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RESEARCH PAPER · ACS Nano · 2021

Tunable Circularly Polarized Luminescence from Single Crystal and Powder of the Simplest Tetraphenylethylene Helicate

Ming Hu, Feng-Ying Ye, Cong Du, Weizhou Wang, Tingting Zhou, Miao-Li Gao, Minghua Liu, Yan‐Song Zheng

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Tunable Circularly Polarized Luminescence from Single Crystal and Powder of the Simplest Tetraphenylethylene HelicateOriginalChiral diphenylacrylonitrile–perylene liquid crystal with circularly polarized luminescence in the aggregated state10Circularly Polarized Luminescence (CPL) from Pyrene‐Appended Cyclohexanediamides and Photoirradiation‐Tuned CPL Inversion25Hindered Tetraphenylethylene Helicates: Chiral Fluorophores with Deep‐Blue Emission, Multiple‐Color CPL, and Chiral Recognition Ability10Hindered Tetraphenylethylene Helicates: Chiral Fluorophores with Deep‐Blue Emission, Multiple‐Color CPL, and Chiral Recognition Ability66Circularly Polarized Luminescence and Dynamic Regulation Based on the co-Assembly of L/D-Lysine Hydrochloride and Photoactivated AIE Molecules12Multicolor-tunable room-temperature afterglow and circularly polarized luminescence in chirality-induced coordination assemblies42Sign control of circularly polarized luminescence of chiral Schiff-base Zn( ii ) complexes through coordination geometry changes24The preparation and properties of circularly polarized luminescent liquid crystal physical gels with self-supporting performance11Fluorescent TPE Macrocycle Relayed Light-Harvesting System for Bright Customized-Color Circularly Polarized Luminescence192Helix‐Sense‐Selective Polymerization of Achiral Monomers for the Preparation of Chiral Helical Polyacetylenes Showing Intense CPL in Solid Film State14Structural Origin of Enhanced Circularly Polarized Luminescence in Hybrid Manganese Bromides113Structural Origin of Enhanced Circularly Polarized Luminescence in Hybrid Manganese Bromides16Metal-organic materials with circularly polarized luminescence141Chiral Macrocyclic AIEgens from BINOL and Tetraphenylethene via Tailoring Chirality of Luminescent Molecular Propellers20Cage-Confinement Induced Emission Enhancement16Clear Disclosure of Hierarchical Chirality Transfer Mechanism and Wide Full‐Color and White‐Light CPL Emissions with Both High glum and Intensity by TPE Helicates17Chirality Transfer from Polylactide to Achiral Fluorophore in Hierarchical Crystallization for Realizing Handedness-Tunable and Nonreciprocal Circularly Polarized Luminescence14Symmetry Breaking and Chiral Side Group Strategy to Manipulate Circularly Polarized Luminescence8Chiral diketopyrrolopyrrole dyes showing light emission in solid and aggregate states12Aggregation-Induced Emission-Active Nanostructures: Beyond Biomedical Applications111One‐Dimensional Chiral Copper Iodide Chain‐Like Structure Cu 4 I 4 ( R / S ‐3‐quinuclidinol) 3 with Near‐Unity Photoluminescence Quantum Yield and Efficient Circularly Polarized Luminescence47Ultralong Room-Temperature Phosphorescence with Second-level Lifetime in Water Based on Cyclodextrin Supramolecular Assembly128Time‐Dependent Colorful Circularly Polarized Organic Ultralong Room Temperature Phosphorescence from a Single‐Component Chiral Molecule32Asymmetric Synthesis of Tetraphenylethylene Helicates and Their Full-Color CPL Emission with High glum and High Fluorescence Quantum Yield22Polymorphism and Light‐Driven Forward Movement of TPE Derivative Micro‐Crystal due to ArH‐pi Interactions Difference5Inverted circularly polarized luminescence based on self-assembly of (1S)-camphanic-decorated biscyanostilbene in smectic mesophase and suspension5Phosphorescent Thermal Chiroptical Switch Built through Highly Efficient Chiral Recognition and Amplification6Boosting Circularly Polarized Luminescence from Alkyl‐Locked Axial Chirality Scaffold by Restriction of Molecular Motions15An organic polarized photonic heterostructure based on tetra(4-pyridylphenyl)ethylene2Enantioselective assembly of tetrahedral Zr 4 (embonate) 6 cages in zeolitic frameworks for synergetic circularly polarized luminescence1Intense Left‐handed Circularly Polarized Luminescence in Chiral Nematic Hydroxypropyl Cellulose Composite Films70Regulating aggregation-induced circularly polarized luminescence of chiral macrocyclic TPEs by tuning the linkage lengths10Synthesis of tetraphenylethylene-based small molecular sensor for the selective “turn-on” detection of pyrophosphoric acid in the aqueous solution3Flexible Organic Chiral Crystals with Thermal and Excitation Modulation of the Emission for Information Transmission, Writing, and Storage10Flexible Organic Chiral Crystals with Thermal and Excitation Modulation of the Emission for Information Transmission, Writing, and Storage47A Chirally Locked Bis-perylene Diimide Macrocycle: Consequences for Chiral Self-Assembly and Circularly Polarized Luminescence69Directed Chiral Self‐Assembly of Purely Organic Phosphors for Room‐Temperature Circularly Polarized Phosphorescence27Generation and Enhancement of Chirality-Induced Spin-Polarized Emission in 3D@1D Lead Halide Perovskites4Full‐color‐tunable chiral aggregation‐induced emission fluorophores with tailored propeller chirality and their circularly polarized luminescence49Intense Circularly Polarized Luminescence Induced by Chiral Supramolecular Assembly: The Importance of Intermolecular Electronic Coupling31Intense Circularly Polarized Luminescence Induced by Chiral Supramolecular Assembly: The Importance of Intermolecular Electronic Coupling10Tetraphenylethylene-based conjugated polymers with valine-containing side chains: Aggregation-induced emission, helical self-assembly, complexation-induced circularly polarized luminescence8Exceptionally High-glum Circularly Polarized Lasers Empowered by Strong 2D-Chiroptical Response in a Host–Guest Supramolecular Microcrystal29Circularly Polarized Lasing from Helical Superstructures of Chiral Organic Molecules3Circularly Polarized Lasing from Helical Superstructures of Chiral Organic Molecules43Boosted Circularly Polarized Luminescence of a Chiral Metallacage Through Co‐Assembly in Confined Microfluidic Environments16Optically active persistent luminescence in supramolecular nanoassemblies constructed from entirely achiral building blocks5Energy Transfer for Constructing Circularly Polarized Luminescence Materials: Recent Progress and Future Prospects42Significantly boosting circularly polarized luminescence by synergy of helical and planar chirality17Facile preparation, mechanochromic luminescence and excitation wavelength-dependent emission of tetra(1 H -benzo[ d ]imidazol-2-yl)ethene Zn( ii ) complexes and their applications2Dual-ligand chiral MOFs exhibiting circularly polarized room temperature phosphorescence for anti-counterfeiting20Contrasting Mechanochromic Luminescence of Enantiopure and Racemic Pyrenylprolinamides: Elucidating Solid‐State Excimer Orientation by Circularly Polarized Luminescence1Contrasting Mechanochromic Luminescence of Enantiopure and Racemic Pyrenylprolinamides: Elucidating Solid‐State Excimer Orientation by Circularly Polarized Luminescence18Achieving Dynamic Circularly Polarized Luminescence with 2D Hydrogen‐Bonded Organic Frameworks19High circularly polarized luminescence based on hydrogen-bonding columnar mesophase of an AIE-active mesogen with stronger D-A structure2Temperature and Solvent Dual Switch Photochromic Chiral Ionic Hydrogen‐Bonded Organic Framework for Circularly Polarized Luminescence and Advanced Encryption4Temperature and Solvent Dual Switch Photochromic Chiral Ionic Hydrogen‐Bonded Organic Framework for Circularly Polarized Luminescence and Advanced Encryption27Inverted Chiroptical Properties of Hybrid Metal Halides Through Reversible Chiral Induction Driven by External and Internal Chirality Transfer18Inverted Chiroptical Properties of Hybrid Metal Halides Through Reversible Chiral Induction Driven by External and Internal Chirality Transfer2Nonreciprocal Circularly Polarized Lasing from Organic Achiral Microcrystals17Hierarchical Chiral Luminescent Macrocyclic Porous Organic Polymer from Chiral π-Conjugated Macrocycles: Tunable Circularly Polarized Luminescence and Enantiomeric Fluorescent Sensing8Twisting Chiral Aggregation‐Induced Emission Macrocycles into a Microhelix with Boosted Circularly Polarized Luminescence2Twisting Chiral Aggregation‐Induced Emission Macrocycles into a Microhelix with Boosted Circularly Polarized Luminescence25Quasiracemic Crystallization of Luminescent Chiral Molecules: Mechanochromic Luminescence and Sign Inversion of Circularly Polarized Luminescence8Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing8Probing Multilevel Chiroptical Activity in Organic Supramolecular Microcrystals for High‐Performance Circularly Polarized Lasing0Chiral Organic Crystals of Binaphthyl Derivatives: Crystallinity-Enhanced CPL Performance6Visual β‐Sheet‐to‐β‐Turn Transition in Luminescent Polymeric Vesicles for Color‐Reporting Drug Delivery6Visual β‐Sheet‐to‐β‐Turn Transition in Luminescent Polymeric Vesicles for Color‐Reporting Drug Delivery2Dimension-Tunable Supramolecular Organic Frameworks with Chiral Pore Channels for Selective Guest Encapsulation and Enhanced Circularly Polarized Luminescence26Thermally Responsive White Circularly Polarized Light from Elastic Chiral Crystals via Dual Fluorescence‐Phosphorescence3Regulation of the Structure and Chiroptical Properties of Chiral Imidazolium Bismacrocycles via Specific Solvents3Precise Construction of Helical Unimolecular Micelles from Poly(phenylacetylene)s for Tunable Circularly Polarized Luminescence and Sensing0Advances in Organic Circularly Polarized Luminescent Materials1Chiral metal cluster-mediated chirality transfer in light-harvesting nanoribbons for amplified circularly polarized luminescence12Construction of BowtieCyclophane from Inherent Charged AIEgens for Two-Photon Excited Fluorescence and Supramolecular Drug Delivery4A chiral multibrominated triangular macrocycle for modulating circularly polarized phosphorescence1Chiral organization of tetraphenylethylenes mediated by multivalent hydrogen bonding2Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle3Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle0Mechanochemical engineering of chiroptical properties in indium-based chiral metal halides by grinding0Tetraphenylethylene-substituted salen complexes of Cu(II), Zn(II), and Ni(II): structural, photophysical, electrochromic and electrofluorochromic properties0Polymorphic Organic Microcrystals for Multi‐Color Circularly Polarized Laser Emission1Positive Encapsulation‐Induced Emission Control of Aggregation‐Induced Emission‐Active Anthracenes within Micellar Capsules in Water3Chiral Au(I)–NHC complexes: Manipulating TPE chirality in crystals via solvent-cooperative chiral transfer0Enantioselective Crystal Growth Induced by Mesoscopic Helical Platforms0

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