[SnOS 3 ] and [Ba 2 Sn]S[Ge 2 O 7 ]: two antiperovskite oxychalcogenides with good IR nonlinear optical performances2Strain-engineered indirect-to-direct band gap transition, photocatalytic water splitting activity, and optical responses in ACuGa 6 S 10 (A = Rb and Cs)0Defect Diamond‐Like d 10 Metal Indium Selenium With Strong Second‐Harmonic Generation and Enhanced Laser‐Induced Damage Threshold3Eu 2+ ‐Activated KGa 5 S 8 : A New Super‐Sensitive Green Emitting Phosphor for Pressure Sensing1Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0A new phase and transformation mechanism in BaGa4Se7 infrared nonlinear optical crystal0Mineral‐Inspired and Computation‐Assisted Rational Design of Polar Gittinsite‐Type Thiophosphates With Exceptional Nonlinear Optical Performance4Enhancing Quantum Efficiency of Narrow Band Green Emitting Phosphor SrGa 2 S 4 :Eu 2+ via Solid Solution Engineering for Wide Color Gamut Display0

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  1. [Ba2F2][Ge2O3S2]: An Unprecedented Heteroanionic Infrared Nonlinear Optical Material Containing Three Typical Anions

    ACS Materials Letters · 2022-07-25

    Haonan Liu, Zhongfu Song, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  2. Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance

    ACS Applied Materials & Interfaces · 2022-08-11

    Jingjing Xu, Kui Wu, Yan Xiao, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  3. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

    Inorganic Chemistry · 2022-09-21

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  4. Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS6

    Inorganic Chemistry · 2022-10-20

    Nan Zhang, Qian-Ting Xu, Zhi‐Hui Shi, Mei Yang, Sheng‐Ping Guo

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  5. AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances

    Advanced Optical Materials · 2022-11-24

    Jiale Chen, Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  6. The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps

    Advanced Science · 2022-12-05

    Shaoxin Cui, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  7. Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction

    Inorganic Chemistry · 2022-12-16

    Yong‐Fang Shi, Shenghua Zhou, Bingxuan Li, Yi Liu, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  8. Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups

    Chemistry - A European Journal · 2022-12-16

    Yu-Jie Zhang, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  9. A unique [Sb 6 O 2 S 13 ] 12− finite chain in oxychalcogenide Ba 6 Sb 6 O 2 S 13 leading to ultra-low thermal conductivity and giant birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Yong‐Fang Shi, Shenghua Zhou, Pengfei Liu, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  11. Melilite oxychalcogenide Sr 2 FeGe 2 OS 6 : a phase-matching IR nonlinear optical material realized by isomorphous substitution

    Inorganic Chemistry Frontiers · 2023-01-01

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  12. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  13. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

    Small · 2023-02-12

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie International Edition · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

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  15. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

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  16. Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides

    Coordination Chemistry Reviews · 2023-04-05

    Jing Xu, Kui Wu

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  17. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

    Advanced Optical Materials · 2023-05-05

    Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  18. Recent progress of newly developed functional building units and corresponding nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-05-11

    Wenjing Tan, Chenyang Zhang, Chenyang Zhang, Tingting Huang, Bingbing Zhang

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  19. [Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds

    Small · 2023-06-04

    Kaixuan Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  20. Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties

    Chemistry of Materials · 2023-08-14

    Zixian Jiao, Osvaldo Medina Mireles, Kevin Ensz, Fei Wang, Mingli Liang, P. Shiv Halasyamani, Bingbing Zhang, D. Paul Rillema, Jian Wang

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  21. Synthesis of Non-centrosymmetric, Metastable Rare-Earth Oxysulfides by Anionic Redox Topochemistry

    Chemistry of Materials · 2023-09-08

    Louis-Béni Mvélé, Shunsuke Sasaki, Philippe Deniard, Yoshihiro Tsujimoto, Étienne Janod, Catherine Guillot‐Deudon, Maria Teresa Caldés, Isabelle Braems, B. Corraze, Stéphane Jobic, Laurent Cario

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  22. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

    Materials Today Chemistry · 2023-09-20

    Pengcheng Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  23. A ll HgM IV S 4 (A ll = Sr, Ba, M IV = Si, Ge): A Series of Materials with Large Second Harmonic Generation Response and Wide Band Gaps

    Advanced Optical Materials · 2023-09-28

    Xingyu Zhang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  24. Eu 2 MGe 2 OS 6 (M = Mn, Fe, Co): Three Melilite-Type Rare-Earth Oxythiogermanates Exhibiting Balanced Nonlinear-Optical Behaviors

    Inorganic Chemistry · 2023-09-28

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  25. Chiral and Polar Duality Design of Heteroanionic Compounds: Sr18Ge9O5S31 Based on [Sr3OGeS3]2+ and [Sr3SGeS3]2+ Groups

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  26. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

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  27. Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks

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  28. Heteroanionic [VO x S 4− x ] groups: tetrahedral units with large birefringence for mid-infrared nonlinear optical crystals

    Inorganic Chemistry Frontiers · 2024-01-01

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  29. Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)

    Inorganic Chemistry Frontiers · 2024-01-01

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  30. Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units

    CrystEngComm · 2024-01-01

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  31. Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework

    Inorganic Chemistry · 2024-02-23

    A-Yang Wang, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  32. Synthesis and Investigation of Electrochemical Studies on Thulium Tellurite (TmTeO3) for Supercapacitor Electrode Application

    NANO · 2024-04-04

    Shanmuga Sundaram Ariponnammal, N. G. Basil Ralph, S. Shanmugha Soundare, Ramasamy Jayavel

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  33. The first Hg-based oxychalcogenide Sr2HgGe2OS6: Achieving balanced IR nonlinear optical properties through synergistic cation and anion substitution

    Materials Today Physics · 2024-04-17

    Mao‐Yin Ran, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  34. Sr2HgGe2OS6: A Hg-Based Oxychalcogenide Infrared Nonlinear Optical Material Exhibiting Favorable Balance between a Large Band Gap and Strong Second Harmonic Generation Response

    Inorganic Chemistry · 2024-05-23

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  35. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  36. Ae3[TO3][SnOQ3] (Ae = Sr, Ba; T = Si, Ge; Q = S, Se) and Ba3[CO3][MQ4] (M = Ge, Sn; Q = S, Se): Design and Syntheses of a Series of Heteroanionic Antiperovskite-Type Oxychalcogenides

    Journal of the American Chemical Society · 2024-09-16

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  37. Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials

    Inorganic Chemistry · 2024-11-06

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  38. Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides

    Chemistry of Materials · 2024-12-03

    Mao-Yin Ran, Sheng-Hua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  39. Probing structural, surface morphological, optical, low temperature magnetic studies and electrochemical studies on gadolinium tellurite (GdTeO3)

    Zeitschrift für Physikalische Chemie · 2024-12-05

    Shanmuga Sundaram Ariponnammal, Ramalakshmi Ramakrishnan, Shanmugha Soundare Sivakumar

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  40. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  41. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  42. Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy

    Materials Chemistry Frontiers · 2025-01-01

    Zhen Qian, Deman Kong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  43. La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior

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  44. Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio

    Advanced Functional Materials · 2025-01-17

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  45. Two-in-one: assembling hybrid supertetrahedra chromophores and achieving high-performance “hexagonal warriors” in nonlinear optical crystals

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  46. A new synthetic tellurium oxychloride (ZrTe2O6Cl): structural evaluation, spectroscopic (FT–IR, Raman, UV–vis) properties and thermal (TGA/DSC) behavior

    Journal of Molecular Structure · 2025-02-25

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  47. Oxygen‐Substitution Induced High‐Performance Nonlinear Optical Properties: Witnessed by the First Quaternary Oxythiostannate

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  48. Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering

    Inorganic Chemistry · 2025-04-11

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  49. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

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  50. From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide

    Inorganic Chemistry · 2025-07-09

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